乙醇环己烷废液的回收

以水为萃取剂，萃取分离乙醇和环己烷，得到乙醇水溶液和粗环己烷。粗环己煊经精馏提纯，得到纯度为９９．９１％的纯品；乙醇水溶液经分馏，ＣａＯ脱水后得无水乙醇，纯度达９９．７４％。     

城市可降解生活垃圾的生物综合处理模式初探

针对现有城市生活垃圾处理方式的不足,结合垃圾生物处理特点,设计了集混合菌群降解、生物过滤除臭、污水回用及植被绿化于一体的立体处理体系。结果表明,该系统在城市生活垃圾的“三化”处理中具有显著的潜势:既使生活垃圾在食物链外形成安全的闭路循环,防止有害物质向人居环境入渗;同时,处理设施的立体化、终产物的生物转化以及即刻的市场效应,有效地增强了系统的消纳能力,缓解了传统处理方式对城市空间的压力。该系统对我国中小城市生活垃圾的综合利用具有积极的参考价值。     

Prevention of gasoline vapor explosions in portable fuel containers

Portable Fuel Containers (PFCs) made for consumer use can, under unusual circumstances, develop a flammable atmosphere in the container headspace. In order to prevent an inadvertent ignition from causing flame propagation into this headspace and a subsequent explosion or flame jetting, PFC manufacturers are developing prototype Flame Mitigation Devices (FMDs) for installation in the PFC. A test method is described in this paper to determine if the installed FMD will indeed prevent flame entry into the PFC in a high-challenge flame propagation scenario. The method entails the use of a butane-air mixture ignited in a 5 cm diameter, 12 cm long tube attached to either the container neck or a spout on the container neck. Two concept FMD designs have successfully prevented repeated attempts at flame propagation into the PFC and have also produced encouraging results in tests for fuel flow restriction, duel dispensing nozzle friction, and prolonged fuel exposure. Versions of these tests are currently being promulgated in a draft ASTM standard on PFC FMDs.     

Lower flammability limits of flammable ternary organic mixtures: Synergistic behavior

Organic flammable liquids and their mixtures, which possess high risk of combustion and explosion, are widely used as raw materials and solvents in chemical and pharmaceutical industries. Lower flammability limits (LFL) is one of the most important parameters to characterize the combustion and explosion hazards of combustible gases and liquid vapors. The LFL of various ternary organic mixtures consist of ketone (acetone and butanone), ester (ethyl acetate) and alcohol (ethanol and isopropanol) were tested at 25 °C and atmospheric pressure. The results showed that resulted LFL values of the experiment were always lower than those calculated by volume fraction weighting method when the volume fraction of alcohol was less than 20 vol% but more than 10 vol%. The co-existence of alcohol and ethyl acetate had synergistic effect on reducing the LFL values of ternary organic mixtures and thus increased their explosive risk. The mechanism of synergistic effect was analyzed, and the results showed that the OH· and H· radicals produced by the oxidation decomposition of alcohols and esters accelerated the oxidation process of ternary organic mixtures, which led to the decrease of experimental LFL values and thus corresponding increased of their explosive risk. This study would be expected to provide some guidance for designing or choosing safer and more suitable ternary organic mixtures prior to their applications for engineering.     

The effects of breath alcohol concentration on postural control

Background: Two of the 3 standardized field sobriety tests that U.S. law enforcement uses at roadside checks have a postural equilibrium component to them. Those tests have been validated to detect impairment caused by blood alcohol concentrations (BACs) of 0.08 g/dL or above. Many medical and traffic safety associations support a lower limit, and one state, Utah, has passed a law to lower the limit to 0.05 g/dL. Many studies have examined the effects of alcohol on postural control (of which postural equilibrium is a component), with a consensus emerging that impairment is usually found at BACs greater than 0.06 g/dL. Most of these studies, however, had a relatively small number of subjects, usually between 10 and 30. The current study collected data from a much larger sample.

Objective: The objective of this study was to provide additional evidence that posture control is negatively affected at BACs greater than 0.06 g/dL or breath alcohol concentrations (BrACs) of 0.06 g/210 L.

Method: This was a between-subjects study, with BrAC group as the independent variable (5 levels: 0.00, 0.04, 0.06, 0.08, and 0.10 g/210 L); 4 measures of postural control as the dependent variables; and age, height, and weight as the covariates. Posture control was measured with a force-sensing platform connected to a computer. The feet's center of pressure (CoP) on the platform was recorded and the corresponding movement of the body in the anterior–posterior and lateral planes was derived. Participants (N = 96) were randomly assigned to one of the BrAC groups. Positive BrAC groups were compared to the zero BrAC group. Data were examined with hierarchical multiple regression.

Results: Adjusted for age, height, and weight, the main effect of lateral CoP with eyes open was not statistically significant. There was a statistically significant main effect of alcohol on anterior–posterior CoP excursion with eyes open and with eyes closed and lateral CoP excursion with eyes closed. For all 3 of those variables, only BrACs of 0.08 and 0.10 g/210 L produced differences against zero BrAC. Although the main effect of alcohol on Lateral CoP Excursion with eyes open was not statistically significant, the contrasts between 0 and 0.08 and 0 and 0.10 g/210L BrAC were in the hypothesized direction.

Conclusion: The current study did not directly address the issue of whether the sobriety tests are sensitive to BrACs of 0.05 g/210 L or above; rather, it provides additional evidence that postural control, one of the components of those tests, is relatively unaffected by BrACs lower than 0.08 g/210 L. Additional research is needed on the diagnostic characteristics of the sobriety tests at BrACs lower than 0.08 g/210 L.     

Combining a finite mixture distribution model with indicator kriging to delineate and map the spatial patterns of soil heavy metal pollution in Chunghua County, central Taiwan

This study identifies the natural background, anthropogenic background and distribution of contamination caused by heavy metal pollutants in soil in Chunghua County of central Taiwan by using a finite mixture distribution model (FMDM). The probabilities of contaminated area distribution are mapped using single-variable indicator kriging and multiple-variable indicator kriging (MVIK) with the FMDM cut-off values and regulation thresholds for heavy metals. FMDM results indicate that Cr, Cu, Ni and Zn can be individually fitted by a mixture model representing the background and contamination distributions of the four metals in soil. The FMDM cut-off values for contamination caused by the metals are close to the regulation thresholds, except for the cut-off value of Zn. The receiver operating characteristic (ROC) curve validates that indicator kriging and MVIK with FMDM cut-off values can reliably delineate heavy metals contamination, particularly for areas lacking background information and high heavy metal concentrations in soil.     

Dietary patterns and blood levels of PCDDs, PCDFs, and dioxin-like PCBs in 1656 Japanese individuals

The association between dietary patterns and blood dioxin levels has not been fully investigated. The present study population consisted of 755 men and 901 women (aged 15-73 years) living in 90 different areas of 30 prefectures of Japan. Dietary habits were assessed by inquiring about the consumption frequency of 28 foods, food groups and beverages. In addition, the blood levels of 29 polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzo-furans (PCDFs), and dioxin-like polychlorinated biphenyl (DL-PCBs) congeners were determined by high-resolution gas chromatography/mass spectrometry. The median total toxicity equivalent (TEQ) in the blood, which was calculated on the basis of the toxicity equivalency factors of WHO (2005), was 16 pg TEQ g⁻¹ lipid. Principal component analysis identified five dietary patterns: Healthy diet (high intake of vegetables and fruits); Meat/High fat intake (high intake of meat, meat products, and eggs); Seafood and Alcohol (high intake of fish, shellfish, and alcoholic beverages); Miscellaneous; and Milk products and Alcohol intake (high intake of milk, Milk products, and alcoholic beverages). After adjusting for sex, age, body mass index, and smoking habits, the Seafood and Alcohol pattern scores were significantly related to higher blood levels of total TEQ and PCDDs/PCDFs/DL-PCBs, and the Milk products and Alcohol pattern scores were correlated with higher blood levels of DL-PCBs. More detailed analysis showed that the intake frequencies for alcoholic beverages and seafood were independently and positively associated with total TEQ and the TEQ of PCDFs and DL-PCBs. The association between alcoholic beverage intake and PCDDs was also significant. Analysis of dietary patterns may be useful for identifying the dietary characteristics of individuals with a high dioxin body burden.     

Developmental toxicity of two common corn pesticides to the endangered southern bell frog (Litoria raniformis)

To examine the link between corn agriculture and the observed decline of the endangered southern bell frog (SBF), the effects of two corn crop pesticides on larval growth and development were investigated. Tadpoles were exposed to terbufos sulfone (10 μg/L), a major breakdown product of the insecticide terbufos, and the herbicide atrazine (25 μg/L) individually and as a mixture until the completion of metamorphosis. Atrazine did not interact synergistically with terbufos sulfone or result in significant effects on growth and development alone, although there was some indication of accelerated metamorphosis in the pilot study. Terbufos sulfone alone and as a mixture (terbufos/atrazine) significantly slowed larval development and ultimately delayed metamorphosis. The observed developmental effects from an environmentally relevant concentration of terbufos sulfone indicates a risk posed by this persistent degradation product to the endangered SBF, which breeds and develops in the rice bays adjacent to corn fields treated with pesticides.     

水煤浆洁净燃烧技术在南海发电一厂的工程应用与分析

简要介绍了水煤浆的特点及其在广东南海发电一厂的应用,分析了水煤浆洁净燃烧技术的应用在减少SO2排放量及环境保护方面的意义。     

Liquefaction process for a hydrothermally treated waste mixture containing plastics

Most landfilled plastic waste is a mixture or is in the form of composites with incombustible wastes such as glass, metals, and ceramics. After hydrothermal treatment, including a steam-explosion process, the separation of mixed waste (MW) into organic and inorganic substances becomes easy. However, the effect of hydrothermal pretreatment on the subsequent liquefaction of organic substances from MW is not obvious. In this study, the effects on the liquefaction of polystyrene and high-density polyethylene are discussed. Moreover, optimum conditions for the liquefaction of organic substances from hydrothermally treated MW are identified. By means of this hydrothermal pretreatment, including the steam-explosion process, polystyrene and high-density polyethylene can be significantly converted to oil by liquefaction at 300°–400°C. In comparison with liquefaction of hydrothermally pretreated mixed waste (HMW) at 300°–400°C with a batch type reactor, the yield of oil increases significantly on liquefaction using a semi-batch type reactor. It is considered that the radical chain and termination reactions among the radicals from HMW were inhibited in the semi-batch type reactor. On liquefaction of HMW in a semi-batch reactor, the conversion of HMW to oil was enhanced on increasing the liquefaction temperature to 350°C and the holding time to 60 min. Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6