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1.
Huirong Lin Chengsong Ye Lu Lv Clark Renjun Zheng Shenghua Zhang Lei Zheng Yidong Zhao Xin Yu 《环境科学学报(英文版)》2014,26(8):1763-1768
A combined approach of physicochemical extraction and sulfur K-edge X-ray absorption near-edge structure(XANES) spectroscopy was applied to characterize the extracellular polymeric substances(EPS) of typical bacterial biofilms in this study. Physicochemical analysis showed variation of the contents of DNA,polysaccharide and protein in different fractions of EPS in different mediums. The sulfur K-edge XANES analysis yielded a variety of spectra.Spectral fitting of the XANES spectra utilizing a large set of model compounds showed that there was more reduced sulfur in both LB-EPS(loosely bound EPS) and TB-EPS(tightly bound EPS) of all the biofilms in LB medium than in R2 A medium. More oxidized sulfur was identified in LB-EPS than that in TB-EPS,suggesting different niches and physiological heterogeneity in the biofilms. Our results suggested that the sulfur K-edge XANES can be a useful tool to analyze the sulfur speciation in EPS of biofilms. 相似文献
2.
John M. Onyari Francis Mulaa Joshua Muia Paul Shiundu 《Journal of Polymers and the Environment》2008,16(3):205-212
In this study, the biodegradation of PLA films using microorganisms from Lake Bogoria (Kenya) were investigated. The biodegradation
tests done using certain strains of thermophilic bacteria showed faster biodegradation rates and demonstrated temperature
dependency. The biodegradation of the PLA films was studied using Gel Permeation Chromatography (GPC) and light microscopy.
The biodegradation of PLA was demonstrated by decrease in molecular weight. The preparation and characterization of PLA/Gum
Arabic blends were also investigated using DSC, TGA, TMA and NMR. In summary, the results obtained in this research show that
PLA films undergo fast biodegradation using thermophiles isolated from Lake Bogoria. The PLA/GA blends studies show it is
possible to prepare films of varying hydrophobic–hydrophilic properties for various applications. 相似文献
3.
K. M. S. Sundaram A. Sundaram 《Journal of environmental science and health. Part. B》2013,48(5):453-473
Abstract Spray deposit patterns were measured on aluminum coils and live balsam fir needles at different canopy heights, following aerial application of mexacarbate (4‐dimethylamino‐3,5‐xylyl N‐methylcarbamate) over a conifer forest in New Brunswick. Droplet size spectra of the spray cloud were determined on cylindrical Kromekote® cards placed at the corresponding crown heights. Ground deposits were collected on cylindrical Kromekote cards, aluminum coils and natural balsam fir foliage placed In forest clearings and under different types of vegetation. Canopy deposits decreased progressively from the top to the bottom level of the tree crown. This trend was observed on aluminum coils, live fir foliage, and Kromekote cards. Droplet size spectra were similar at all sampling heights of the tree crown, and were comparable to those obtained on the ground cards placed in the forest clearings. Deposits of mexacarbate obtained on ground samplers on the open forest floor were markedly lower than those found at the top canopy but were similar to those at the mid or bottom canopy level. Droplet size spectra and mexacarbate deposits obtained on samplers placed under different types of forest vegetation indicated a selective filtration of the large droplets present in the spray cloud by plant canopies. 相似文献
4.
Cheryl L. Dahlin Connie A. Williamson W. Keith Collins David C. Dahlin 《Environmental Forensics》2013,14(2):191-201
The applicability of sequential extraction as a means to determine species of heavy-metals was examined by a study on soil samples from two Superfund sites: the National Lead Company site in Pedricktown, NJ, and the Roebling Steel, Inc., site in Florence, NJ. Data from a standard sequential extraction procedure were compared to those from a comprehensive study that combined optical- and scanning-electron microscopy, X-ray diffraction, and chemical analyses. The study shows that larger particles of contaminants, encapsulated contaminants, and/or man-made materials such as slags, coke, metals, and plastics are subject to incasement, non-selectivity, and redistribution in the sequential extraction process. The results indicate that standard sequential extraction procedures that were developed for characterizing species of contaminants in river sediments may be unsuitable for stand-alone determinative evaluations of contaminant species in industrial-site materials. However, if employed as part of a comprehensive, site-specific characterization study, sequential extraction could be a very useful tool. 相似文献
5.
Holger Ecke Nourreddine Menad Anders Lagerkvist 《Journal of Material Cycles and Waste Management》2002,4(2):117-126
Dry scrubber residue from municipal solid waste incineration (MSWI) was characterized to identify critical inorganic pollutants
and to suggest a conceptual treatment method. The key methods used were thermal analysis, including thermogravimetry (TG)
and differential thermal analysis (DTA), pHstat titration, qualitative X-ray diffraction (XRD), scanning electron microscopy (SEM), chemical equilibrium calculations, and
statistics such as error propagation, principal component analysis (PCA), and empirical modeling based on factorial designs.
Based on EU directives, the major inorganic pollutants Cd, Cr, Pb, and Zn were found. In addition, the pH was too high. With
dry scrubber residue stabilization in mind, the impact of carbonation and hydration was assessed and judged to be encouraging.
In particular, chemical equilibrium calculations showed that carbonation has considerable potential to lower the pH and the
availability of Pb, Zn, and Cr. The impact of carbonation on the mobility of Cd was found to be small. During carbonation,
a metal-trapping calcium aluminosilicate hydrate (C–A–S–H) phase is also formed. Both processes together have the potential
to lead to a robust, reliable, and reasonable stabilization method for dry scrubber residue. However, to control these processes,
the decisive factors need to be identified and their effects need to be quantified. Ca, Cl, Na, and K might be abundant components
which would be mobile even after stabilization.
Received: September 11, 2001 / Accepted: December 6, 2001 相似文献
6.
The recovery of anionic azo dyes namely Congo red (CR), methyl orange (MO) from acidic aqueous solutions using tri-octyl amine (TOA) as an extractant has been investigated. The percentage of extraction of MO and CR increases with an increasing TOA concentration. The anionic dyes were extracted from aqueous solution at pH 2.0 ± 0.1. The extracted dye has been back extracted into aqueous solutions using sodium hydroxide, sodium carbonate and sodium bicarbonate. The organic phase obtained after the stripping of dyes was washed with dilute sodium hydroxide solution to neutralize any sulphuric acid trapped or adhered to the solvent and then with distilled water. This solvent was reused in succeeding extraction of dyes. The influencing parameters were; the effect of diluents, effect of extractant concentration, effect of pH, effect of interference study, effect of equilibrium time, various stripping reagents and stripping phase ratio. The characterization studies such as UV and IR spectra of extracted and stripped MO and CR was also studied. 相似文献
7.
Qinwei Lu Yi Zhou Qian Sui Yanbo Zhou 《Frontiers of Environmental Science & Engineering》2023,17(8):100
8.
Junling Li Hong Li Xuezhong Wang Weigang Wang Maofa Ge Hao Zhang Xin Zhang Kun Li Yan Chen Zhenhai Wu Fahe Chai Fan Meng Yujing Mu Abdelwahid Mellouki Fang Bi Yujie Zhang Lingyan Wu Yongchun Liu 《环境科学学报(英文版)》2021,33(4):185-197
Understanding the formation mechanisms of secondary air pollution is very important for the formulation of air pollution control countermeasures in China. Thus, a large-scale outdoor atmospheric simulation smog chamber was constructed at Chinese Research Academy of Environmental Sciences (the CRAES Chamber), which was designed for simulating the atmospheric photochemical processes under the conditions close to the real atmospheric environment. The chamber consisted of a 56-m3 fluorinated ethylene propylene (FEP) Teflon film reactor, an electrically-driven stainless steel alloy shield, an auxiliary system, and multiple detection instrumentations. By performing a series of characterization experiments, we obtained basic parameters of the CRAES chamber, such as the mixing ability, the background reactivity, and the wall loss rates of gaseous compounds (propene, NO, NO2, ozone) and aerosols (ammonium sulfate). Oxidation experiments were also performed to study the formation of ozone and secondary organic aerosol (SOA), including α-pinene ozonolysis, propene and 1,3,5-trimethylbenzene photooxidation. Temperature and seed effects on the vapor wall loss and SOA yields were obtained in this work: higher temperature and the presence of seed could reduce the vapor wall loss; SOA yield was found to depend inversely on temperature, and the presence of seed could increase SOA yield. The seed was suggested to be used in the chamber to reduce the interaction between the gas phase and chamber walls. The results above showed that the CRAES chamber was reliable and could meet the demands for investigating tropospheric chemistry. 相似文献
9.
Particles from ambient air and combustion sources including vehicle emission, coal combustion and biomass burning were collected and chemically pretreated with the purpose of obtaining isolated BC (black carbon) samples. TEM (transmission electron microscopy) results indicate that BC from combustion sources shows various patterns, and airborne BC appears spherical and about 50 nm in diameter with a homogeneous surface and turbostratic structure. The BET (Barrett–Emmett–Teller) results suggest that the surface areas of these BC particles fall in the range of 3–23 m2/g, with a total pore volume of 0.03–0.05 cm3/g and a mean pore diameter of 7–53 nm. The nitrogen adsorption–desorption isotherms are indicative of the accumulation mode and uniform pore size. O2-TPO (temperature programmed oxidation) profiles suggest that the airborne BC oxidation could be classified as the oxidation of amorphous carbon, which falls in the range of 406–490°C with peaks at 418, 423 and 475°C, respectively. Generally, the BC characteristics and source analysis suggest that airborne BC most likely comes from diesel vehicle emission at this site. 相似文献
10.
《Journal of Manufacturing Processes》2014,16(2):176-182
Cladding is generally characterized by partial dilution of the substrate and hence formation of metallurgical bonding between the substrate and the deposits. Laser cladding is one of the most widely practiced surface engineering techniques. The present work mainly focuses on a novel development in surface engineering techniques in the form of microwave cladding. Clads of tungsten carbide (WC) based WC10Co2Ni powder on austenitic stainless steel were produced using microwave hybrid heating. Microwave clads were developed by exposing the preplaced, preheated powder for a duration of 120 s to microwave radiation at 2.45 GHz frequency and 900 W power in a home microwave system. Characterization of the clads was carried out in the form of microstructural and elemental composition studies. Investigations show crack-free interface revealing good metallurgical bond associated with partial dilution of the stainless steel substrate and full melting of WC particles. Typical X-ray diffraction results confirm presence of metallic carbides in the clad which is primarily responsible for significantly higher microhardness of the clad. Process mechanism has been discussed. 相似文献