气袋直接进样法测定丙烯腈

采用气袋直接进样法测定环境和污染源空气中的丙烯腈。结果表明:丙烯腈在0.4～99.5 mg/m3浓度范围内具有良好的线性关系,相关系数为0.999 8。在低、中、高3个添加水平回收率为88.9%~100%,相对标准偏差为0.6%~4.7%,均能较好地满足实验室分析要求。     

Airbag for the closing of pipelines on explosions and leakages

This paper is a result of international effort aimed at the construction of a device for quick closing of pipelines in the case of explosion propagation and/or chemical leakage. Such a problem exists in industries where flammable substances are transported by pipelines. The basic solution principle was the idea to use airbags similar to those utilized in cars.

Two pipeline applications were taken into consideration: a low-pressure module able to suppress explosion propagation and a high-pressure module to stop leakages from, e.g. natural gas pipeline capable to be used for duct diameters up to 0.6 m, pressures up to 5 MPa and reaction times of 50 ms. It was necessary to construct a new airbag, capable of withstanding up to 10 bar pressure. The choice of material was critical to ensure sufficient strength and chemical resistance while retaining impermeability.

CFD modeling of the bag deployment into a pipe flow and analysis of the bag shapes was also completed. Two gas generators were constructed and tested with novel propellant materials.

Different airbag models were tested to evaluate their effectiveness. Risk analysis approach was applied to evaluate the safety and economic benefits of the new technology in different fields of application.