稳定土技术在土路扬尘治理中的应用及展望

综合分析了稳定土技术用于土路扬尘污染治理的各种方法。然后在此基础上对该课题的研究及其发展提出了有关看法和建议     

克雷伯氏菌NY1产絮凝剂的阳离子修饰研究

为简化微生物絮凝剂投加步骤,消除由于助凝剂添加而引起的环境二次污染问题,以3-氯-2-羟丙基三甲基氯化铵(CTA)修饰荷负电的微生物絮凝剂(~-54mV),从而获得荷正电的改性絮凝剂.实验结果显示,CTA与NaOH的摩尔比值是影响阳离子修饰效果的主要因素;阳离子修饰的的最佳条件为:10g微生物絮凝剂, 0.015mol CTA,20%含水率,CTA与NaOH的摩尔比为0.95,80℃反应2h后.在最佳条件下所得阳离子化微生物絮凝剂的Zeta电位可达+16mV,其对高岭土的絮凝率也由阳离子化前的60.5%上升至91%.由阳离子化絮凝剂的结构表征可知,阳离子修饰过程并未改变微生物絮凝剂的根本结构,只是在原微生物絮凝剂基础上引入阳离子基团,从而增加了絮凝剂整体分子量;同时,由于阳离子基团的大量引入,絮凝剂的结晶度增加,从而使其溶解度增加.将阳离子化前后微生物絮凝剂应用于去除铜绿微囊藻,当阳离子化后微生物絮凝剂添加量为40mg/L时,其对藻类的去除率超过98%;而未阳离子修饰的微生物絮凝剂对该藻几乎没有去除效果.     

Cationic content effects of biodegradable amphoteric chitosan-based flocculants on the flocculation properties

A series of biodegradable amphoteric chitosan-based flocculants (3-chloro-2-hydroxypropyl trimethyl ammonium chloride (CTA) modified carboxymethyl chitosan, denoted as CMC-CTA) with different substitution degrees of CTA were prepared successfully. The content of carboxymethyl groups in each CMC-CTA sample was kept almost constant. The solubility of the various flocculants showed that, higher cationic content of flocculants caused a better solubility. The flocculation experiments using kaolin suspension as synthetic water at the laboratory scale indicated that the substitution degree of CTA was one of the key factors for the flocculation properties. With the increase of cationic content, the flocculants were demonstrated better flocculation performance and lower dosage requirement. Flocculation kinetics model of particles collisions combining zeta potential and turbidity measurements was employed to investigate the effects of the cationic content of the flocculants on the flocculation properties from the viewpoint of flocculation mechanism in detail. Furthermore, flocculation performance using raw water from Zhenjiang part of Yangtze River at the pilot scale showed the similar effects to those at the laboratory scale.     

Cold-modeling study of a circulating fluidized-bed reactor for flue gas desulfurization (FGD)

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Catalyst assisted destruction of trichloro ethylene and toluene in corona discharges

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印染废水处理方法的研究

针对印染废水的特点 ,采用混凝沉降 -氧化法处理印染废水。根据生产实际 ,把废水分成较易处理和较难处理两种情况。经过混凝沉降、化学氧化、砂滤后 ,可达到国家印染废水的排放标准。同时 ,确定了主要技术参数和工艺流程 ,并对实验结果进行了理论和经济分析     

三醋酸纤维(CTA)正渗透膜活性层朝向对正渗透过程的影响

本文通过在线实时监测研究了三醋酸纤维(CTA)正渗透膜的活性层在朝向料液(AL-FS)和汲取液(AL-DS)两种模式下的正渗透水通量、反向溶质通量、特性反向溶质通量等因素及其变化规律。在实验室条件下模拟了三醋酸纤维膜(CTA)对于不同浓度苦咸水的处理,当苦咸水浓度为2000ppmNaCl、5000ppmNaCl、8000ppmNaCl时,CTA膜活性层朝向对脱盐率几乎没有影响,AL-FS模式和AL-DS模式的脱盐率分别为96.49%和96.13%、97.40%和96.38%、98.04%和96.81%。研究结果对于进一步开发CTA正渗透系统和实用化具有重要意义。