Nylon recovery from carpet waste through pyrolysis under the presence of zinc oxide and the roll-milling treatment

Recycling of carpet waste is not extensively carried out because of its complex combination of materials. A representative type of carpet consists of three layers: nylon fibers, adhesives, and backing materials made of poly(vinyl chloride), PVC. Thermal treatment of carpet waste, thus, leads to the emission of hazardous chlorinated compounds. In the present work, we have employed the one-directional thermal treatment of the backing materials under the presence of zinc oxide, which promotes the thermal degradation of PVC. Nylon fibers could be effectively recovered by the consequent milling treatment from the brittle backing materials. The influence of process parameters, such as pyrolysis temperature and reaction time, on the separation efficiency is discussed.     

Seismological aspects of the Japan Sea earthquake of 1983

The Japan Sea earthquake of 1983 took place at the eastern margin of the Japan Sea, which is a marginal sea situated west of the island are of Japan and the Japan trench in the Pacific Ocean. Its magnitude of 7.7 is the largest among earthquakes which have been known to occur in the seismic belt along the Japan Sea coast of Northeast Honshu, Japan. Since the seismic activity in the belt is not so high, the earthquake is especially important in the geophysical interpretation of tectonic process in the region. The aftershock distribution and the focal mechanism reveals that the earthquake is a thrust fault on a plane dipping eastwards by about 30°. The waveform analysis shows that the earthquake can be regarded as a double shock to a first approximation. Interestingly, there was a 10-second intermission between the two events. These are preliminary results, and more detailed studies are under development.     

Use of a seeder reactor to manage crystal growth in the fluidized bed reactor for phosphorus recovery.

The authors have been engaged in the development of a phosphorus recovery system capable of maintaining high recovery efficiencies, with the chemical cost suppressed. This time, they conducted demonstration tests of a fluidized bed magnesium ammonium phosphate reactor provided with a seeder reactor for the supernatant from anaerobic digestion using a pilot experimental plant with a wastewater treatment capacity of 20 m3/d. For the digestion supernatant with a phosphorus concentration of approximately 300 mg/L, the treated water phosphorus concentration was 10 to 25 mg/L, and the phosphorus recovery efficiency was more than 90%. Relative to the chemical cost in the case of magnesium chloride, the chemical cost in the case of magnesium hydroxide is approximately 40%. Thus, with the new system, it was possible to reduce the running cost while maintaining high recovery efficiencies.     

Decontamination of anaerobically digested slurry in a paddy field ecosystem in Jiaxing region of China

Anaerobic digestion has become increasing popular for managing biowastes in rural China as it has the advantage of generating biogas, a renewable energy. A new challenge, however, is minimizing the environmental pollution resulting from the anaerobically digested slurry (ADS). The aim of this study was to assess the feasibility of using a paddy field to remediate ADS while simultaneously cultivating rice. A field experiment was trialed using six treatments based on varying nitrogen loadings over the period of a rice-growing season. These treatments were adjusted to the content of the N within the ADS and had loadings of 270, 405, 540 and 1080 kg N ha⁻¹. These treatments were compared to a negative control (no fertilizer) and a positive control (chemical fertilizer) that consisted of urea applied at 270 kg N ha⁻¹. The effects of these N sources and slurry remediation were monitored using standard methods to measure water quality, soil properties and changes in rice production. Rice grain yields were generally higher for all ADS treatments than for the urea N treatment. Standing water quality in the field could reach national discharge standards for all treatments within 7-8 days after each ADS irrigation. Groundwater quality and heavy metal concentrations in both soil and the rice grain were not affected by the ADS treatments. We suggest that the quantities of ADS irrigated in 867-1734 m³ ha⁻¹ was not only safe for food quality (rice grain) and the receiving environment (water and soil), but also beneficial to soil fertility and rice grain yield.