排序方式: 共有14条查询结果,搜索用时 31 毫秒
1.
Tekeli Muhammet Yasin Eraslan Gökhan Çakır Bayram Latife Soyer Sarıca Zeynep 《Environmental science and pollution research international》2021,28(13):15890-15908
Environmental Science and Pollution Research - The aim of this study was to investigate the protective efficacy of diosmin against subacute deltamethrin exposure. For this purpose, 40 male Wistar... 相似文献
2.
Cadmium and lead were determined simultaneously in seawater by differential pulse stripping voltammetry (DPSV) preceded by
adsoptive collection of complexes with 8-hydroxyquinoline (oxine) on to a hanging mercury drop electrode (HMDE). In preliminary
experiments the optimal analytical condition for oxine concentration was found to be 2.10−5 M, at pH 7.7, the accumulation potential was −1.1 V, and the initial scannig potential was −0.8 V. The peak potentials were
found −0.652 V for Cd and −0.463 V for Pb At the 60 s accumalation time. The limit of detection (LOD) and limit of quantitatification
(LOQ) were found to be by voltammetry as 0.588 and 1.959 μg l−1 (RSD, 5.50%) for Cd and 0.931 and 3.104 μg l−1 (RSD, 4.10%) for Pb at 60 s stirred accumulation time respectively. In these conditions the most of the seawater samples
are amenable for direct voltammetric determination of cadmium and lead using a HMDE. An adsorptive stripping mechanism of
the electrode reaction was proposed. For the comparison, seawater samples were also analysed by ICP-atomic emission spectrometry
method (ICP-AES). The applied voltammetric technique was validated and good recoveries were obtained. 相似文献
3.
The comparison of heavy metal accumulation ratios of some fish species in Enne Dame Lake (Kütahya/Turkey) 总被引:1,自引:0,他引:1
Uysal K Köse E Bülbül M Dönmez M Erdogan Y Koyun M Omeroglu C Ozmal F 《Environmental monitoring and assessment》2009,157(1-4):355-362
The metal accumulation levels for muscle, skin, gill, liver and intestine tissues of some Cyprinidae species (Carassius carassius, Condrostoma nasus, Leuciscus cephalus and Alburnus alburnus) in Enne Dame Lake (Kütahya/Turkey), which is mostly fed by hot spring waters, were investigated. Analyses were performed for copper (Cu), zinc (Zn), manganese (Mn), iron (Fe), cobalt (Co), magnesium (Mg), nickel (Ni), chrome (Cr) and boron (B) using inductively coupled plasma-optic emission spectroscopy (ICP-OES), and cadmium (Cd) using atomic absorption spectrophotometer (AAS) utilizing microwave digestion techniques. The concentrations of the heavy metals found in the fish varied in the follow ing ranges: Cu: < DL-7.04, Zn: 6.96-357.25, Mn: < DL-20.70, Ni: < DL-6.21, Fe: 9.62-2500.33, Cr: < DL-1.74, Co: < DL-0.54, Cd: 0.01-0.27 and Mg: 197.44-904.90 mg/kg wet weight. While B had the second highest concentration in the water of the lake, it was not encountered in any tissue of the investigated species. In all tissues and the species, While the bioaccumulation factors (BAFs) of Mn, Zn, Fe and Cu were remarkably high, the BAFs of Mg, Cr, Co, and B were also fairly low or none. Although the heavy metal accumulation levels for the muscle were generally lower than other tissues, there were some exceptions. Cd level in the muscle of C. carassius was higher than the permissible limit stated by Turkish legislation, FAO and WHO. The mean metal amounts for all the investigated tissues and species are statistically compared and discussed in this study. 相似文献
4.
Ünal Hüseyin Aktuğ Muhammet 《Environmental science and pollution research international》2022,29(30):45635-45645
Environmental Science and Pollution Research - This study investigates the effects of human capital, bio-capacity, energy use, and economic growth on the ecological footprint of G20 countries for... 相似文献
5.
Hasan Çabuk Muhammet Samet Kılıç Muhammet Ören 《Environmental monitoring and assessment》2014,186(3):1515-1524
This research was carried out in the cities of Zonguldak and Eregli, which have been characterized as urban and industrial environments of the Western Black Sea Region, Turkey, in order to assess the contamination of polycyclic aromatic hydrocarbons (PAHs) using mosses as biomonitors. The methodology involved the collection of moss samples (Hypnum cupressiforme), ultrasonic extraction with dichloromethane, cleanup using silica gel and analysis by liquid chromatography with ultraviolet detection. The total PAH concentrations ranged from 78.1 to 1693.5 ng g?1 in Zonguldak and from 15.2 to 275.1 ng g?1 in Eregli. The total PAH concentration in Eregli was about six times lower than that in Zonguldak, revealing the importance of switching from coal to natural gas in residential heating. The diagnostic ratios and the correlation analysis have indicated that coal combustion and traffic emissions were the major PAH sources at both sites. The contour maps were constructed for the determination of spatial distributions of total PAHs, and it was shown for Zonguldak as well as for Eregli that the PAH pollution was much more predominant in highly populated regions. Moving away from the city centres, a gradual decrease in PAH pollution rates was observed. 相似文献
6.
A Ethylene glycol dimethacrylate (EGDMA) methacrylic acid (MAA) resin was used for preconcentration of lead at trace levels in water samples. For this purpose, a flow-injection, solid phase extraction method was developed for the determination of lead by flame atomic absorption spectrometry. Lead ions were sorbed on a EGDMA–MAA column at pH 4, followed by an elution step using 288 µL of 4.0 M nitric acid solution and determination by flame atomic absorption spectrometry. Optimum conditions for quantitative sorption involving the pH, sample volume, loading and elution flow rates, eluent type, and volume were investigated. A 868-fold enrichment factor could be reached. The detection limit for the water samples, estimated from the noise on the signal obtained for 250 mL of 10 µg L?1 loaded at 4.9 mL min?1 was 1.04 µg L?1. The method was applied for lead determination in river water samples collected in Edirne, Turkey. Recoveries of spiked solutions (10 µg L?1) to river water samples were quantitative. Finally, the method was validated by the analysis of certified reference material SRM 2704 (Buffalo River Sediment). 相似文献
7.
Recep Ekiciler Muhammet Samet Ali Çetinkaya Kamil Arslan 《International Journal of Green Energy》2020,17(10):555-567
ABSTRACT Al2O3/water nanofluid has been numerically examined for the first time with different nanoparticle shapes including, cylindrical, blade, brick, platelet and spherical, on the flat and triangular-corrugated impinging surfaces. The volume fractions of 1.0%, 2.0% and 3.0% nanoparticles have been used. The Reynolds number is between 100–500 depending on the slot diameter. The finite volume method is utilized to determine the governing equations. The study is analyzed to determine how the flow features, heat transfer features and entropy production were affected by the diversity of nanoparticle shape, nanoparticle volume fraction, and shape of impinging surface. Darcy friction factor and Nusselt number are studied in detail for different conditions. The temperature contours are presented in the case of different nanoparticle volume fractions, nanoparticle shapes and both impinging surfaces. The results of the study suggest that the nanoparticle shape of the platelet shows the highest heat transfer development due to the thinner thermal boundary layer. Heat transfer augments with increasing volume fraction of nanoparticles. In addition, the study is consistent with the results of the literature on heat transfer and flow properties. 相似文献
8.
Varol Memet Sünbül Muhammet Raşit 《Environmental science and pollution research international》2017,24(29):23114-23124
Environmental Science and Pollution Research - In this study, levels of ten metals (arsenic, cadmium, cobalt, chromium, copper, iron, manganese, nickel, lead, and zinc) in muscles of farmed and... 相似文献
9.
Özlem Çakal Arslan Hatice Parlak Selma Katalay Meltem Boyacioglu Muhammet Ali Karaaslan Hale Guner 《Environmental monitoring and assessment》2010,165(1-4):55-66
Micronuclei tests is a system of mutagenicity testing used for determining the pollution and chemicals causing changes in DNA fragments such as micronuclei in the cytoplasm of interphase cells. Damage caused on the DNA by genotoxic pollutants is the first consequence occurring in the aquatic organisms. Thus, it was attempted to determine whether pollution affected the erythrocytes and gills of fish Gobius niger and haemolymph and gills of mussels Mytilus galloprovincialis living in Izmir Bay at the level of DNA by the means of micronuclei (MN) test. Organisms used in the MN test were collected from seven locations (Alsancak, Alaybey Shipyard, Karsiyaka, Bostanli, Göztepe, Konak and Pasaport) which are known as the most polluted part of inner Bay of Izmir (Western Coast of Turkey). According to the results of the present study, frequency of MN was found at high level in Alaybey Shipyard and Pasaport where wastes from existing dockyard contributed to high level of pollution. In conclusion, this study indicates that the micronuclei test gives sensitive results in monitoring the pollution, especially the pollution of harbor, and thus it might be used as standard method in regular monitoring of pollution of coastal ecosystem. 相似文献
10.
Yayintas OT Yilmaz S Turkoglu M Dilgin Y 《Environmental monitoring and assessment》2007,127(1-3):389-397
Waste water pollution of industrial areas can answer for the serious consequences of one of the most important environmental
threats to the future. In this study, inductively coupled plasma-atomic emission spectrometry method (ICP-AES) is proposed
to determine heavy metals (Pb, Cu, Cd, Cr, Zn, Al, Fe, Ni, Co, Mn) and major elements (Ca, Mg) in waste water of Kocabas Stream.
The concentration of metals in the waste water samples taken from 9 different stations (St.) in Biga-Kocabas Stream in November
2004 (autumn period) were determined after simple pretreatment of samples by the proposed ICP-AES method. An analysis of a
given sample is completed in about 15 min for ICP-AES the method. The results of heavy metals concentrations in waste water
were found between 0.00001–77.69610 mg l−1 by the ICP-AES technique. The concentrations of Pb, Cd, Cu, Zn, Cr, Al, Fe, Mn, Ni, Co, Mg and Ca 0.00001 (St.3,6,7) – 0.0087
mg l−1 (St.9), 0.00001 (St.4-7) – 0.0020 mg l−1 (St.8), 0.00001 (St.1,3-7,9) – 0.0041 mg l−1 (St.2), 0.0620 (St.2) – 0.2080 mg l−1 (St.3), 0.0082 (St.6) – 0.2290 mg l−1 (St.8), 0.3580 (St.2) – 1.7400 mg l−1 (St.3), 0.2240 (St.1) – 0.6790 mg l−1 (St.3), 0.0080 (St.1) – 1.5840 mg l−1 (St.3), 0.0170 (St.3) – 0.0640 mg l−1 (St.2), 0.0010 (St.1,4,5,8) – 0.0080 mg l−1 (St.3), 5.0640 (St.9) – 5.2140 mg l−1 (St.1) and 43.3600 (St.2) – 77.6961 mg l−1 (St.9), respectively. Also we measured environmental physicochemical parameters such as temperature, salinity, specific conductivity,
total dissolved solid (TDS), pH, oxidation and reduction potential (ORP), and dissolved oxygen (DO) in the waste water at
sampling stations. 相似文献