某简易垃圾填埋场渗滤液在场底天然土层迁移模拟与长期预测

为了解我国早期建设的简易填埋堆场底部天然土层中污染物迁移状况,作者以安徽某填埋场为例,在前期现场勘查、取样和室内测试工作基础上建立了三维有限元分析模型,对宏量有机污染物COD在土层中的迁移状况进行了模拟分析.通过拟合求参获得COD在该场底土层中扩散系数、机械弥散系数和阻滞因子等运移参数的合理取值,在此基础上开展了污染物...     

Accumulation and quantitative estimates of airborne lead for a wild plant (Aster subulatus)

Foliar uptake of airborne lead is one of the pathways for Pb accumulation in plant organs. However, the approximate contributions of airborne Pb to plant organs are still unclear. In the present study, aerosols (nine-stage size-segregated aerosols and total suspended particulates), a wild plant species (Aster subulatus) and the corresponding soils were collected and Pb contents and isotopic ratios in these samples were analyzed. Average concentration of Pb was 96.5 ± 63.5 ng m⁻³ in total suspended particulates (TSP) and 20.4 ± 5.5 ng m⁻³ in the fine fractions of size-segregated aerosols (SSA) (<2.1 μm), higher than that in the coarser fractions (>2.1 μm) (6.38 ± 3.71 ng m⁻³). Enrichment factors show that aerosols and soils suffered from anthropogenic inputs and the fine fractions of the size-segregated aerosols enriched more Pb than the coarse fractions. The order of Pb contents in A. subulatus was roots > leaves > stems. The linear relationship of Pb isotope ratios (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) among soil, plant and aerosol samples were found. Based on the simple binary Pb isotopic model using the mean ²⁰⁶Pb/²⁰⁷Pb ratios in TSP and in SSA, the approximate contributions of airborne Pb into plant leaves were 72.2% and 65.1%, respectively, suggesting that airborne Pb is the most important source for the Pb accumulation in leaves. So the combination of Pb isotope tracing and the simple binary Pb isotope model can assess the contribution of airborne Pb into plant leaves and may be of interest for risk assessment of the exposure to airborne Pb contamination.     

A COMPARISON OF STATISTICAL TESTS ON THE EXTREME-VALUE TYPE-1 DISTRIBUTION1

ABSTRACT: The effects of the selections of plotting position formulae and class division schemes on goodness of fit tests are investigated for the extreme-value type-1 distribution using annual flood and annual maximum daily rainfall data. It was found that the plotting position formulae have a minor influence on the tests which involve their use, while the class division schemes may have a pronounced effect on the X²-test. The study also recommended the maximum likelihood method for fitting purposes and a new test which is independent of the afore-mentioned selections for judging the goodness of fit.     

火灾下匀质防火保护钢构件温度计算(Ⅰ):理论与公式

介绍了火灾下有匀质防火层保护的钢构件温度计算的一维传热模型。给出了求解该模型的相关边界条件和假定,并给出求解该一维传热模型在不同边界条件下的解。通过分析三种典型防火材料保护下、截面系数不同的三种截面的升温,比较了由我国规范CECS200、欧洲规范、欧钢协标准、美国规范及其他学者推荐的方法得到的结果,并对照有限元结果,考察了不同计算方法的有效性。结果表明,CECS200与国外规范给出的结果符合良好且略微偏高。通过计算典型截面在不同耐火极限要求下的最小保护层厚度,比较了各国规范的设计结果。结果显示,由不同规范推荐的公式计算得到的最小保护层厚度相差不大。CECS200计算的最小保护层厚度与国外规范一致,与欧洲规范得到的结果基本相同。研究表明,在标准火灾环境中我国规范给出的方法合理有效且形式简单便于工程运用。     

Toxic Effects of Crude Oil Combined with Oil Cleaner Simple Green on Yolk-sac Larvae and Adult Rainbow Trout Oncorhynchus mykiss (4 pp)

Background, Goal and Scope Cleaner CRYSTAL Simple Green (SG) was used for the cleanup of the oil spill in the Baltic Sea near Lithuania in 2001. No scientific data are available on the effects and consequences of its application for local aquatic life. The aim of this study was to determine and compare sublethal effects of a) solution SG; b) crude oil alone; c) SG in combination with oil on rainbow trout Oncorhynchus mykiss at different stages of its development in laboratory conditions.Methods Laboratory studies were performed on adult rainbow trout (4-day duration) and on yolk-sac larvae (25-day duration) evaluating their biological parameters. Concentrations of water-soluble and thin-dispersed fractions of petroleum hydrocarbons were measured using gas chromatography.Results and Discussion SG solution (0.5 mg/l) did not affect the survival of larvae and adult fish, and no significant changes were determined in respiratory parameters of the exposed larvae and adult fish. The most expressed alterations were found in morphological parameters (a decrease in the average body mass) of larvae and in haematological indices (a decrease in the leukocyte count) of adult fish at the end of the tests. Crude oil (1610 mg/l) did not affect the survival of adult fish during the 4-day exposure. An increase in larvae mortality rate (~ 36%) was recorded at the end of the tests. A significant decrease in the average body mass and heart rate of larvae as well as in gill ventilation frequency of larvae and adult fish were determined. SG combined with oil induced an increase in larval mortality &#61566; 46% of individuals died at the end of the tests. No mortality was recorded in adult fish. The average body mass and heart rate of larvae were significantly decreased. Marked changes were also found in respiratory parameters (gill ventilation frequency of larvae and adult fish significantly decreased, while “coughing” rate increased). A 1-day, 2-day exposure of fish to SG combined with oil induced a significant decrease in the leukocyte count of adult fish, which was also determined at the end of the tests. The augmentation of adverse impact could be explained by the data obtained from our studies. When SG was added into dilution water with crude oil the concentration of petroleum hydrocarbons in the mixture increased 3 ~ 4.5 times after 24 h and 96 h, respectively. Conclusions The comparative study of the effects of crude oil alone, SG and SG combined with oil showed that their toxic effects on fish differed. Oil combined with SG was found to be more toxic to fish (larvae and adults) than SG alone and oil alone. Fish at early stages of development (yolk-sac larvae) were more sensitive to the effects of the compounds studied than adults.Recommendations and Outlook To diminish the negative impact of oil spill cleanup using chemicals on aquatic ecosystems, it is recommended to carry out more comprehensive studies of their effects and after-effects in laboratory conditions using a wide scale of local aquatic organisms. The selected species of the most sensitive aquatic organisms should include those which are unable to escape the impact of combined action of oil and cleaners. Special attention should be directed to the research of effects of these pollutants on studied organisms at their most sensitive stages of life (reproduction, hatching, early stages of development), as after-effects of exposure to pollutants may be observed in future generations.     

BLEVE: Safety distances estimation by simple models based on the Jakob number

One of the most important points in the design of inherently safe processes is to estimate reliable distances among process units at preliminary stages of the plant project to minimize losses and damages caused by the potential occurrence of technological accidents. Therefore, in this paper the achievement of simple, general, dimensionless and reliable equations (Simple Dimensionless Models SDMs) for the direct estimation of safety distances considering the occurrence of BLEVE (Boiling Liquid Expanding Vapour Explosion) event, is proposed. The developed models directly relate safety distances with critical design/operation variables (involved substance, vessel volume, target vulnerability and explosion temperature), which are easily accessible at early stages of the plant project. SDMs are achieved by analysing the influence of these simple variables on the safety distances, which are estimated using a selected rigorous model (Reference Model R_fM). This task is simplified by the incorporation of the Jakob Number as an input variable, allowing to obtain dimensionless models and simultaneously an adequate representation of the explosion conditions and the involved substances. As result, the achieved SDMs demonstrate a particularly good fit with respect to the R_fM estimations and, at the same time, reliability and versatility. As it is shown in the analysed study cases (involving critical decision variables for the process design and the system safety), the SDMs prove to be also accurate, general, and easily incorporable into more complex optimization problems (QRA analysis, design of emergency plans, safety distance estimation to minimize the probability of domino effects, optimal layout designs, among others).     

浅层地下水定深取样器的研制

介绍了新型浅层地下水定深取样器的基本结构和工作原理。应用表明,该取样器可准确采集预定深度的水样,且水样可原位直接进入采样瓶,降低交叉污染,减少样品中易挥发组分的损失。     

机动车排放检测运行体系的相关研究

机动车污染物排放标准与其检测方法是相辅相成的，不同的机动车检测方法对应不同的机动车排放污染物限值。该文主要对机动车排放检测运行体系中的怠速和简易工况检测方法进行了对比性研究，并对机动车实施常规检测的年检和监督手段的路检进行了对比分析，从而得出：工况法检测对于尾气排放情况的模拟要优于怠速法检测，并可对NOx进行有效控制，所以建议在有条件的地区，应该尽量实施工况法检测：年检和路检的数据有较大的差异，反映出对在用车的监督不力，今后应加强；高排放车辆的贡献率所占的比例与发达国家相比太小，说明机动车总体控制水平较低。     

使用聚胺脂的锁片成形模设计

介绍了一种使用聚胺脂结构的锁片成形模.对该模具的结构作了详细分析.并介绍了其成形过程及特点.     

Simple removal of dioxins by injecting combustion gas into water

A simple, low-cost method for suppression of dioxins/furans (hereinafter referred to as dioxins) is required because many middle- and, especially, small-scale incinerators have fallen into disuse or have been dismantled because of the high running and system costs of measures for the suppression of dioxins. Therefore, the purpose of the present study was to develop a simple removal method for dioxins from combustion gas and to evaluate the basic removal rate of dioxins. The removal method for suspended matter in a gas mixture (cold model) and dioxins in exhaust gases (hot model) has been investigated by means of gas injection into water, the mechanism of which is that the suspended matter in the gas gathers at the gas–liquid interface. In the cold model, the removal ratio of fine particles (R_P) by gas injection into water was reproduced well by the following equation: R_P (%) = 100 × {1−exp(−0.8 · S_S · t_C)}, where S_S (cm²/cm³) is the specific surface area of bubbles and t_C (s) is the residence time of bubbles in water. The removal ratio of fine particles increased as the product S_s · t_C increased. In a hot model using the exhaust gas from combustion experiments of polyvinyl chloride, the removal ratio of dioxins (R_D) by injecting the exhaust gas into water was estimated by the following equation: R_D (%) = 100 × {1−exp(−0.8 · S_S · t_C · C_D0 ^0.07)}, where C_D0 [ng/cm³ (at standard temperature and pressure)] is the dioxins concentration in the exhaust gas before injection into water. R_D depends greatly on the specific surface area of bubbles and the residence time of the bubbles in water, and only weakly on the dioxins concentration in the exhaust gas. Injection of the exhaust gas into water has been shown to be effective and was evaluated as a simple method for the removal of dioxins from exhaust gas.