Heavy metals in the SPM of air in the environment surrounding a ferro-alloy industrial plant in India

Prices for ferro-alloys have hardened due to the closure of plants in developed countries on account of increasingly stringent pollution control legislation, resulting in a higher cost of production. A ferro-alloy industry with a capacity of 80000 MT per annum was selected to study the nature of pollution. Because of the objectionable nature of polluting air in and around the plant it was located in a rural area where there was no other industry. The area was agriculturally active and there was no effective control system for this plant.The quality of ambient air around the plant site is discussed in this paper along with the meteorological conditions. The maximum concentration of suspended particulate matter (SPM) was 768 µg/NM³ downwind of the plant, minimum 184 µg/NM³, and the average was more than 446 µg/NM³. The presence of heavy metals, viz. Fe, Mn, Cr and Pb, was also assessed. The concentration of Fe was 50 µg/NM³ downwind and 10 µg/NM³ upwind. The concentration of other metals followed a similar trend.     

Effects of combinations of malathion and cypermethrin on survivability and time of metamorphosis of tadpoles of Indian cricket frog (Fejervarya limnocharis)

This study was undertaken to determine the effect of environmentally realistic concentrations of two commonly used pesticides viz., malathion and cypermethrin, using a fully 3 × 3 factorial experiments on the survivability and time of metamorphosis in a common rice paddy field frog (cricket frog) Fejervarya limnocharis under laboratory conditions. The results suggest that cypermethrin is more toxic than malathion and combinations of higher concentrations of cypermethrin (50 μg/L) with malathion (250 and 500 μg/L) are more deleterious to the survivability of tadpoles. With increasing cypermethrin concentration, the survivability of tadpole decreased (r = ?0.986, P = 0.108). But cypermethrin alone induced early metamorphosis among the surviving tadpoles. However, there was a delay in the time required for metamorphosis induced by malathion and its combination with cypermethrin. The delay in metamorphosis may indicate the altered physiological fitness of the individual. The emergent froglets will be subjected to environmental stressors like high temperature and less humidity of post-monsoon tropical climate that could enhance negative influence triggered by pesticides.     

Soil washing treatability tests for pesticide-contaminated soil

The 1987 Sand Creek Operable Unit 5 record of decision (ROD) identified soil washing as the selected technology to remediate soils contaminated with high levels of organochlorine pesticides, herbicides, and metals. Initial treatability tests conducted to assess the applicability of soil washing technology did not effectively evaluate the removal of the elevated contaminant concentrations that were found. To further evaluate the applicability of soil washing at this industrial site, a second more comprehensive pilot-scale treatability test was conducted. Twenty-three test runs were conducted over a two-week period in late September 1992, using a pilot-scale soil washing device called the volume reduction unit (VRU). The experimental design evaluated the effects of two wash temperatures, two pH levels, three surfactants, four surfactant concentrations, and two liquid-to-soil ratios on the contaminant removal efficiency of the soil washing process. Site soils from layers at three different depths were used in the study. Results from the pilot-scale treatability test indicated that the VRU could achieve contaminant reduction efficiencies of 97 percent for heptachlor and greater than 91 percent for dieldrin in the uppermost contaminated soils (surface to 1-ft. depth). Residual concentrations of heptachlor and dieldrin in the treated soil ranged from 50 ppm to less than 1.6 ppm, and 6.8 ppm to less than 1.6 ppm, respectively. However, the analytical method detection limit of 1.6 ppm was not low enough to provide residual concentration data at the risk-based action levels of 0.55 ppm for heptachlor and 0.15 ppm for dieldrin.     

Kinetic and equilibrium isotherm studies for the adsorptive removal of Brilliant Green dye from aqueous solution by rice husk ash

The present study deals with the adsorption of Brilliant Green (BG) on rice husk ash (RHA). RHA is a solid waste obtained from the particulate collection equipment attached to the flue gas lines of rice husk fired boilers. Batch studies were performed to evaluate the influences of various experimental parameters like initial pH (pH0), contact time, adsorbent dose and initial concentration (C0) on the removal of BG. Optimum conditions for BG removal were found to be pH0 approximately 3.0, adsorbent dose approximately 6 g L(-1) of solution and equilibrium time approximately 5 h for the C0 range of 50-300 mg L(-1). Adsorption of BG followed pseudo-second-order kinetics. Intra-particle diffusion does not seem to control the BG removal process. Equilibrium isotherms for the adsorption of BG on RHA were analyzed by Freundlich, Langmuir, Redlich-Peterson (R-P), Dubnin-Radushkevich (D-R), and Temkin isotherm models using a non-linear regression technique. Langmuir and R-P isotherms were found to best represent the data for BG adsorption onto RHA. Adsorption of BG on RHA is favourably influenced by an increase in the temperature of the operation. Values of the change in entropy (DeltaS0) and heat of adsorption (DeltaH0) for BG adsorption on RHA were positive. The high negative value of change in Gibbs free energy (DeltaG0) indicates the feasible and spontaneous adsorption of BG on RHA.     

The performance of three cultivars of rice grown near to, and distant from, a fertiliser plant

The effects of three cultivars, two water regimes and two rates of applying nitrogen fertilisers were tested when studying the performance of rice (Oryza sativa L.) near to, and distant from, a fertiliser plant emitting atmospherically dispersed pollutants. The atmosphere near the fertiliser plant had average daily peak concentrations of 144 and 210 microg m(-3) of SO(2) and NO(2), respectively. Growth was less near to, than at a distance from, the fertiliser plant. On average it was decreased by water stress while the effects of different amounts of nitrogen fertiliser were variable. Whilst there were a number of interactions involving nitrogen and water treatments, the most consistent were associated with the responses of the three cultivars at the two locations. The three cultivars performed similarly at the unpolluted control site, but there were major differences at the polluted site. These were most clearly exemplified by changes in the proportion of dry matter allocated to yields of grain and straw. At the unpolluted site, grain accounted for about 30% of the combined yields of grain and straw. At the polluted site, grain accounted for 1, 23 and 31% of the combined grain and straw yields of cultivars CO 43 (the most sensitive), TKM 9 and GR 3 (the most tolerant). Grain yields were closely related to numbers of filled grains per plant. At the polluted site, 98% of grains failed to develop in CO 43, whereas in GR 3, the number of panicles, and therefore the potential number of grains, was significantly enhanced.     

Ecological aspects of plankton production

The study was carried out in the neritic and estuarine waters of Porto Novo, Coromandel Coast, Bay of Bengal, India during the period January, 1960 to December, 1967. The average displacement volume of plankton usually varied between 2 and 4 c²/m². During summer, with a season of high plankton productivity, the average plankton displacement volume rose to 8 c²/m³. Generally speaking, the average zooplankton density (standing crop) was usually between 80,000 and 100,000 organisms/m³, of which copepods alone comprised usually between 70,000 and 90,000 organisms/m³. The average copepod density per sample varied from 30,000 to 50,000 organisms/m³. However, in the summer months, the copepod density was usually not less than 100,000 organisms/m³; in some years this was even higher (from 125,000 to 170,000 organisms/m³). Copepods comprised between 80 and 95% of the zooplankton population. The maximum non-copepod population in the zooplankton seldom reached 30%, was ofter below 25%, and usually less than 20%. During the period March to October (in some years as early as February, and in some years up to November), either an increasing or a steady trend of plankton production was evident. It would appear that salinity and rainfall determine the occurrence and distribution of plankton in Porto Novo.Contribution No. 189 from the Centre of Advanced Study in Marine Biology, Marine Biological Station of Annamalai University, Porto Novo, Tamilnadu, India.     

The adoption of a Climate Disaster Resilience Index in Chennai,India

Results derived from the Climate Disaster Resilience Index (CDRI)—consisting of five dimensions (economic, institutional, natural, physical, and social), 25 parameters, and 125 variables—reflect the abilities of people and institutions to respond to potential climate‐related disasters in Chennai, India. The findings of this assessment, applied in the 10 administrative zones of the city, reveal that communities living in the northern and older parts of Chennai have lower overall resilience as compared to the flourishing areas (vis‐à‐vis economic growth and population) along the urban fringes. The higher resilience of communities along the urban fringes suggests that urbanisation may not necessarily lead to a deterioration of basic urban services, such as electricity, housing, and water. This indication is confirmed by a strong statistical correlation between physical resilience and population growth in Chennai. The identification of the resilience of different urban areas of Chennai has the potential to support future planning decisions on the city's scheduled expansion.     

Characterization and Biotechnological Functional Activities of Exopolysaccharides Produced by Lysinibacillus fusiformis KMNTT-10

Journal of Polymers and the Environment - In this study, the production and physicochemical characterization of exopolysaccharide (EPS) produced by Lysinibacillus fusiformis KMNTT-10 were...     

Reproduction in Balanus amphitrite Darwin (Cirripedia: Thoracica): influence of temperature and food concentration

Balanus amphitrite, an acorn barnacle, is distinctly euryhaline, eurythermal and a dominant fouling organism found in warm and temperate waters throughout the world. In this study, the influence of temperature and food concentration on the reproductive biology of this species collected from a tropical habitat was evaluated. Adult barnacles were maintained at 20, 25 and 30°C temperatures at different concentrations of food (50, 100, 150 and 200 Artemia ind⁻¹ day⁻¹). In this previously believed obligatory cross-fertilizing hermaphrodite, self-fertilization was observed. The rise in temperature from 20 to 30°C resulted in a longer interbreeding interval (6–7 days, 200 Artemia ind⁻¹ day⁻¹; 11–13 days, 50 Artemia ind⁻¹ day⁻¹). Computed carbon gained through feeding during the interbreeding interval indicated an inverse relationship to the temperature. At 20°C, although a greater amount of carbon was gained through feeding, the numbers of larvae produced were fivefold less when compared to those raised at 30°C. At 20°C, 2.3 μg C was required to produce a single larva, whereas at 30°C it was 0.4 μg C. A rise in rearing temperature also influenced the molting rate positively. Observations on temporal variation in the gonad development of this species in a tropical coastal environment influenced by the monsoons indicated gonad development to be positively related to chlorophyll a concentration.     

Using biopolymers to remove heavy metals from soil and water

Chemical remediation of soil may involve the use of harsh chemicals that generate waste streams, which may adversely affect the soil's integrity and ability to support vegetation. This article reviews the potential use of benign reagents, such as biopolymers, to extract heavy metals. The biopolymers discussed are chitin and chitosan, modified starch, cellulose, and polymer-containing algae.