防灾预案研究

本文提出了防御灾害预案的五要素和逻辑结构,进而讨论了防灾预案的优化准则、制定程序等问题。     

Density functional theory (DFT) studies of vanadium-titanium based selective catalytic reduction (SCR) catalysts

Based on density functional theory (DFT) and basic structure models, the chemical reactions on the surface of vanadium-titanium based selective catalytic reduction (SCR) denitrification catalysts were summarized. Reasonable structural models (non-periodic and periodic structural models) are the basis of density functional calculations. A periodic structure model was more appropriate to represent the catalyst surface, and its theoretical calculation results were more comparable with the experimental results than a non-periodic model. It is generally believed that the SCR mechanism where NH₃ and NO react to produce N₂ and H₂O follows an Eley-Rideal type mechanism. NH₂NO was found to be an important intermediate in the SCR reaction, with multiple production routes. Simultaneously, the effects of H₂O, SO₂ and metal on SCR catalysts were also summarized.     

Air Pollution and Heat Exposure Study in the Workplace in a Glass Manufacturing Unit in India

Air pollution in the workplace environment due to industrial operation have been found to cause serious occupational health hazard. Similarly, heat stress is still most neglected occupational hazard in the tropical and subtropical countries like India. The hot climate augments the heat exposure close to sources like furnaces. In this study an attempt is made to assess air pollution and heat exposure levels to workers in the workplace environment in glass manufacturing unit located in the State of Gujarat, India. Samples for workplace air quality were collected for SPM, SO₂, NO₂ and CO₂ at eight locations. Results of workplace air quality showed 8-hourly average concentrations of SPM: 165–9118 μg/m³, SO₂: 6–9 μg/m³ and NO₂: 5–42 μg/m³, which were below the threshold limit values of workplace environment. The level of CO₂ in workplace air of the plant was found to be in the range 827–2886 μg/m³, which was below TLV but much higher than the normal concentration for CO₂ in the air (585 mg/m³). Indoor heat exposure was studied near the furnace and at various locations in an industrial complex for glass manufacturing. The heat exposure parameters including the air temperature, the wet bulb temperature, and the globe parameters were measured. The Wet Bulb Globe Temperature (WBGT), an indicator of heat, exceeded ACGIH TLVs limits most of the time at all the locations in workplace areas. The recommended duration of work and rest have also been estimated.     

Molecular behavior and interactions with microbes during anaerobic degradation of bio-derived DOM in waste leachate

It is the key to control bio-derived dissolved organic matters (DOM) in order to reduce the effluent concentration of wastewater treatment, especially for waste leachate with high organic contaminants. In the present study, the anaerobic degradation of aerobically stabilized DOM was investigated with DOM substrate isolated through electrodialysis. The degradation of bio-derived DOM was confirmed by reduction of 15% of total organic carbon in 100 days. We characterized the molecular behavior of bio-derived DOM by coupling molecular and biological information analysis. Venn based Sankey diagram of mass features showed the transformation of bio-derived DOM mass features. Occurrence frequency analysis divided mass features into six categories so as to distinguish the fates of intermediate metabolites and persistent compounds. Reactivity continuum model and machine learning technologies realized the semi-quantitative determination on the kinetics of DOM mass features in the form of pseudo-first order, and confirmed the reduction of inert mass features. Furthermore, network analysis statistically establish relationship between DOM mass features and microbes to identify the active microbes that are able to utilize bio-derived DOM. This work confirmed the biological technology is still effective in controlling recalcitrant bio-derived DOM during wastewater treatment.     

烟气脱硫工艺的选择

论述了现今国内外烟气脱硫的现状及烟气脱硫工艺的分类，国内外较为先进的烟气脱硫工艺的机理及特点，且对不同的脱硫技术的优缺点进行了全面的比较，对需要进行脱硫的装置现状了科学地分析，并最终提出选择合理的脱硫工艺的方法及注意的问题。     

约束求解的数据模型及算法

此文针对参数化造型系统中约束方程组的求解问题,深入分析了匹配求解的核心思想,提出了一种简单实用的约束网络建模方法,并且围绕该数据模型介绍了与其相关的算法.     

湿式高效除尘脱硫装置的试验研究

本文介绍了一种高效除尘脱硫装置──三相流化床的性能和原理，并对三相流化床除尘脱硫工业中试系统的试验结果进行了分析．试验表明三相流化床除尘效率可达９８％，脱硫效率达７０％，运行安全可靠．     

沙尘天气对沈阳市空气质量的影响分析

针对沙尘天气的成因、来源及危害进行综述 ,对沈阳市 2 0 0 2年出现的沙尘天气特点及对空气质量影响进行了分析 ,提出几点防治对策     

湿法烟气脱硫添加剂的试验研究

采用我校自主设计研制的水浴脱硫设备,以石灰石为脱硫剂,通过模拟烟气净化冷态模型试验研究了甲酸,乙酸,已二酸,草酸作为有机添加剂对湿法烟气脱硫的影响,并讨论了其机理.试验结果表明,有机酸添加剂能减缓脱硫液pH值的降低过程,能在较低的pH值时得到较高的脱硫率.实验结果为有机添加剂在湿法脱硫中的应用提供了理论依据.     

煤气洗涤废水的处理研究

本研究对特难处理的煤气洗涤废水，采用混凝──电化学氧化处理，可获得良好的处理效果．其ＣＯＤ、油、酚分别由１０３２２ｍｇ／Ｌ、１５０００ｍｇ／Ｌ、１５７０ｍｇ／Ｌ降至２８９ｍｇ／Ｌ、１００ｍｇ／Ｌ、０．５ｍｇ／Ｌ．去除率分别为９７．２％，９３．３％，９９．９７％．