某石化企业粉体料仓爆燃事故原因分析

本文以某企业HDPE料仓的一次爆燃事故为案例,通过分析事故的成因,提供了调查料仓事故的思路及整改方案的确定方法.     

异构环保信息资源整合及归档系统的开发与应用

随着环保信息资源的不断丰富,不同应用系统生成的各种异构数据日益增多,信息孤岛现象十分严重。异构环保信息资源整合及归档系统将分散的信息系统进行有效整合,在异构平台上实现了信息收集、流转及共享利用,全面提升了环保档案的信息化建设水平,为新时期下环保档案信息管理工作提供了一条新途径。     

Introducing a multi-variate classification method: Risky driving acceptance among different heterogeneous driver sub-cultures

Introduction: Heterogeneous driving populations with many different origins are likely to have various sub-cultures that comprise of drivers with shared driver characteristics, most likely with dissimilar traffic safety cultures. An innovative methodology in traffic safety research is introduced which is beneficial for large datasets with multiple variables, making it useful for the multi-variate classification of drivers, driving attitudes and/or (risky) driving behaviours. Method: With the application of multidimensional scaling analysis (MDS), this study explores traffic safety culture in the State of Qatar using a questionnaire and investigates the similarity patterns between the questionnaire items, aiming to classify attitudes towards risky driving behaviours into themes. MDS is subsequently applied to classify drivers within a heterogeneous driving sample into sub-cultures with shared driver characteristics and different risky driving attitudes. Results: Results show that acceptance of speeding is highest among the young Arabic students and acceptance of distraction and drivers’ negligence such as phone use and not wearing a seatbelt is highest among male Arab drivers. Acceptance of extreme risk-taking like intoxicated driving and red-light running is highest among South-Asian business drivers. Conclusion: It is important and practical to understand risky behavioural habits among sub-cultures and thereby focussing on groups of drivers instead of individuals, because groups are easier to approach and drivers within sub-cultures are found to influence each other. By indicating which groups of drivers are most likely to perform specific risky driving themes, it is possible to target these groups and effectively emphasise certain subsets of risky driving behaviours during training or traffic safety education. Practical Applications: This study provides guidance for the improvement of driver education and targeted traffic safety awareness campaigns, intending to make changes to attitudes and habits within specific driver sub-cultures with the aim to improve traffic safety on the longer term.     

The chemical exploitation of nickel phytoextraction: An environmental, ecologic and economic opportunity for New Caledonia

Herein, we explore the outlines of an innovative method based on the chemical recovery of metal-rich biomass produced in phytoextraction technologies. Taking advantage of the adaptive capacity of some New Caledonian plants to hyperaccumulate Ni²⁺ cations in their aerial parts, this technique is based on the direct use of metals derived from plants as “Lewis acid” catalysts in organic chemistry. Metallic cations contained in New Caledonian nickel hyperaccumulators are recovered through a simple cost-effective process and serve the preparation of heterogeneous catalysts used in synthetic transformations allowing access to molecules with high added-value. The design of all processes is in line with the principles of green chemistry; it is adapted to the new economic constraints; it offers a new relevant outlet for metal-rich biomass; and it represents an alternative to non-renewable mineral materials.     

Non-Fickian dispersion in a single fracture

Solute transport in fractured rocks is of major interest in many applications, from the petroleum industry to ground water management. This work focuses on the dispersion process in a transparent replica of a real single fracture. The fracture exhibits strong changes in heterogeneity, with the first half very heterogeneous and the second half fairly homogeneous. Three models have been used to interpret the tracer experiments: the classical advection-dispersion equation (ADE), the continuous time random walk (CTRW), and the stratified model. The main goals were to test these models and to study possible correlations between fitting parameters and heterogeneities. As expected, the solution derived from the ADE equation appears to be unable to model long-time tailing behavior. On the other hand, the results confirm the CTRW robustness and the coefficient beta seems well correlated to heterogeneities. Finally, the stratified model is also able to describe non-Fickian dispersion. The parameters defined by this model are correlated to the heterogeneities of the fracture.     

矿井瓦斯煤尘爆炸传播数值模拟研究

基于连续相、燃烧、颗粒相数理方程建立瓦斯煤尘爆炸传播数理模型,并应用连续相、颗粒相计算方法,依据大型巷道瓦斯爆炸、瓦斯煤尘爆炸传播实验数据,借助普遍应用的流场模拟平台,成功开发瓦斯、煤尘爆炸数值模拟系统。该系统可有效地模拟煤矿瓦斯、煤尘的爆炸事故过程,对瓦斯爆炸的爆燃转爆轰、煤尘是否参与爆炸、爆炸冲击传播速度、衰减规律以及爆炸灾害的波及范围都能进行较准确的模拟。     

大气中有机胺类物质反应机理和消除过程研究

综述大气中有机胺可能的来源、健康危害及其在大气中的均相和非均相化学转化机制,阐述有机胺的反应产物对二次有机气溶胶及其对大气气溶胶的物理和化学性质的改变,此类改变增强大气气溶胶间接气候效应(如成云结核能力等)。大气中的有机胺主要通过与大气氧化剂的反应和非均相反应过程的溶解或置换进入颗粒相,而后随着湿沉降(如云滴、雾滴、雨滴等)到达地面或海面。     

几种碳氢燃料与空气混合物相对爆轰敏感度的测定

利用矩形激波管测定了几种碳氢燃料（丁烷，石脑油，ＪＣ５，戊烯，已烯）直接起爆时形成爆轰所需的临界起爆能，并以化学当量比的乙炔氧气混合物直接起爆形成爆轰的临界起爆能为基准，定义了一个无量纲常数Ｄｈ。再利用这个常数，比较了这几种燃料的相对爆轰敏感度。     

Deflagration to detonation transition in a vapour cloud explosion in open but congested space: Large scale test

The paper reviews large scale experiments with various fuels in air where successful deflagration to detonation transition (DDT) took place. This includes a recent experiment disclosed in the Buncefield R&D program, where DDT developed in the propane/air mixture. The DDT occurred in branches of deciduous trees in a premixed stagnant mixture. An internal R&D investigation programme was initiated to better understand the phenomena. A large scale experiment in an open space with ethane air mixture is presented in the paper. The premixed mixture was ignited at the edge of the congested three-dimensional rigs which consisted of vertical and horizontal pipes. After ignition, the flame accelerated in the congestion and transitioned to detonation at the end of congestion. Stable detonation propagated through the remaining open and uncongested space.The flame acceleration process leading to DDT is scale dependent. It also depends on many parameters leading to a large investigation array and, significant cost. However, such R&D efforts aimed toward a safer plant design, i.e. the prevention of occurrence of a major accident, are a small fraction of a real accident cost.