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Glycine(Gly) is ubiquitous in the atmosphere and plays a vital role in new particle formation(NPF).However,the potential mechanism of its on sulfuric acid(SA)-ammonia(A)clusters formation under various atmospheric conditions is still ambiguous.Herein,a(Gly)_x·(SA)_y·(A)_z(z≤x+y≤3) multicomponent system was investigated by using density functional theory(DFT) combined with Atmospheric Cluster Dynamics Code(ACDC) at different temperatures and precursor concentrations.The results show that Gly,with one carboxyl(-COOH) and one amine(-NH_2) group,can interact strongly with SA and A in two directions through hydrogen bonds or proton transfer.Within the relevant range of atmospheric concentrations,Gly can enhance the formation rate of SA-A-based clusters,especially at low temperature,low [SA],and median [A].The enhancement(R) of Gly on NPF can be up to 340 at T=218.15 K,[SA]=10~4,[A]=10~9,and [Gly]=10~7 molecules/cm~3.In addition,the main growth paths of clusters show that Gly molecules participate into cluster formation in the initial stage and eventually leave the cluster by evaporation in subsequent cluster growth at low [Gly],it acts as an important "transporter" to connect the smaller and larger cluster.With the increase of [Gly],it acts as a "participator" directly participating in NPF. 相似文献
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Heavy metals in honey are of interest not only for quality control, but also for determination environmental contamination.
The objective of this work was to determine distribution of the levels of selected heavy metals. Levels of copper (Cu), cadmium
(Cd), manganese (Mn), Iron (Fe), magnesium (Mg) and nickel (Ni) in honey samples (21) in Kahramanmaraş region were determined
by atomic absorption spectrometer (AAS). The mean values for Cu, Cd, Mn, Fe, and Mg were 0.01, 0.32, 0.03, 0.36 and 10.45
ppm, respectively. Nickel was not detected in honey samples. Kahramanmaraş honey samples were not free of heavy metals but
the levels of them were found well below the permitted levels. The results suggested that honey may be useful for assessing
the presence of environmental contaminants. 相似文献
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论DNA分子标记在家畜遗传多样性保护中的应用 总被引:1,自引:0,他引:1
本文就DNA分子遗传标记在家畜遗传多样性保护中应用的可行性及途径进行了探讨,提出了家畜遗传多样性标记辅助保护新策略。 相似文献
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IntroductionTheuseofchemicals,includingpesticides,hasbecomeanintegralandeconomicallyessentialpartofmodernagriculture.Pesticide?.. 相似文献
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Denise A. S. Batista PhD Cathleen Escallon Karin J. Blakemore Gail Stetten 《黑龙江环境通报》1995,15(2):123-127
We report a 16-month-old boy with delayed psychomotor development, dysmorphic features, and failure to thrive. He had a mosaic karyotype detected prenatally: mos 46,XY/47,XY,+r(20)/47,XY,+20. After birth, the abnormal cell lines were confirmed in a number of tissues. The small ring chromosome was identified using fluorescence in situ hybridization as derived from chromosome 20. We compared our patient with previously reported cases of mosaic trisomy 20 detected prenatally and associated with an abnormal phenotype. In an attempt to characterize an r(20) syndrome, we also compared our case with two similar reports in the literature. 相似文献
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针对目前桩锚式支护计算方法的局限性,对复杂土层中下端固定的锚定式挡土桩作了受力分析,并编写了计算机程序,适用于处理深基坑支护中的分层土(砂土、粘性土)、有超载、存在地下水等各种复杂土层。 相似文献
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Inthecourseofoilrefining,organicwastewaterwithhighconcentrationofemulsifiedoilandphenolisproduced,sofar,themethodsofphysicoche?.. 相似文献
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On the study of ecosystem health:state of the art 总被引:2,自引:0,他引:2
IntroductionDuringlastdecades,theterm“ecosystemhealth”isusedwithincreasingfrequencyintheliterature.Thegrowinginterestsinthestu... 相似文献