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排序方式: 共有137条查询结果,搜索用时 0 毫秒
1.
Priyanka P. Kumavat Asha D. Jangale Dipak R. Patil Kiran S. Dalal Jyotsna S. Meshram Dipak S. Dalal 《Environmental Chemistry Letters》2013,11(2):177-182
Thioureas are of importance in medicinal chemistry due to their biological activities such as antituberculosis, anti-HIV, analgesic, anti-inflammatory, antimicrobial, antiarrhythmic, fungicide, herbicides, rodenticides and as phenoloxidase enzymatic inhibitors. Treatment of primary and secondary amines with thiophosgene is the common method of making symmetrical disubstituted thioureas. However, this method is hazardous due to the toxic properties of thiophosgene. Here, we report a green, operationally simple approach for the synthesis of 1, 3-disubstituted thiourea derivatives in moderate to excellent yields of 57–99 %. We use primary amines and CS2 in water without any catalyst and solar thermal energy. This method is more environmentally benign and energy-saving compared with previously reported methods. 相似文献
2.
Volatile organic compounds (VOCs) analysis was carried out for the surface water of the Savitri river during the period of June 2005 to June 2007. BTEX compounds (Benzene, Toluene, Xylene & Ethyl benzene) were analyzed by using micro extraction technique (Purge & Trap). Concentrations of these BTEX compounds were ranging from 0.1 to 1.5 ppm during sampling period. Higher concentrations of BTEX were found at sampling location VI. Concentration of ethyl benzene was very low as compare to other compounds. However, the concentration of benzene was very high. Seasonal variations in conc. of BTEX compounds were observed and higher concentration was detected during the summer season. Salting-out effect had given higher quantification values. In PCA and PFA, the component loading for all the variables are positively correlated. Death of fishes was observed in the river that is indication of severe pollution problem. 相似文献
3.
Port causes environmental and health concerns in coastal cities if its operation and development are not made environmentally compatible and sustainable. An emission inventory is necessary to assess the impact of port projects or growth in marine activity as well as to plan mitigation strategies. In this study, a detailed emission inventory of total suspended particulate (TSP) matter, respirable particulate matter (PM10), sulphur dioxide (SO2) and oxides of nitrogen (NOx) for a port having operation and construction activities in parallel is compiled. The study has been done for 1 year. Results show that the maximum contribution of emission of air pollutants in the port area was from TSP (68.5%) and the minimum was from SO2 (5.3%) to the total pollutants considered in this study. Total TSP emission from all activities of the port was 4,452 tyr???1 and PM10 emission was 903 tyr???1 in the year 2006. Re-suspension of dust from paved roads was the major contributor of TSP and PM10 in the road transport sector. Construction activities of the port had contributed 3.9% of TSP and 7.4% of PM10 to total emission of particulate matter. Of the total particulate emissions from various port activities approximately 20% of TSP could be attributed to PM10. The sectoral composition indicates that major contribution of SO2 emission in the port was from maritime sector and major contribution of NOx was from road transport sector. 相似文献
4.
Ports can generate large quantity of pollutants in the atmosphere due to various activities like loading and unloading,transportation, and construction operations. Determination of the character and quantity of emissions from individual sources is an essential step in any project to control and minimize the emissions.In this study a detailed emission inventory of total suspendedparticulate matter (TSP), particulate matter less than 10 m(PM10), sulfur dioxide (SO2) and nitrogen oxides (NOx) for a port and harbour project near Mumbai is compiled. Results show that the total annual average contributions of TSP and PM10 from all the port activitieswere 872 and 221 t yr-1, respectively. Annual average emissions of gaseous pollutants SO2 and NOxwere 56 and 397 t yr-1, respectively, calculatedby using emission factors for different port activities. The maximum TSP emission (419 t yr -1) was from paved roads, while the least (0.4 t yr-1) was from bulk handling activity. The maximum PM10 emission (123 t yr-1) was from unpaved roads and minimum (0.2 t yr-1) from bulk handling operations. Similarly the ratio of TSP and PM10 emission was highest (5.18) from paved roads and least (2.17) from bulk handling operations. Regression relation was derivedfrom existing emission data of TSP and PM10 from variousport activities. Good correlation was observed between TSP andPM10 having regression coefficient >0.8. 相似文献
5.
Patil MP Subramani T Patil SA Chakrabarti T 《Environmental monitoring and assessment》2002,76(3):299-309
A comprehensive environmental assessment (EA) is a pre-requisite before the site for developing a hazardous waste treatment and disposal facility (HWTDF) is selected. However, the resource limitations, especially for developing countries, often dictatethat the detailed EA be restricted to those sites, which are constraint free and have low hazard potentials. Thus, a preliminary screening exercise for assessing the suitability ofsite for developing the HWTDF needs to be carried out to avoid huge costs involved in detailed EA. While screening a HWTDF site,various factors such as present land use, ecologically sensitiveareas, geology and hydrogeology of the area, the quality and quantity of wastes, engineered safeguards, and the operationalprocedures that need to be adopted, are required to be addressed. In this paper, a multi-level screening criteria employing RemoteSensing, Constraint Mapping, Groundwater Pollution Potential Index (DRASTIC Index), and the Site Ranking was used to assess the suitability of a proposed site for the development of HWTDF.The study helped to identify various constraints at the proposedsite and their significance on the development of the HWTDF. 相似文献
6.
This paper presents a scan statistic, progressive upper level set (PULSE) scan statistic, for geospatial hotspot detection
and its software implementation. Like ULS, the PULSE scan statistic is based on the arbitrarily shaped scan window and can
be adapted for a network setting. PULSE is a refinement of the upper level set (ULS) scan statistic. Like some other likelihood
based scanning devices, the ULS scan statistic identifies maximum likelihood estimate (MLE) zones that tend to be ‘stringy’
and sprawling. Its search path increases possibility of inclusion of extraneous cells in its MLE zones and, to a smaller extent,
of exclusion of cells that belong to a true hotspot from its MLE zone. The PULSE scan statistic achieves improvement over
the ULS scan statistic in two ways. First, it begins its search for a most likely zone with a large population of candidate
zones obtained by modifying the ULS tree structure and continues its search using a genetic algorithm. Secondly, to reduce
chances of generating an MLE that is excessively stringy and that includes extraneous cells in the MLE zone, PULSE uses cardinality
and compactness of zones along with their likelihoods as the fitness function in the genetic algorithm and uses several pertinent
criteria including evenness of intra-zone cellular response ratios to determine the MLE zone. To reduce computation, Gumbel
distribution of extreme values is used to determine the p-value of the MLE zone. Better results come at the cost of increased processing time. An evaluative performance study is presented. 相似文献
7.
Srivastava A Joseph AE More A Patil S 《Environmental monitoring and assessment》2005,109(1-3):227-242
Air pollution has assumed gigantic proportion killing almost half a million Asians every year. Urban pollution mainly comprises
of emissions from buses, trucks, motorcycle other forms of motorized transport and its supporting activities. As Asia's cities
continue to expand the number of vehicles have risen resulting in greater pollution. Fugitive emissions from retail distribution
center in urban area constitute a major source. Petrol vapours escape during refueling adding pollutants like benzene, toluene,
ethylbenzene and xylene to ambient air. This paper discusses a study on fugitive emissions of Volatile Organic Compounds (VOC)
at some refueling station in two metropolitan cities of India, i.e., Mumbai and Delhi. Concentration of VOCs in ambient air
at petrol retail distribution center is estimated by using TO-17 method. Concentration of benzene in ambient air in Delhi
clearly shows the effect of intervention in use of petroleum and diesel fuel and shift to CNG. Chemical Mass Balance (CMB)
model is used to estimate source contributions. At Delhi besides diesel combustion engines, refueling emissions are also major
sources. At Mumbai evaporative emissions are found to contribute maximum to Total VOC (TVOC) concentration in ambient air. 相似文献
8.
Patil Sakshi Bafana Amit Naoghare Pravin K. Krishnamurthi Kannan Sivanesan Saravanadevi 《Environmental science and pollution research international》2021,28(5):4951-4974
Environmental Science and Pollution Research - Microplastics are considered to be ubiquitous and widespread emerging contaminants. They are persistent in the nature and pose considerable harm to... 相似文献
9.
Composite sampling techniques for identifying the largest individual sample value seem to be cost effective when the composite samples are internally homogeneous. However, since it is not always possible to form homogeneous composite samples, these methods can lead to higher costs than expected. In this paper we propose a two-way composite sampling design as a way to improve on the cost effectiveness of the methods available to identify the largest individual sample value. 相似文献
10.
Assessment of drinking water quality using ICP-MS and microbiological methods in the Bholakpur area,Hyderabad, India 总被引:1,自引:0,他引:1
Abdul RM Mutnuri L Dattatreya PJ Mohan DA 《Environmental monitoring and assessment》2012,184(3):1581-1592
A total of 16 people died and over 500 people were hospitalized due to diarrhoeal illness in the Bholakpur area of Hyderabad,
India on 6th May 2009. A study was conducted with immediate effect to evaluate the quality of municipal tap water of the Bholakpur
locality. The study consists of the determination of physico-chemical properties, trace metals, heavy metals, rare earth elements
and microbiological quality of drinking water. The data showed the variation of the investigated parameters in samples as
follows: pH 7.14 to 8.72, EC 455 to 769 μS/cm, TDS 303.51 to 515.23 ppm and DO 1.01 to 6.83 mg/L which are within WHO guidelines
for drinking water quality. The water samples were analyzed for 27 elements (Li, Be, B, Na, Mg, Al, Si, K, Ca, V, Cr, Mn,
Fe, Ni, Co, Cu, Zn, As, Se, Rb, Sr, Mo, Ag, Cd, Sb, Ba and Pb) using inductively coupled plasma-mass spectrometry (ICP-MS).
The concentrations of Fe (0.12 to 1.13 mg/L), Pb (0.01 to 0.07 mg/L), Cu (0.01 to 0.19 mg/L), Ni (0.01 to 0.15 mg/L), Al (0.16
to 0.49 mg/L), and Na (38.36 to 68.69 mg/L) were obtained, which exceed the permissible limits of the World Health Organization
(WHO) for drinking water quality guidelines. The remaining elements were within the permissible limits. The microbiological
quality of water was tested using standard plate count, membrane filtration technique, thermotolerant coliform (TTC), and
most probable number (MPN) methods. The total heterotrophic bacteria ranged from 1.0 × 105 to 18 × 107 cfu/ml. Total viable bacteria in all the water samples were found to be too numerable to count and total number of coliform
bacteria in all water samples were found to be of order of 1,100 to >2,400 MPN index/100 ml. TTC tested positive for coliform
bacteria at 44.2°C. All the water samples of the study area exceeded the permissible counts of WHO and that (zero and minimal
counts) of the control site (National Geophysical Research Institute) water samples. Excessively high colony numbers indicate
that the water is highly contaminated with microorganisms and is hazardous for drinking purposes. Bacteriological pollution
of drinking water supplies caused diarrhoeal illness in Bholakpur, which is due to the infiltration of contaminated water
(sewage) through cross connection, leakage points, and back siphoning. 相似文献