Thio arsenosugars in freshwater mussels from the Danube in Hungary

In contrast to the large body of data on naturally-occurring arsenic compounds in marine organisms, relatively little is known about arsenic speciation in freshwater biota. We report an investigation using HPLC-ICPMS into the arsenic compounds in five species of freshwater mussels collected from five sites from the Danube in Hungary. Total arsenic concentrations in the mussels ranged from 3.8-12.8 mg As kg(-1). The arsenic speciation patterns were broadly similar for mussels representing each of the five species and five sites, but quite different from those reported for marine mussels. The major extractable arsenicals were two oxo arsenosugars (glycerol sugar and phosphate sugar), and their thio analogues (thio glycerol sugar and thio phosphate sugar). Arsenobetaine, usually the major arsenical in marine organisms, was not a significant compound in the freshwater mussels and was detected in only three of the 11 samples. This is the first report of thio arsenosugars in freshwater biota and suggests that these compounds may be common and widespread naturally-occurring arsenicals.     

Monitoring the changes in impervious surface ratio and urban heat island intensity between 1987 and 2011 in Szeged,Hungary

Landsat time series data make it possible to continuously map and examine urban land cover changes and effects on urban environments. The objectives of this study are (1) to map and analyse an impervious surface and its changes within a census district and (2) to monitor the effects of increasing impervious surface ratios on population and environment. We used satellite images from 1987, 2003 and 2011 to map the impervious surface ratio in the census district of Szeged, Hungary through normalized spectral mixture analysis. Significant increases were detected from 1987 to 2011 in industrial areas (5.7–9.1%) and inner residential areas (2.5–4.8%), whereas decreases were observed in the city centre and housing estates due to vegetation growth. Urban heat island (UHI) values were derived from the impervious surface fraction map to analyse the impact of urban land cover changes. In 2011, the average value in the industrial area was 1.76 °C, whereas that in the inner residential area was 1.35–1.69 °C. In the city centre zones and housing estates, values ranging from 1.4 to 1.5 °C and from 1.29 to 1.5 °C, respectively, were observed. Our study reveals that long-term land cover changes can be derived at the district level from Landsat images and that their effects can be identified and analysed, providing important information for city planners and policy makers.     

AZFc deletion detected in a newborn with prenatally diagnosed Yq deletion

A case of prenatally diagnosed Yq deletion is described. Fluorescence in situ hybridisation (FISH) was used to identify the abnormal chromosome and to exclude mosaicism. Based on the cytogenetic result and the ultrasound investigation the pregnancy was continued. A newborn with normal male genitalia was delivered. Microdeletion analysis of the Yq showed the absence of the AZFc region. This type of deletion has been described as being associated with azoospermia or oligozoospermia with a progressive decrease of sperm number over time. Long-term andrological follow-up of the newborn will be necessary with eventual cryoconservation of sperm at early adulthood. The present report proposes that AZF analysis combined with FISH has an important role in accurate genetic counselling in sex chromosome anomalies. Copyright © 2001 John Wiley & Sons, Ltd.