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1.
Deepak Anurag Kumar Dinesh Sharma Varun 《Environmental science and pollution research international》2021,28(45):64014-64029
Environmental Science and Pollution Research - The waste from healthcare facilities (HCFs) is most devastating as they induce health hazards and pollute the environment. The effective management of... 相似文献
2.
Glucose oxidase is a well-known enzyme that catalyzes the oxidation of β-d-glucose to produce gluconic acid and hydrogen peroxide. Fenton reaction is a powerful oxidation technology used for the oxidation of groundwater pollutants. For the application of Fenton reaction in groundwater remediation, successful operation of Fenton reaction near neutral pH, and on-site generation of both H2O2 and chelate will be beneficial. The focus of this experimental study was to couple the glucose oxidation reaction with chelate-based Fenton reaction. The idea was to use the hydrogen peroxide and chelate gluconic acid generated during glucose oxidation for the dechlorination of 2,4,6-trichlorophenol (TCP) by Fenton reaction. The oxidation of glucose was achieved using the enzyme in free and immobilized forms. The rate of production of hydrogen peroxide was determined for each system, and was used to estimate the time required for complete consumption of glucose during the process, thus avoiding any traces of glucose in the Fenton reaction. In the case of free enzyme reaction, separation of the enzyme was achieved using an ultrafiltration membrane before initiating the Fenton reaction. The oxidation of TCP by Fenton reaction was performed at varying ratios of gluconic acid/Fe, and its effect on the decomposition of TCP and H2O2 was studied. TCP degradation was studied both in terms of parent compound degradation and free chloride generation. 相似文献
3.
Manita Thakur Deepak Pathania Gaurav Sharma Mu. Naushad Amit Bhatnagar Mohammad Rizwan Khan 《Journal of Polymers and the Environment》2018,26(4):1415-1424
Gelatin-Zr(IV) phosphate composite (GT/ZPC) was synthesized by sol–gel method. Different techniques viz. Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray powdered diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used for the characterisation of GT/ZPC composite ion exchanger. The ion exchange capacity (IEC) of GT/ZPC was observed to be better (1.04 meq g?1) than its inorganic counterpart (0.64 meq g?1). The pH studies revealed the monofunctional nature of GT/ZPC with one inflection point. The distribution studies showed that the GT/ZPC was highly selective for Cd2+ as compare to other metal ions. The environmental applicability of ion exchanger has been analysed for binary separations of metal ions using column method. Cd2+ was effectively removed from synthetic mixture of metal ions (Zn2+, Pb2+, Ni2+, Co2+ and Cu2+). 相似文献
4.
Sarkar Sayantan Datta Deepshikha Deepak K. S. Mondal Bikash Kumar Das Bimal 《Journal of Material Cycles and Waste Management》2023,25(4):1935-1965
Journal of Material Cycles and Waste Management - Waste lubricating oil is considered to be a hazardous waste and has tremendous impact on human health and environment. The present review... 相似文献
5.
Minakshi?Sultania Deepak?SrivastavaEmail author 《Journal of Polymers and the Environment》2011,19(4):950-956
Diglycidyl ether of bisphenol—A (DGEBA)—based epoxy resin was blended in the ratio of 3:1 (weight basis) with cycloaliphatic
epoxy (CAE) resin. The prepared blend sample was further blended with different weight percentages of carboxyl-terminated
butadiene acrylonitrile copolymer (CTBN) ranging between 0 and 25 wt% with an interval of 5 wt% and cured with stiochiometric
amounts of 4, 4’- diamino diphenyl sulphone (DDS) cure agent. Structural changes during blending were studied by Fourier-transform
infra-red (FTIR) spectroscopic analysis. The kinetic parameters, viz., order of decomposition reaction (n), activation energy (E), pre-exponential factor (Z) and rate decomposition constant (k), for the decomposition of the samples were calculated by applying Coats-Redfern equation over thermogravimetric (TG) data.
The degradation of each sample followed second-order degradation kinetics, which was calculated by Coats-Redfern equation
using best-fit analysis. This was further confirmed by linear regression analysis. The validity of data was checked by t-test
statistical analysis. Further, the blend sample had higher initial degradation temperature and activation energy than its
respective pure epoxy resin indicating that the CTBN acted as thermal stabilizer for epoxy resin which improved the thermal
stability. 相似文献
6.
Urbanization and its impact on groundwater: a remote sensing and GIS-based assessment approach 总被引:1,自引:0,他引:1
The perils of unplanned urbanization and increasing pressure of human activities on hydro-geomorphologic system often result
in modification of the existing recharge mechanism, which leads to many environmental consequences. In the present research,
an attempt has been made to investigate the applicability of remote sensing and geographical information system (GIS) in dealing
with spatial and temporal variability of dynamic phenomena, like urbanization and its impact on groundwater. This paper covers
primarily, quantitative and qualitative impacts of urban growth on the behavior of aquifer in Ajmer city (India). Urban growth
of the Ajmer city in last 17 years has been estimated from the satellite images. Database related to urbanization and groundwater
has been created in GIS. Groundwater recharge has been computed using a water balance approach known as Water Level Fluctuation
Methodology. Recharge estimation methodology has been implemented in GIS to introduce the spatial variability of hydro-geological
characteristics. Further, temporal and spatial variations in groundwater quality and quantity have been correlated with urban
growth using overlay analysis in GIS. The study reveals a general decline in water table and quality with urbanization. Further,
remote sensing and GIS technologies have been found useful in assessment of spatial and temporal phenomena of urbanization
and its impact on groundwater system. 相似文献
7.
Niraj Pant G. Kumar A. D. Upadhyay D. K. Patel Y. K. Gupta P. K. Chaturvedi 《Environmental science and pollution research international》2014,21(18):11066-11074
Environmental toxicants viz lead or cadmium and phthalate esters (di(2-ethylhexyl) phthalate [DEHP], dibutyl phthalate [DBP], and diethyl phthalate [DEP]) widely found in different environmental strata are linked to deteriorating male reproductive health. The objective was to assess the relationships between the seminal lead, cadmium, and phthalate (DEHP, DBP, DEP) concentrations at environmental level and serum hormone levels and semen quality in non-occupationally exposed men and specify the effect of individual and combined exposure of toxicants on semen quality. A study of 60 male partners of couples attending the Andrology Laboratory of the Reproductive Biology Department, All India Institute of Medical Sciences (AIIMS), New Delhi, India for semen analysis to assess their inability to achieve a pregnancy was selected for the study. The results of univariate and stepwise multiple regression analysis in the unadjusted model showed a significant correlation between lead or cadmium and phthalates DEHP/DBP/DEP and sperm motility, sperm concentration, and DNA damage. After adjusting for potential confounders, an association with lead or DEHP was only observed. The present data shows that lead (Pb) or cadmium (Cd) or phthalates might independently contribute to decline in semen quality and induce DNA damage. Phthalates might influence reproductive hormone testosterone. These findings are significant in light of the fact that men are exposed to a volley of chemicals; however, due to the small sample size, our finding needs to be confirmed in a larger population. 相似文献
8.
Deepak Pudasainee Yong-Chil Seo Jeong-Hun Kim Ha-Na Jang 《Journal of Material Cycles and Waste Management》2013,15(2):202-209
In this paper, emission and distribution behavior of six heavy metals (As, Cd, Cr, Ni, Pb, and Hg), particulate matter and mass distribution of mercury within the different streams of a fluidized bed sewage sludge incinerator are presented. At the inlet of air pollution control devices (APCDs); Cd, Cr, Ni and Pb were mainly enriched in coarse particles; comparatively As content was higher in fine particles (<PM2.5). The concentration of heavy metals in total particulate matter and PM2.5, at the inlet of APCDs, were in the order of Cr > Ni > Pb > As > Cd. Mercury was almost always distributed in flue gas. Metals, other than mercury, were efficiently removed in APCDs and their concentrations in bottom ash, with fly ash being higher, whereas for that in wastewater, then waste sand was lesser. Overall mercury removal efficiency of APCDs was 98.6 %. More than 83.3 % of mercury was speciated into oxidized form at the inlet of APCDs, attributed by higher chlorine content in sludge. Mercury was mainly distributed in wastewater (78.4 %), wastewater from a spray dry reactor (16.8 %), fly ash in a hopper (3.4 %) and flue gas (1.4 %). This result is one of the first for data to be obtained; more experiments are required to control emission from such sources. 相似文献
9.
Aquatic macroinvertebrate diversity in the Nanda Devi Biosphere Reserve (NDBR) was monitored for a period of twelve months (September 2000 to August 2001). All the important hydrological attributes were measured monthly for one year. Macroinvertebrates were sampled from three sites (S1$, S2$, & S3$) of the headwater stream Dhauliganga of NDBR. The present study revealed that the velocity of the water current, hydromedian depth, turbidity and dissolved oxygen in addition to nature and size of the bottom substrates have their significant impact on benthic invertebrate diversity. The ecological relevance of the measured hydrological attributes was investigated by comparing their degree of correlation with invertebrate density and diversity. Macroinvertebrate diversity was found to be highest (3.096 ± 0.03) in winter months (November–January) and lowest (2.816 ± 0.02) in monsoon months (July–August). The high diversity of macroinvertebrates may be due to low turbidity, high water transparency, optimum water temperature, high dissolved oxygen, low water velocity and suitable composition of the bottom substrates. 相似文献
10.
Anjana Pant 《The Environmentalist》2000,20(4):295-300
Nostoc calcicola cells exposed to mercuric chloride (0.05–0.25 M), methyl mercuric chloride (0.05–0.15 M) and the fungicide ceresan (phenyl mercuric acetate; 0.05–0.20 M) showed sensitivity in the sequence: methyl mercury3) over phenyl mercuric acetate (0.51×103); inorganic mercury occupied the intermediate position with a bioconcentration factor of 1.32×103. The data infer that larger molecules of organomercurials may not be taken up by cells at the rate and extent comparable to the smaller species. 相似文献