Fractionation of Cu, Pb and Zn in certified reference soils SRM 2710 and SRM 2711 using the optimized BCR sequential extraction procedure

Sequential extraction of metals from solid media is a common analytical tool used in environmental and exploration geochemistry. A number of procedures exist, but without harmonization and standardization, meaningful comparisons are tenuous without baseline data. A newly developed, standardized sequential extraction procedure (optimized BCR) was applied to two contaminated certified reference soils from Montana, US (SRM 2710 and SRM 2711) for Cu, Pb and Zn. Four operationally defined fractions were isolated, acid extractable, reducible, oxidizable, and residual (by aqua regia). Fraction-specific concentrations, percentages and recoveries for Cu, Pb and Zn were used to explore differences between the optimized BCR procedure and three other sequential extraction schemes with published data for SRM 2710 and 2711 (i.e. Tessier scheme, Geological Survey of Canada scheme and the original BCR scheme). Results indicate significant differences between the four schemes, even for schemes that are closely associated (i.e. the original and optimized BCR schemes). Order-of-magnitude fraction-specific concentration differences were observed, especially for Pb in the reducible fraction. Differences between schemes are worrisome because trends varied between metals, between fractions and between reference soils. These data reinforce the need for increased adoption of standardized sequential extraction procedures and further examination of different solid media.     

新排污收费制度

排污收费制度是环境保护的一项有效的经济手段,2003年7月1日,我国开始实施新的排污收费制度。本文对新排污收费制度在排污费收费标准、排污费征收管理和排污费使用管理三方面的改革进行了较为深入的分析。     

论嵌套制——一种安全生产管理的新方法

笔者所论述的嵌套制 ,是继现有 5种工厂管理运行机制之后的第 6种机制。通过阐述嵌套制的特征、原理、实例、理论与现有的 5种机制的区别 ,证明它是一种有效的工厂安全生产管理机制。推行嵌套制 ,对于追求更切合危险源点的潜在性与复杂性的控制方案 ,对于解决职业健康安全管理体系的路径与工厂其他各种管理途径接轨的问题 ,对于提升职业健康安全管理体系的实用性 ,对于催生具有实质效果的各级、各层次安全监督管理机制 ,对于促进安全生产管理理论的发展 ,都具有重要的作用。     

Village-scale reserves in the forest frontier regions of Chenes and Calakmul,Mexico

ABSTRACT

Sketch-map-facilitated interviews were conducted in 23 villages in two adjacent regions in the southern Yucatan Peninsula of Mexico – the Maya (and increasingly Mennonite) forest-agriculture mosaic of the Chenes, and the late-20^th-century-settlement forest frontier of Calakmul – to determine the frequency and typology of local-scale reserves, including the external (e.g. Payments for Environmental Services programs) and internal sources of their generation. 9% of the study communities are found to satisfy the author’s criteria for deliberate, autochthonous reserves. The static polygon reserve and static map are found to have limited value for understanding the evolving cultural ecologies of these regions. Alternative approaches are discussed, particularly those employed by geographers.     

Cost‐effectiveness of conservation payment schemes for species with different range sizes

Payments to compensate landowners for carrying out costly land‐use measures that benefit endangered biodiversity have become an important policy instrument. When designing such payments, it is important to take into account that spatially connected habitats are more valuable for many species than isolated ones. One way to incentivize provision of connected habitats is to offer landowners an agglomeration bonus, that is, a bonus on top of payments they are receiving to conserve land if the land is spatially connected. Researchers have compared the cost‐effectiveness of the agglomeration bonus with 2 alternatives: an all‐or‐nothing, agglomeration payment, where landowners receive a payment only if the conserved land parcels have a certain level of spatial connectivity, and a spatially homogeneous payment, where landowners receive a payment for conserved land parcels irrespective of their location. Their results show the agglomeration bonus is rarely the most cost‐effective option, and when it is, it is only slightly better than one of the alternatives. This suggests that the agglomeration bonus should not be given priority as a policy design option. However, this finding is based on consideration of only 1 species. We examined whether the same applied to 2 species, one for which the homogeneous payment is best and the other for which the agglomeration payment is most cost‐effective. We modified a published conceptual model so that we were able to assess the cost‐effectiveness of payment schemes for 2 species and applied it to a grassland bird and a grassland butterfly in Germany that require the same habitat but have different spatial‐connectivity needs. When conserving both species, the agglomeration bonus was more cost‐effective than the agglomeration and the homogeneous payment; thus, we showed that as a policy the agglomeration bonus is a useful conservation‐payment option.     

构建广西生态补偿机制对策探析

广西构建生态补偿机制仍存在相关法制不健全,现行财税政策不完善,缺乏相应的技术支持、良性的投融资机制,以及管理体制存在缺陷等方面问题。从加强宣传和提高意识,建立和完善生态补偿法律法规,完善税收收费制度、投融资机制以及管理体制,并努力建立绿色国民经济核算体系和政绩考核制度,积极开展基础研究和试点工作等方面探索构建广西生态补偿机制的措施与对策。     

县域尺度下生态补偿机制构建初探——以桐庐县为例

为了保护水源区生态环境和推进区域经济社会的可持续发展,需要建立和完善生态补偿制度。在评价桐庐县现有生态补偿现状的基础上,整合优化财政补助结构,提出了建立生态补偿专项资金,各乡镇的生态补偿资金分配与地区对县域生态环境贡献率、交界断面水质考核和资金使用绩效挂钩的生态补偿制度。     

Result-oriented approaches to the management of drinking water catchments in agricultural landscapes

Management of water quality in drinking water catchments is of ongoing, high importance as nitrate concentrations are often still very high. We analysed the Augsburg catchment in Germany, a unique example where a result-oriented approach has been implemented. We investigated the historical evolution of the water protection programme, the result-oriented payment contracts with farmers, and farmer satisfaction with the contracts, based on interviews with the water utility and farmers as well as an analysis of the literature. Today, the water protection programme has been successfully implemented, and a significant reduction of nitrate concentration was achieved due to the following factors: (1) investment of non-negligible amounts of money for high compensation and remuneration payments, (2) different contract options, (3) farmers’ participation in the negotiation process for result-oriented payment contracts, (4) involvement of “outside” people and institutions in negotiation processes, (5) anticipation of starting a programme when nitrate levels were still far below legislative thresholds, and (6) a political and legislative framework allowing direct decisions by a water supplier.     

Forest Protection and Reforestation in Costa Rica: Evaluation of a Clean Development Mechanism Prototype

/ Costa Rica has recently established a program that provides funds for reforestation and forest protection on private lands, partly through the sale of carbon certificates to industrialized countries. Countries purchasing these carbon offsets hope one day to receive credit against their own commitments to limit emissions of greenhouse gases. Costa Rica has used the proceeds of the sale of carbon offsets to Norway to help finance this forest incentive program, called the Private Forestry Project, which pays thousands of participants to reforest or protect forest on their lands. The Private Forestry Project is accompanied by a monitoring program conducted by Costa Rican forest engineers that seeks to determine net carbon storage accomplished on these lands each year. The Private Forestry Project, which is officially registered as an Activity Implemented Jointly, is a possible model for bundled projects funded by the Clean Development Mechanism (CDM) established by the 1997 Kyoto Protocol to the UN Framework Convention on Climate Change. It also serves as an interesting example for the CDM because it was designed by a developing country host-not by an industrialized country investor. Accordingly, it reflects the particular "sustainable development" objectives of the host country or at least the host planners. Early experience in implementing the Private Forestry Project is evaluated in light of the main objectives of the CDM and its precursor-Activities Implemented Jointly. It is concluded that the project appears to meet the criteria of global cost-effectiveness and financing from non-ODA sources. The sustainable development implications of the project are specific to the region and would not necessarily match the ideals of all investing and developing countries. The project may be seen to achieve additional greenhouse gas abatement when compared against some (although not all) baselines.     

Concentration and chemical speciation for the determination of Cu,Zn, Ni,Pb and Cd from refuse dump soils using the optimized BCR sequential extraction procedure

The optimized BCR sequential extraction procedure (proposed by the Standards, Measurements and Testing Programme (SM&T) of the European Union) was applied to seven topsoil samples from refuse dump sites for the determination of Cu, Zn, Ni, Pb and Cd. The metals were partitioned into four operationally defined chemical fractions: acid extractable, reducible, oxidizable and residual, and analysed using flame atomic absorption spectrophotometry, FAAS. The results were compared with total metal concentrations obtained using HNO₃, HClO₄ and HF digestion procedures. Results for total metal analysis ranged from - 15.55 to 43.45 for Cu, 37.15 to 222.35 for Zn, 5.15 to 12.10 for Ni, 10.30 to 93.05 for Pb and 0.35 to 3.75 for Cd in μgg⁻¹ dry weight. The results of the partitioning study showed that zinc prevailed in the more soluble fractions and was distributed between the acid-extractable (32.4%) and the reducible (40.3%) fractions, whereas Pb was distributed mainly in the reducible fraction. Copper and nickel were predominantly associated with the reducible and residual fractions - 53.4, 33.3 and 51.1, 24.1% respectively. The ranking of the four fractions for the partitioning of cadmium was: reducible > residual > oxidizable > acid extractable. The percentage recovery for all metals when comparing total metal concentration with the fractional sum of the optimized BCR procedure, were of the order: Zn(93%) > Pb(83%) > Cu(78) > Cd > (68%) > Ni(63%).