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1.
通过在西安市三环内6个功能区布设62个采样点,采样分析其表层土壤中邻苯二甲酸酯(PAEs)质量比及其构成特征。结果表明,西安市表层土壤中DMP、DEP、BBP、DnBP、DEHP和DnOP平均值分别为0.188 mg/kg、0.187 mg/kg、0.091 mg/kg、4.174 mg/kg、6.122 mg/kg和0.188 mg/kg,6种PAEs总质量比(∑6PAEs)范围为1.54 mg/kg^153.17 mg/kg,平均值为10.95 mg/kg。6个功能区∑6PAEs从高到低为交通区>工业区>混合区>公园>文教区>住宅区。与其他城市表层土壤中PAEs值比较发现,DMP处于高水平,DEP、DnBP、DEHP和∑6 PAEs处于较高水平,BBP和DnOP处于中等水平。 相似文献
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One methodology is proposed to estimate the quantification and composition of building-related construction and demolition (C&D) waste in a fast developing region like Shanghai, PR China. The varieties of structure types and building waste intensities due to the requirement of progressive building design and structure codes in different decades are considered in this regional C&D waste estimation study. It is concluded that approximately 13.71 million tons of C&D waste was generated in 2012 in Shanghai, of which more than 80% of this C&D waste was concrete, bricks and blocks. Analysis from this study can be applied to facilitate C&D waste governors and researchers the duty of formulating precise policies and specifications. As a matter of fact, at least a half of the enormous amount of C&D waste could be recycled if implementing proper recycling technologies and measures. The appropriate managements would be economically and environmentally beneficial to Shanghai where the per capita per year output of C&D waste has been as high as 842 kg in 2010. 相似文献
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铝和铁共聚物的组成与结晶形貌 总被引:6,自引:0,他引:6
通过扫描电镜对铝,铁均聚物与共聚物样品的观察,不同Al/Fe的能谱点测定,其晶形貌象进行了比较,并探讨其共聚合作用的机理,为深入研究铝,铁无机共聚合物特性及絮凝效能提供了基础依据。 相似文献
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Krupa SV 《Environmental pollution (Barking, Essex : 1987)》2002,120(3):565-594
Wet deposition is one of two processes governing the transfer of beneficial and toxic chemicals from the atmosphere on to surfaces. Since the early 1970s, numerous investigators have sampled and analyzed precipitation for their chemical constituents, in the context of "acidic rain" and related atmospheric processes. Since then, significant advances have been made in our understanding of how to sample rain, cloud and fog water to preserve their physico-chemical integrity prior to analyses. Since the 1970s large-scale precipitation sampling networks have been in operation to broadly address regional and multi-regional issues. However, in examining the results from such efforts at a site-specific level, concerns have been raised about the accuracy and precision of the information gathered. There is mounting evidence to demonstrate the instability of precipitation samples (e.g. with N species) that have been subjected to prolonged ambient or field conditions. At the present time precipitation sampling procedures allow unrefrigerated or refrigerated collection of wet deposition from individual events, sequential fractions within events, in situ continuous chemical analyses in the field and even sampling of single or individual rain, cloud and fog droplets. Similarly analytical procedures of precipitation composition have advanced from time-consuming methods to rapid and simultaneous analyses of major anions and cations, from bulk samples to single droplets. For example, analytical techniques have evolved from colorimetry to ion chromatography to capillary electrophoresis. Overall, these advances allow a better understanding of heterogeneous reactions and atmospheric pollutant scavenging processes by precipitation. In addition, from an environmental perspective, these advances allow better quantification of semi-labile (e.g. NH4+, frequently its deposition values are underestimated) or labile species [e.g. S (IV)] in precipitation and measurements of toxic chemicals such as Hg and PCBs (polychlorinated biphenyls). Similarly, methods now exist for source-receptor studies, using for example, the characterization of reduced elemental states and/or the use of stable isotopes in precipitation as tracers. Future studies on the relationship between atmospheric deposition and environmental impacts must exploit these advances. This review provides a comprehensive and comparative treatment of the state of the art sampling methods of precipitation and its physico-chemical analysis. 相似文献
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The organic fraction of municipal solid waste (OFMSW) is composed of several heterogeneous organic and inorganic wastes. The diversity of composition, the high volatile solid content and the biodegradable material that this waste offers make it quite an interesting option for anaerobic digestion (AD). Depending on the substrate composition, the biological degradation and kinetics of the AD could vary. Biochemical methane potential (BMP) tests are used as a tool to evaluate the methane production of several fractions of OFMSW, in order to study the influence of each fraction in the final mixture. The kinetic parameters of methane curves and the prediction of final productions are studied by different approaches to model equations using linear, exponential, logistic and Gaussian models. The analyses of the fractions indicate that organic substrates such as meat/fish which are in a small proportion in the final mixture, obtain major productivities (291 ± 3 mlCH4/gVS), however others such as paper (217 ± 5 mlCH4/gVS) could have their productivity enhanced due to their high VS present in the final mixture. Both the Gomperzt and the first order model fit reasonably with all the fractions, although substrates with lag phase adjust only to the Gompertz model explaining 99% of the experimental results. 相似文献
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Solid waste management practices in the Eastern Province of Saudi Arabia are reviewed. The officials of various municipalities and agencies responsible for collecting and disposing of municipal waste were interviewed. The refuse generation rate found is in the range of 1.61–2.72 kg per capita per day. The refuse composition data indicate a high percentage of glass, metals, and wood. For storage purposes, 0.2-m3 barrels are used in residential areas and 0.75 to 1.50 m3-capacity containers are used in commerical areas. The present solid-waste collection system is labor-intensive, and a significant part of the budget is spent on collection and haul operations. The unit collection and haul cost is much higher than the unit disposal cost of refuse. The direct haul of refuse is the common practice, and the use of transfer stations has not yet been considered. It is also observed that the disposal methods used at these sites are not in line with modern techniques for refuse disposal. Landfilling and combined burning and landfilling are the common disposal methods at all the sites. 相似文献
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The dissolution of the 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) from microscale particles (<250 μm) of the explosive formulation Composition B was examined and compared to dissolution from macroscopic particles (>0.5 mm). The dissolution of explosives from detonation soot was also examined. The measured mass transfer coefficients for the microscale particles were one to two orders of magnitude greater than the macroscopic particles. When normalized to particle surface area, mass transfer coefficients of microscale and macroscale particles were similar, indicating that the bulk dissolution processes were similar throughout the examined size range. However, an inverse relationship was observed between the particle diameter and the RDX:TNT mass transfer rate coefficient ratio for dry-attritted particles, which suggests that RDX may be more readily dissolved (relative to TNT) in microscale particles compared to macroscale particles. Aqueous weathering of larger Composition B residues generated particles that possessed mass transfer coefficients that were on the order of 5- to 20-fold higher than dry-attritted particles of all sizes, even when normalized to particle surface area. These aqueous weathered particles also possessed a fourfold lower absolute zeta-potential than dry-attritted particles, which is indicative that they were less hydrophobic (and hence, more wettable) than dry-attritted particles. The increased wettability of these particles provides a plausible explanation for the observed enhanced dissolution. The wetting history and the processes by which particles are produced (e.g., dry physical attrition vs. aqueous weathering) of Composition B residues should be considered when calculating mass transfer rates for fate and transport modeling. 相似文献