环境升温过程对常温固化环氧树脂热力学性能的影响

目的提高常温固化环氧树脂体系的高温使用性能。方法采用常温固化剂T31、中温固化剂IPDA以及高温固化剂DDM作为混合固化剂,对E-44型和AG-80型混合环氧树脂体系进行常温固化反应,并分析环境升温过程对固化物热力学性能的影响。通过DMA分析、热变形测量、固化度测试,分别评价室温固化环氧树脂在环境升温过程前后的玻璃化转变温度、热变形量及体系内部的固化反应程度变化,并通过吸水率测试和弯曲强度测试对玻璃纤维布增强常温固化环氧树脂基复合材料的耐湿热性能以及高温条件下的力学性能进行分析。结果环氧树脂常温固化物的tg为85.21℃,经1.5℃/min的平均升温速率加热至90℃之后,该环境升温过程使固化物的固化度增大至92%以上,tg增长为132.06℃的同时热变形温度增大。其复合材料耐湿热性能提高,且100℃时弯曲强度的保持率为65%,对于加热至120℃的环境升温过程,固化物的固化度接近96%,tg增长为144.45℃的同时热变形温度进一步提高,其复合材料耐湿热性能改善程度更加明显,且130℃时弯曲强度保持率仍接近60%。结论常温、中温、高温混合固化剂的合理复配有助于环氧树脂体系在环境升温变化的诱导条件下发生梯度式固化反应,使体系内部的交联固化程度迅速升至较高水平,可以有效提高其玻璃化转变温度,显著改善常温固化环氧树脂体系在高温条件下的热力学性能。     

Air Pollution and Heat Exposure Study in the Workplace in a Glass Manufacturing Unit in India

Air pollution in the workplace environment due to industrial operation have been found to cause serious occupational health hazard. Similarly, heat stress is still most neglected occupational hazard in the tropical and subtropical countries like India. The hot climate augments the heat exposure close to sources like furnaces. In this study an attempt is made to assess air pollution and heat exposure levels to workers in the workplace environment in glass manufacturing unit located in the State of Gujarat, India. Samples for workplace air quality were collected for SPM, SO₂, NO₂ and CO₂ at eight locations. Results of workplace air quality showed 8-hourly average concentrations of SPM: 165–9118 μg/m³, SO₂: 6–9 μg/m³ and NO₂: 5–42 μg/m³, which were below the threshold limit values of workplace environment. The level of CO₂ in workplace air of the plant was found to be in the range 827–2886 μg/m³, which was below TLV but much higher than the normal concentration for CO₂ in the air (585 mg/m³). Indoor heat exposure was studied near the furnace and at various locations in an industrial complex for glass manufacturing. The heat exposure parameters including the air temperature, the wet bulb temperature, and the globe parameters were measured. The Wet Bulb Globe Temperature (WBGT), an indicator of heat, exceeded ACGIH TLVs limits most of the time at all the locations in workplace areas. The recommended duration of work and rest have also been estimated.     

温度对酚试剂分光光度法测定空气中甲醛的影响

GB/T 18204.26《公共场所空气中甲醛测定方法》中的酚试剂分光光度法,其方法原理是空气中甲醛与酚试剂反应生成嗪,嗪在酸性溶液中被高铁离子氧化形成蓝绿色化合物。根据颜色深浅,比色定量。两步反应在室温较低时作用不完全。吸光度随时间延长而逐渐加大。文章经过不同室温实验提出,在室温低于23℃时,两步反应应在恒温水浴43℃保温10min。室温达到23℃时可不必加热。     

方轧件在椭圆孔型中轧制温度场的三维有限元分析

应用MARC/autoforge有限元软件对方轧件在椭圆孔型中的轧制温度场进行了热力耦合模拟.研究了模拟过程中的传热边界条件,分析了轧制前和轧制过程中轧件中温度场的分布和变化规律.模拟计算结果和实验结果的比较说明二者基本是相符的.     

中─高级变质相中水热流体的形成与作用

固体地壳中流体是普遍存在的，中—高级变质相中的矿物并非只发生晶体塑性变形，溶解和溶移作用在非糜棱岩化岩石中占主导地位，因为高温高压环境下存在的水热流体，在变质变形作用中起着至关重要的作用。在周围分布有网络状进进剪切带的递进缩短带中，与应交梯度有直接关系的单个矿物的位错密度梯度在其晶体边缘形成，产生了化学位梯度，从而使矿物边缘发生溶解。变形分解作用是产生这一过程的动力，并为流体汇聚形成水热循环系统提供了空间。     

利用pH值梯度研究建筑砂浆的酸蚀程度

在两种不同ｐＨ值模拟酸雨和３种浸泡时间条件下，据ｐＨ值梯度测定了各类保护剂处理建筑砂浆试件的酸化层厚度，从而判定保护剂的保护效果，了解酸蚀程度。并分析了影响酸化层厚度的因素。     

磁分离技术在我国废水处理中的研究进展

本文介绍了磁分离技术的基本原理、分离方法和设备，综述了该技术在某些特定废水处理中的应用现状。磁分离技术的实际应用具有分离效率高、分离速度快、选择性好、处理对象广、成本低廉、分离物系的粒度可达到很小，并且不受处理体系的温度、密度、酸碱度限制等优点，可以使某些采用传统分离方法较难或不能分离的物系得以顺利地分离，有较为广泛的应用前景。     

在降雨量极少的条件下日本琵琶湖的环境因子的分布(英文)

琵琶湖是日本第一大淡水湖,20世纪60年代以来,由于经济的发展,湖水水质逐步变坏。1977年湖的北部出现赤潮,1983年湖的南部出现了湖泊富营养化的产物微囊藻。多年来,在深水区湖水温度分层情况下,叶绿素a或浮游植物主要分布在湖的表层(Tezuka,1984)。但在1994年夏季,降雨量极少的情况下,在深水区叶绿素a或浮游植物主要分布在温跃层附近,这种现象在琵琶湖是罕见的(Nakanishi,1995)。最近,琵琶湖北湖的藻类爆发显著增加了溶氧的消耗,导致了湖底层溶氧的减少。如果湖底层溶氧持续减少,底泥储存的磷就会释放到湖水中,从而加快湖泊富营养化的进程。本文分析了琵琶湖南北10个点1994年4月至1995年3月每月1次的常规观测资料,深入剖析了全湖物理化学参数的时空分布,不仅发现叶绿素的峰值在湖水温度分层时出现在温跃层的上部,而且湖底边界层同时出现了低溶氧和高浊度的现象。分析认为绿素a和溶氧、浊度的对应关系表明温跃层是一光合成活跃的区间。     

A reflection on four impactful Ambio papers: The biotic perspective: This article belongs to Ambio’s 50th Anniversary Collection. Theme: Climate change impacts

Climate change represents one of the most pressing societal and scientific challenges of our time. While much of the current research on climate change focuses on future prediction, some of the strongest signals of warming can already be seen in Arctic and alpine areas, where temperatures are rising faster than the global average, and in the oceans, where the combination of rising temperatures and acidification due to increased CO₂ concentrations has had catastrophic consequences for sensitive marine organisms inhabiting coral reefs. The scientific papers highlighted as part of this anniversary issue represent some of the most impactful advances in our understanding of the consequences of anthropogenic climate change. Here, we reflect on the legacy of these papers from the biotic perspective.