全文获取类型
收费全文 | 428篇 |
免费 | 68篇 |
国内免费 | 138篇 |
专业分类
安全科学 | 102篇 |
废物处理 | 17篇 |
环保管理 | 39篇 |
综合类 | 266篇 |
基础理论 | 83篇 |
污染及防治 | 40篇 |
评价与监测 | 13篇 |
社会与环境 | 64篇 |
灾害及防治 | 10篇 |
出版年
2024年 | 4篇 |
2023年 | 13篇 |
2022年 | 23篇 |
2021年 | 21篇 |
2020年 | 25篇 |
2019年 | 23篇 |
2018年 | 16篇 |
2017年 | 21篇 |
2016年 | 21篇 |
2015年 | 32篇 |
2014年 | 22篇 |
2013年 | 57篇 |
2012年 | 45篇 |
2011年 | 60篇 |
2010年 | 27篇 |
2009年 | 25篇 |
2008年 | 24篇 |
2007年 | 26篇 |
2006年 | 25篇 |
2005年 | 13篇 |
2004年 | 10篇 |
2003年 | 16篇 |
2002年 | 12篇 |
2001年 | 10篇 |
2000年 | 13篇 |
1999年 | 13篇 |
1998年 | 8篇 |
1997年 | 10篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1991年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1975年 | 1篇 |
1971年 | 2篇 |
1970年 | 1篇 |
排序方式: 共有634条查询结果,搜索用时 46 毫秒
1.
The performance of Ce-OMS-2 catalysts was improved by tuning the fill percentage in the hydrothermal synthesis process to increase the oxygen vacancy density. The Ce-OMS-2 samples were prepared with different fill percentages by means of a hydrothermal approach (i.e. 80%, 70%, 50% and 30%). Ce-OMS-2 with 80% fill percentage (Ce-OMS-2-80%) showed ozone conversion of 97%, and a lifetime experiment carried out for more than 20?days showed that the activity of the catalyst still remained satisfactorily high (91%). For Ce-OMS-2-80%, Mn ions in the framework as well as K ions in the tunnel sites were replaced by Ce4+, while for the others only Mn ions were replaced. O2-TPD and H2-TPR measurements proved that the Ce-OMS-2-80% catalyst possessed the greatest number of mobile surface oxygen species. XPS and XAFS showed that increasing the fill percentage can reduce the AOS of Mn and augment the amount of oxygen vacancies. The active sites, which accelerate the elimination of O3, can be enriched by increasing the oxygen vacancies. These findings indicate that increasing ozone removal can be achieved by tuning the fill percentage in the hydrothermal synthesis process. 相似文献
2.
3.
B. Beck-Friis M. Pell U. Sonesson H. Jönsson H. Kirchmann 《Environmental monitoring and assessment》2000,62(3):317-331
Composting can be a source of N2O andCH4 production. In this investigation, differentcompost heaps of organic household waste weremonitored with the focus on potential formation ofCH4 and N2O in the heaps and emission ofthese gases from the heaps. The studied compost heapshad different compost ages, turning intervals andcompost sizes. The analysed compost gases containedbetween 1–3421 L of N2O-N L-1 and 0–470 mL of CH4 L-1. The emission rates ofN2O and CH4 from the compost heaps werebetween 1–1464 mg N2O m-2 day-1 and0–119 000 mg CH4 m-2 day-1. These verylarge differences in compost gas composition andemission indicate the importance of compostmanagement. The results also give an understanding ofwhere in the composting process an increasing emissionof N2O and CH4 can occur. 相似文献
4.
A. Haurie J.J.E. Kübler A. Clappier H. van den Bergh 《Environmental Modeling and Assessment》2004,9(1):1-12
A method is proposed to build integrated models (also called Metamodels) aimed at quantifying the economic efficiency of air quality policies. This Metamodeling approach is based on the coupling of two complementary models, that operate at different scales in space and time, and which represent the economic and the physical and chemical processes, respectively. The joint consideration of the physico-chemical and techno-economic structure of the pollution control problems permits a comprehensive evaluation of air pollution abatement strategies. The motivating pollution control problems include urban-regional air quality management through efficient energy and traffic control policies. A pilot study, exploiting data collected in the Geneva canton (Switzerland), is used to demonstrate the potential of the approach. 相似文献
5.
6.
The effects of different aluminium chloride concentrations together with varying calciumchloride concentrations on root growth, cell division and nucleoli in root tip cells of Allium cepa werestudied. The concentrations used for aluminium chloride were 10-4, 10-3 and 10-2 mol/L ; and for calcium chloride were 10-5 , 10-4 , 10-3 and 10-2 mol/L, respectively. The results showed that after thetreatments with 10-2 to 10-3 mol/L Al3+ , root growth was severely inhibited , a large nurnber of thecells with c-mitosis were induced and the nucleolar material was extruded from the nucleus into the cytoplasm. However , the treatments with 10-2 to 10-3 mol/L of Al3+ together with 10-2)to 10-5 mol/LCa2+ suggested that Ca2+ gave the obviously protective effects against Al3+ poisoning in root growth.cell division and nucleoli of the root tip cells in A. cepa. The possible mechanism of these protective effects of Ca2+) is also briefly discussed. 相似文献
7.
TiO2膜固载型多孔催化剂的光催化分解试验 总被引:3,自引:0,他引:3
以多孔基质为载体,用溶胶-凝胶法制备出载TiO2薄膜的多孔型光催化剂。用X射线衍射和扫描电镜对催化剂的物相和形貌进行了表征,此催化剂能在光照下分解水溶液中四环素抗菌素。经1h光照,四环素的分解率可达85%左右。 相似文献
8.
Liu Zhengchao Pan Xunxi Dong Wenbo Hou Huiqi Zhang Zhenman Hou Jian Yu Yong Li Changlin 《环境科学学报(英文版)》1997,9(1):95-99
In this paper pulsed corona discharge is shown to be effective for the decomposition of CF3Cl(Freon-13).The pressure of CF3Cl was 2.67×103Pa,after discharged for 2 min,39.5% of CF3Cl was decomposed.The products were mainly CF4,Cl2 and CF2Cl2.The yield increased by adding O2 or air.Under the same conditions,more than 94% decomposition yield was obtained if 5.32×103Pa O2 or air was added.The composition of products became CF2O,Cl2 and CF4.While the partial pressure of O2 or air reached 1 arm,the decomposition yield decreased to 54.5% and 48. 5% respectively. 相似文献
9.
The preparation of immobilizing-catalysts for decomposing ozone by using dipping method was studied. XRD, XPS and TEM were used to characterize the catalysts. The three kinds of catalysts were selected preferentially, and their catalytic activities were investigated. The results showed that the catalyst with activated carbon dipping acetate( active components are Mn:Cu = 3:2, active component proportion in catalyst is 15%, calcination temperature is 200℃ ) has the best catalytic activity for ozone decomposing. One gram of catalyst can decompose 17.6g ozone at initial ozone concentration of 2.5g/m^3 and the residence time in reactor of 0.1s. The experimental results also indicated that humidity of reaction system had negative effect on catalytic activity. 相似文献
10.
Decomposition mass loss and pyrolysis products analyses of particles sampled at various locations along the tailpipe of a Euro-IV diesel engine were performed using a thermogravimetry in conjunction with Fourier transformation infrared spectrometry-mass spectrum. Diesel particles were collected at the same location with and without diesel oxidation catalyst (DOC) mounted on the test engine separately. The three poles in thermal gravity-differential thermal gravity images suggested that the decomposition process of diesel particles could be divided into three stages which correspond to the decompositions of lower boiling substances, higher boiling substances and soot respectively. It is noticed that no matter whether DOC was mounted or not, the further the particles were sampled away from the engine block, the lower the peak temperatures and the heavier the mass losses within the first two stages, which indicated that the soluble organic fraction in the particle samples increased and therefore lowering the activation energy of thermal decomposition. Hydroxyl, ammonia, CxHy fragments, benzene, toluene, and phenol were found to be the primary products of particle decomposition, which didn't change with the location of particle sample point. The employment of DOC increased the activation energy for particle oxidation and resulted in a higher peak temperature and lower mass loss within the first-stage. Moreover, the CO stretching bands of aldehyde and ketone at 1771 cm?1 was only detected without a DOC, while the NO2 peak at 1634 cm?1 was solely noticed with the presence of DOC. Compared to the first-stage pyrolysis products, more polycyclic aromatic hydrocarbons and less CxHy fragments were seen in the second-stage. 相似文献