Distribution of PAHs in Surface Soils from Petroleum Handling Facilities in Calabar

The level of concentrations of polycyclic aromatic hydrocarbons (PAHs) in surface soils from petroleum handling facilities (kerosene tank, generating plant, petrol stations, mechanic workshops, leaking pipeline and air port fuel dump) from Calabar metropolis southeastern Nigeria was determined by gas chromatography/ mass spectrometry. The results show that total polycyclic aromatic hydrocarbons (PAHs) varied from 1.80 to 334.43 mg/kg with a mean of 50.31 mg/kg. The lowest value of 1.80 mg/kg was obtained from petrol station while the highest value of 334.43 mg/kg was obtained from facility characterised by petrol stations and mechanic workshops. The ratio of phenanthrene/anthracene and fluoranthene/pyrene, varied from 0.43 to 27.72 and from 0.14 to 17.76 respectively. These ratios indicate various sources for the PAH. The two to three ring PAHs are the most abundant. Based on the PAH ratios and content alone it is not possible to distinguish between contribution from motor vehicle exhaust, gasoline spillage, used engine oil or petroleum production. However, considering the area of the study, it is very likely that the major source of soil contamination is originating from petroleum product.     

Monitoring of the physical parameters and evaluation of the chemical composition of river and groundwater in Calabar (Southeastern Nigeria)

A 12-month study was carried to assess the seasonal and tidal effects on the physical parameters of river and groundwater, which constitute the major potable water sources in Calabar (Nigeria). The study also included an evaluation of the chemical composition of the different water bodies and their relationship. The results show that there was a significant seasonal effect on dissolved oxygen (DO) and nitrate in groundwater on one hand, and on temperature, redox potential (Eh), and DO in river water on the other. Also, a significant tidal influence exists on DO in both river-and groundwater. Comparison between groundwater and river water show statistically significant difference in EC, TDS, Eh, DO, Na, Cl and NO(3). The significant differences in EC, TDS, Na and Cl are due to tidal flushing. The difference in Eh is due to geology of the area while, NO(3) is as a result of anthropogenic pollution. The concentrations of ions in the river and groundwater for the different seasons and tidal cycles show an inverse relationship, while the river water is generally more concentrated than the groundwater. Using a binary mixing model, estimates show that the degree of mixing of river water and groundwater is low, with values of between 1.93% and 2.76% respectively, in the western and eastern parts of the study area. The study concludes that tidal flushing, anthropogenic effects and oxygen supply during recharge contribute to the shaping of water chemistry in the area.     

Associations Between Worker Characteristics,Workplace Factors,and Work-Related Musculoskeletal Disorders: A Cross-Sectional Study of Male Construction Workers in Nigeria

Objective. This study assessed the association between worker characteristics, workplace factors, and work-related musculoskeletal disorders (WMSDs) in Nigeria’s construction industry. Methods. A cross-sectional site-by-site survey was conducted in 5 existing construction companies in Uyo, Nigeria. The subjects (n = 1200 males), aged 18-55 years, filled in the semistructured Nordic musculoskeletal questionnaire and the job content questionnaire on demographics, work and lifestyle characteristics, and workplace risk factors for WMSDs. Results. The overall prevalence of WMSDs was 39.25%. Differences in age, race, weight, body mass index (BMI), education status, and employment status were significantly associated with the prevalence of WMSDs. Prevalence according to trade was as follows: ironworkers highest at 49% and administrative staff lowest at 31%. Ironworkers (55.7%), administrative staff (53.3%), and security staff (38.7%) scored higher on physical, psychosocial, and individual risk factors, respectively. Workplace factors with increased odds for WMSDs were psychological demands and mental workload, age, BMI, low work experience, low education status, awkward movement of head and arms, working against force or vibration, fast work pace, and race. Conclusion. The recorded high prevalence was multifactorial in etiology; hence, multi-intervention strategies are required.