Advanced molecular-fingerprinting analysis of dissolved organic sulfur by electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry using optimal spray solvent

Molecular level characterization of dissolved organic sulfur (DOS) by electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR MS) is necessary for further understanding of the role of DOS in the environment. Here, ESI spray solvent, a key parameter for ion production during ESI process, was investigated for its effect on the molecular characterization of DOS by ESI-FTICR MS. 100% MeOH as spray solvent was found for the first time to remarkably enhance the ionization efficiency of the majority of CHOS-molecules in NOM, which facilitated a total of 1473 CHOS-molecular formulas with one sulfur atom to be detected. The number of CHOS-molecular formulas obtained using 100%MeOH as spray solvent increased notably over 740 in comparison with those using 50% MeOH aqueous solution (731) or 50% ACN aqueous solution (653). Moreover, due to the enhancement of ionization efficiency of DOS during ESI processes, the tandem mass spectra of the NOM CHOS-molecules could be easily obtained using 100% MeOH as spray solvent, which were hardly obtained using 50% MeOH aqueous solution as spray solvent. The results of the tandem mass spectra suggested the first discovery of organosulfates or sulfonic acids in Suwannee River NOM sample. A simple method based on 100% MeOH as ESI spray solvent for advanced molecular characterization of DOS by ESI-FTICR MS was proposed and applied, and the results revealed more molecular information of DOS in sea DOM samples.     

托盘式烟气脱硫喷淋塔空塔冷态流场数值模拟

以600MW机组多孔合金托盘喷淋塔为研究对象,利用国际流行的商用CFD(ComputationalFluidDynamics)软件Fluent及其前处理软件Gambit对烟气脱硫立式喷淋空塔的流场进行二维数值模拟。计算中选用模型作为计算模型,用SIMPLE算法进行计算。计算结果表明,喷淋塔的烟气入口角度以及多孔合金托盘的安装高度对塔内流场分布有一定的影响,安装托盘后气速明显均匀化,斜切式烟气进口流场分布较直进式均匀,还获得了合适的托盘安装高度。     

喷雾干燥脱硫法中石灰浆液特性的影响

以模拟实验研究了喷雾干燥脱硫法中吸收剂有效钙含量、粒度、浆液固含量及添加剂等石灰浆液参数对脱硫过程的影响，并作了分析。     

XK—1．5型除尘清洗两用机的研究、试验与应用

采用高压水和喷嘴的引射原理，使水射流通过喷嘴后高效雾化，达到降尘的目的，并主要沉降５μｍ以下对人体具有致命危害的呼吸性粉尘。当更换喷嘴后也可进行积上和物体的表面清洗。     

基于数值模拟的细水雾在汽车涂装车间喷漆室的应用研究

采用FDS软件对细水雾扑救汽车涂装车间喷漆室火灾的灭火效能进行数值模拟分析,着重探讨了喷漆室纵向通风、细水雾雾滴粒径、雾滴喷射速度、汽车障碍物等对扑灭油漆火的影响。模拟结果表明:在细水雾与油漆火的相互作用过程中,细水雾对火源的表面冷却和隔氧窒息作用显著;为了防止室内氧气得到补充,在开启细水雾灭火的同时应当联动控制关闭纵向通风系统;在模拟工况条件下雾滴粒径为100μm~300μm的细水雾灭火效果优于粒径为400μm、500μm的细水雾;雾滴在一定喷射速度范围内速度越大灭火效果越好,喷射速度为10m/s的雾滴灭火效果明显优于3m/s和5m/s的雾滴,但是为了防止火焰横向蔓延,喷射速度不宜过高;在汽车障碍物火灾中部分微小的细水雾雾滴受到火焰的卷吸作用,可以绕过障碍物进入火区发挥冷却作用,细水雾灭火系统能够有效控制障碍物火灾,可以应用于汽车涂装车间喷漆室。     

LY12CZ铝合金腐蚀损伤的概率分布及其变化规律

采用铜加速乙酸盐雾试验方法对LY12CZ铝合金腐蚀行为进行了研究。结果表明：腐蚀深度服从Gumbel分布、正态分布、威布尔分布和对数正态4种分布。选用正态分布描述了LY12CZ铝合金在盐雾环境下的腐蚀损伤的分布特性,并得出了不同置信度和可靠度下腐蚀深度随时间变化的规律。     

高压喷雾及其在煤矿井下粉尘防治中的应用

系统分析了高压喷雾的喷雾参数，雾粒粒度分布，雾粒在雾流中运动的平均速度，雾粒带电及喷咀结构，并将此技术用于煤矿井下采煤机和炮掘工作面，取得了很好的降尘效果。     

Dioxin removal in “energy from waste plants” - comparison of air pollution control methods

The graph below shows the emitted dioxin - equivalents (Eadon) in grams per year in flue gas from municipal solid waste incinerators with various air pollution control methods for plants of capacity of 200 000 ton municipal solid waste (MSW) per year.

Full-size image (15K)

With optimized combustion and an effective air pollution control system the emissions of dioxins can be kept very low (concentrations below 0.1 ng/m³n).

With a very effective air pollution control system the total emission from all Swedish MSW-incinerators burning approximately 1.5 Mton/year will by 1990 be below 2 g/year - a drastic reduction from approximately 15 g today. As the total dioxin - equivalent emission to the environment in Sweden in the year 1987 was almost 500 g we see that municipal waste incineration really is on the way to solve their dioxin problem.     

干式烟气脱硫装置对除尘器性能影响的分析

简单介绍了3种干法脱硫技术:喷雾干燥法、炉内喷钙法、循环流化床脱硫法的工艺流程,分析了3种脱硫系统运行后除尘器入口处粉尘烟气温度、湿度、比电阻、粉尘粒径、粘性等性质改变,分析了在这种粉尘性质的改变下,指出了静电除尘器和布袋除尘器在这种改变下所受影响的不同。     

Life cycle assessment of spray dried soluble coffee and comparison with alternatives (drip filter and capsule espresso)

This paper aims to evaluate the environmental burdens associated with spray dried soluble coffee over its entire life cycle and compare it with drip filter coffee and capsule espresso coffee. It particularly aims to identify critical environmental issues and responsibilities along the whole life cycle chain of spray dried coffee. This life cycle assessment (LCA) specifically uses foreground data obtained directly from coffee manufacturers and suppliers. Aside from energy consumption and greenhouse gases emissions, water footprint is also studied in detail, including regionalization of water impacts based on the ecological scarcity method 2006. Other impact categories are screened using the IMPACT 2002+ impact assessment method.The overall LCA results for a 1 dl cup of spray dried soluble coffee amounts approximately to 1 MJ of primary non-renewable energy consumption, to emissions of 0.07 kg of CO_2-eq, and between 3 and 10 l of non-turbined water use, depending on whether or not the coffee cultivation is irrigated and wet treated. When considering turbined water, use can be up to 400 l of water per cup. Pouch – and to a lesser extent metal can packaging alternatives – show lower environmental burdens than glass or sticks.On average, about one half of the environmental footprint occurs at a life cycle stage under the control of the coffee producer or its suppliers (i.e., during cultivation, treatment, processing, packaging up to distribution, along with advertising) and the other half at a stage controlled by the user (shopping, appliances manufacturing, use and waste disposal). Key environmental parameters of spray dried soluble coffee are the amount of extra water boiled and the efficiency of cup cleaning during use phase, whether the coffee is irrigated or not, as well as the type and amount of fertilizer used in the coffee field. The packaging contributes to 10% of the overall life cycle impacts.Compared to other coffee alternatives, spray dried soluble coffee uses less energy and has a lower environmental footprint than capsule espresso coffee or drip filter coffee, the latter having the highest environmental impacts on a per cup basis. This study shows that a broad LCA approach is needed to help industry to minimize the environmental burdens directly related to their products. Including all processes of the entire system is necessary i) to get a comprehensive environmental footprint of the product system with respect to sustainable production and consumption, ii) to share stakeholders responsibility along the entire product life cycle, and iii) to avoid problem shifting between different life cycle stages.