全文获取类型
收费全文 | 732篇 |
免费 | 69篇 |
国内免费 | 158篇 |
专业分类
安全科学 | 238篇 |
废物处理 | 43篇 |
环保管理 | 72篇 |
综合类 | 332篇 |
基础理论 | 100篇 |
污染及防治 | 66篇 |
评价与监测 | 31篇 |
社会与环境 | 67篇 |
灾害及防治 | 10篇 |
出版年
2024年 | 4篇 |
2023年 | 24篇 |
2022年 | 29篇 |
2021年 | 51篇 |
2020年 | 44篇 |
2019年 | 33篇 |
2018年 | 23篇 |
2017年 | 23篇 |
2016年 | 31篇 |
2015年 | 50篇 |
2014年 | 43篇 |
2013年 | 79篇 |
2012年 | 62篇 |
2011年 | 70篇 |
2010年 | 34篇 |
2009年 | 36篇 |
2008年 | 39篇 |
2007年 | 44篇 |
2006年 | 40篇 |
2005年 | 15篇 |
2004年 | 15篇 |
2003年 | 23篇 |
2002年 | 21篇 |
2001年 | 16篇 |
2000年 | 19篇 |
1999年 | 22篇 |
1998年 | 17篇 |
1997年 | 14篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 5篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1971年 | 2篇 |
1970年 | 1篇 |
排序方式: 共有959条查询结果,搜索用时 203 毫秒
1.
Matthew Bates Paolo Bruno Mariangela Caputi Maurizio Caselli Gianluigi de Gennaro Maria Tutino 《Atmospheric environment (Oxford, England : 1994)》2008,42(24):6144-6151
The technique of thermal desorption (TD)–GC/MS was evaluated for measuring airborne, 4–6 ring polycyclic aromatic hydrocarbons (PAHs) collected onto quartz filters. TD provides a more readily automated and sensitive alternative to traditional solvent extraction, decreasing the time/cost of analysis and reducing the risk of analyte loss or sample contamination. The developed method was successfully applied to the analysis of PAH standard solutions loaded on sorbent tubes packed with quartz wool and the graphitized carbon black sorbent Carbograph2. The optimized method showed high desorption efficiency over the whole range of target PAHs with good precision, linearity and sensitivity. The proposed method was verified on an urban dust Standard Reference Material (SRM 1649a); the experimentally determined concentrations agreed with the certified ranges (95% confidence limit) for all target compounds except benzo[a]anthracene, which fell just outside the narrow certified range. The desorption efficiency and the reproducibility of the method was evaluated by analysing pieces of real sample filters sampled from urban air for a period of 24 h. The results confirmed the homogeneity of the filter and showed high recovery efficiencies for all target PAHs. 相似文献
2.
The performance of Ce-OMS-2 catalysts was improved by tuning the fill percentage in the hydrothermal synthesis process to increase the oxygen vacancy density. The Ce-OMS-2 samples were prepared with different fill percentages by means of a hydrothermal approach (i.e. 80%, 70%, 50% and 30%). Ce-OMS-2 with 80% fill percentage (Ce-OMS-2-80%) showed ozone conversion of 97%, and a lifetime experiment carried out for more than 20?days showed that the activity of the catalyst still remained satisfactorily high (91%). For Ce-OMS-2-80%, Mn ions in the framework as well as K ions in the tunnel sites were replaced by Ce4+, while for the others only Mn ions were replaced. O2-TPD and H2-TPR measurements proved that the Ce-OMS-2-80% catalyst possessed the greatest number of mobile surface oxygen species. XPS and XAFS showed that increasing the fill percentage can reduce the AOS of Mn and augment the amount of oxygen vacancies. The active sites, which accelerate the elimination of O3, can be enriched by increasing the oxygen vacancies. These findings indicate that increasing ozone removal can be achieved by tuning the fill percentage in the hydrothermal synthesis process. 相似文献
3.
Agata Gallipoli Camilla M. Bragugli Andrea Gianico Daniele Montecchio Pamela Pagliaccia 《环境科学学报(英文版)》2020,32(3):167-179
Biowaste valorization through anaerobic digestion is an attractive option to achieve both climate protection goals and renewable energy production. In this paper, a complete set of batch trials was carried out on kitchen waste to investigate the effects of mild thermal pretreatment, temperature regimen and substrate/inoculum ratio. Thermal pretreatment was effective in the solubilisation of macromolecular fractions, particularly carbohydrates. The ability of the theoretical methodologies in estimating hydrogen and methane yields of complex substrates was evaluated by comparing the experimental results with the theoretical values. Despite the single batch configuration, a significant initial hydrogen production was observed, prior to methane yield. Main pretreatment effect was the gain in hydrogen production; the extent was highly variable according to the other parameters values. High hydrogen yields, up to 113 mL H2/g VSfed, were related to the prompt transformation of soluble sugars. Thermophilic regimen resulted, as expected, in faster digestions (up to 78 mL CH4/gVS/day) and sorted out pH inhibition. The relatively low methane yields (342–398 mL CH4/g VSfed) were the result of the consistent lignocellulosic content and low lipid content. Thermal pretreatment proved to be a promising option for the enhancement of hydrogen production in food waste dark fermentation. 相似文献
4.
5.
B. Beck-Friis M. Pell U. Sonesson H. Jönsson H. Kirchmann 《Environmental monitoring and assessment》2000,62(3):317-331
Composting can be a source of N2O andCH4 production. In this investigation, differentcompost heaps of organic household waste weremonitored with the focus on potential formation ofCH4 and N2O in the heaps and emission ofthese gases from the heaps. The studied compost heapshad different compost ages, turning intervals andcompost sizes. The analysed compost gases containedbetween 1–3421 L of N2O-N L-1 and 0–470 mL of CH4 L-1. The emission rates ofN2O and CH4 from the compost heaps werebetween 1–1464 mg N2O m-2 day-1 and0–119 000 mg CH4 m-2 day-1. These verylarge differences in compost gas composition andemission indicate the importance of compostmanagement. The results also give an understanding ofwhere in the composting process an increasing emissionof N2O and CH4 can occur. 相似文献
6.
A. Haurie J.J.E. Kübler A. Clappier H. van den Bergh 《Environmental Modeling and Assessment》2004,9(1):1-12
A method is proposed to build integrated models (also called Metamodels) aimed at quantifying the economic efficiency of air quality policies. This Metamodeling approach is based on the coupling of two complementary models, that operate at different scales in space and time, and which represent the economic and the physical and chemical processes, respectively. The joint consideration of the physico-chemical and techno-economic structure of the pollution control problems permits a comprehensive evaluation of air pollution abatement strategies. The motivating pollution control problems include urban-regional air quality management through efficient energy and traffic control policies. A pilot study, exploiting data collected in the Geneva canton (Switzerland), is used to demonstrate the potential of the approach. 相似文献
7.
8.
根据铝型材挤压模具的服役条件,采用宏观与微观相结合的分析方法,分析现场挤压模具的失效形式、失效性质和失效原因,并提出了提高模具使用寿命的一些措施. 相似文献
9.
热解析气相色谱法测定土壤中苯系物 总被引:1,自引:0,他引:1
建立了用热解析气相色谱法测定土壤中苯系物的方法.采用保留时间定性,外标法定量.方法检出限分别为:苯1.8 μg·L-1、甲苯3.5 μg·L-1、乙苯7.0 μg·L-1、间二甲苯8.6 μg·L-1、对二甲苯8.6 μg·L-1、邻二甲苯9.8 μg·L-1、苯乙烯10.0 μg·L-1;加标回收率在79%~100%之间,相对标准偏差为1.5%~3.9%.方法操作简便,快速,灵敏度高,能适应现代化的应急监测. 相似文献
10.
城市污水厂污泥热干燥处理技术及其应用分析 总被引:26,自引:0,他引:26
提出采用热干燥处理技术进一步降低脱水泥饼的含水率,介绍了现行的污泥热干燥处理技术,并就该技术在污泥处理中的应用尤其是在焚烧预处理中的应用进行了分析。 相似文献