Hazard evaluation for chlorination and amination reactions of fluorocytosine production process

Reaction thermal runaway is one of the most important reasons leading to chemical accidents. With the rapid development of the chemical industry in the world, especially the fine chemical industry, various safety accidents also occur frequently. Therefore, it is necessary to study the exothermic behavior of the reaction process. In this study, reaction calorimeter was used to study the exothermic phenomena during the chlorination reaction and amination reaction. Differential scanning calorimetry was performed on the reactants, and thermogravimetric experiments were performed on the products. In addition, adiabatic experiment was performed to study the thermal runaway behavior of amination products under adiabatic conditions. The results showed that the target reactions generated a large amount of heat in the initial stage. The maximum temperature of amination reaction is higher than the initial decomposition temperature of the amination product under adiabatic condition. The pyrolysis of amination product was divided into three stages. The product had a high apparent activation energy at the beginning of decomposition, and the apparent activation energy decreased as the decomposition progressed.     

Batch sorption dynamics and equilibrium for the removal of lead ions from aqueous phase using activated carbon developed from coffee residue activated with zinc chloride

Lignocellulosic materials are good precursors for the production of activated carbon. In this work, coffee residue has been used as raw material in the preparation of powder activated carbon by the method of chemical activation with zinc chloride for the sorption of Pb(II) from dilute aqueous solutions.The influence of impregnation ratio (ZnCl₂/coffee residue) on the physical and chemical properties of the prepared carbons was studied in order to optimize this parameter. The optimum experimental condition for preparing predominantly microporous activated carbons with high pore surface area (890 m²/g) and micropore volume (0.772 cm³/g) is an impregnation ratio of 100%. The developed activated carbon shows substantial capability to sorb lead(II) ions from aqueous solutions and for relative impregnation ratios of 75 and 100%, the maximum uptake is practically the same. Thus, 75% represents the optimal impregnation ratio.Batch experiments were conducted to study the effects of the main parameters such as contact time, initial concentration of Pb(II), solution pH, ionic strength and temperature. The maximum uptake of lead(II) at 25 °C was about 63 mg/g of adsorbent at pH 5.8, initial Pb(II) concentration of 10 mg/L, agitation speed of 200 rpm and ionic strength of 0.005 M. The kinetic data were fitted to the models of pseudo-first order and pseudo-second order, and follow closely the pseudo-second order model. Equilibrium sorption isotherms of Pb(II) were analyzed by the Langmuir, Freundlich and Temkin isotherm models. The Freundlich model gives a better fit than the others.Results from this study suggest that activated carbon produced from coffee residue is an effective adsorbent for the removal of lead from aqueous solutions and that ZnCl₂ is a suitable activating agent for the preparation of high-porosity carbons.     

Effects of typical additives on the thermal stability of ammonium peroxydisulfate

Ammonium peroxydisulfate (APS), one of the most widely used inorganic peroxides in the process industries, is a thermally unstable peroxide and potent oxidizer due to the presence of peroxy bond in the molecule and is incompatible with most substances. To investigate the effect of typical additives on the thermal decomposition of APS, in this paper, diamine phosphate (DAP), monoamine phosphate (MAP), and aluminum hydroxide (AH) were selected as additives; pure APS and samples with 10 wt% and 20 wt% of additives were first tested by differential scanning calorimetry (DSC). The experiments and analysis showed that the samples with 10 wt% of additive had better thermal stability than those with 20 wt% of additive. After screening, the three groups of 10 wt% AH, 10 wt% MAP, and 20 wt% MAP additive conditions could be considered to have a better thermal stability effect on the thermal decomposition of APS. Four groups of samples were, in turn, tested by Phi-Tec II. The adiabatic results showed two discontinuous exothermic processes; 10 wt% AH promoted the weak exothermic effect in the first stage. In contrast, the three groups of additives in the main exothermic stage showed different degrees of inhibition, and the inhibiting effect was ranked as 10 wt% AH, 10 wt% MAP, and 20 wt% MAP in order. Finally, the self-accelerated decomposition temperature (SADT) was calculated under the 25 kg standard package. The adiabatic results, including SADT, were combined to render feasible recommendations for the use of additives, which provides references for the packaging and transportation of additives and their applications.     

几种捕集高比电阻粉尘的电收尘器的机理

详细论述了影响电收尘器收尘效率的主要因素,指出常规电收尘器在捕集高比电阻粉尘时产生反晕现象,从而使收尘效率大大降低,并且提出几种适用于捕集高比电阻粉尘的电除尘结构,对开发新型电收尘器有一定的指导作用。     

加卸载响应比理论用于中期地震预报的研究进展

本文对近年来在加卸响应比理论应用于中期地震预报的研究方面所取得的进展进行了评述。主要内容为大震震例检验、地震平静区的强烈反差、国外典型震例、互补与超前现象以及地震预测的尝试。展望了加卸载响应比理论的应用前景。     

锅炉缺水事故的现象、原因和预防措施

概述了锅炉缺水事故的现象和原因，对锅炉缺水从管理到技术方面提出预防措施，是作者20多年从事锅炉设备运行和技术管理实际工作经验之集成。     

EVALUATING RELIABILITY OF STORAGE SCHEMES WITH DENDROHYDROLOGY AND THE HURST PHENOMENON1

ABSTRACT: The mean annual flow at a damsite during a water project yield study of several decades may differ considerably from the mean flow of several hundred years. The frequency of the most severe droughts of record may be much different than apparent from the historical record as well. Dendrohydrology and the Hurst Phenomenon provide means to evaluate the validity of the study period for project reliability analysis. The most severe hydrologic drought (1928–1934) affecting the watersheds of the Sacramento River and tributaries in Northern California during the 75-year period 1906–1980 was also the worst drought in 421 years (1560–1980). In contrast, the most severe drought (1945–1951) in the Santa Ynez River watershed in Santa Barbara County, California, during the 62-year period 1918–1979 was the ninth worst drought in 443 years (1537–1979). Thus, in one case the drought risk indicated by the dendrohydrologic time series would actually be less; in the other, actual risk would be greater than perceived from the historical record. In the absence of a dendrohydrologic prehistoric time series, Hurst Phenomena would have provided clues to this outcome. Hurstian plotting of the accumulated deviation from the mean for long time series facilitates observation of the wet-dry regime of the examples and identification of characteristics that should be accounted for in water development planning.     

基于逆滤波法的图像复原技术研究

主要研究对已损坏了的图像恢复.它是利用退化现象的某种先验知识(退化模型),按退化的逆过程重建图像的技术.其退化模型是原始图像经过算子,或系统经退化因素作用之后和噪声叠加,形成退化后的图像,即实际得到的图像.利用逆滤波法复原的原理,通过已知复原图像和噪声,采用退化函数,经过反傅里叶变换,求出原始图象.同时以Visual C++6.0与Matlab为开发工具.实验表明本算法具有良好的性能,能有效抑制和清除干扰对测试结果的影响,具有算法简单可靠等优点,使图像质量得到改善.     

Calorimetric behaviors of hydroxylamine and its salts caused by Fe(III)

The objective of this study is to obtain information on the calorimetric behaviors of aqueous solutions of hydroxylamine (HA), hydroxylamine chloride (HACl), and hydroxylamine nitrate(HAN) caused by different Fe(III) states (free Fe(III) from Fe(NH₄)(SO₄)₂, Fe(CN)₆³⁻, and Fe(EDTA)⁻). The calorimetric data were obtained with a small-scaled reaction calorimeter, Super-CRC.

In the mixing with Fe(III), HA showed the highest reactivity among three substrates. Free Fe(III) and Fe(EDTA)⁻ showed catalytic effects in the reactions. In the overall heat of reactions, Fe(EDTA)⁻ exceeded free Fe(III), which precipitated as Fe(OH)₃ and decreased the chances of interactions with HA. It was suggested that the generation of NH₃ had taken place in the process of reducing HA along with Fe(II) oxidation. Fe(CN)₆³⁻ was less reactive than free Fe(III) and Fe(EDTA)⁻.

The ability of masking Fe(III) was estimated for CyDTA. The HA including CyDTA had no exothermic peak; however, there was an endothermic peak of the heat flow at Fe(III) injection. CyDTA was found to have the ability to inhibit a violent exothermic reaction of HA.     

安全伦理初探

揭示了安全伦理现象,分析了安全伦理关系,提出了构建安全伦理科学的新观点。