Potential world garbage and waste carbon sequestration

To offset the carbon dioxide released by fossil fuels, a proposed sequestration strategy relies on burying garbage and waste in landfills. This paper roughly estimates the current annual world supply of carbonaceous waste to be 35.5 billion metric tons and to contain about 18 billion metric tons of carbon. If landfills received all of this waste, sequestration of more than 5.6 billion metric tons of carbon seems theoretically possible—an amount well in excess of the 3.3 billion metric tons which the atmosphere is currently gaining.     

The potential leaching and mobilization of trace elements from FGD-gypsum of a coal-fired power plant under water re-circulation conditions

Experimental and geochemical modelling studies were carried out to identify mineral and solid phases containing major, minor, and trace elements and the mechanism of the retention of these elements in Flue Gas Desulphurisation (FGD)-gypsum samples from a coal-fired power plant under filtered water recirculation to the scrubber and forced oxidation conditions. The role of the pH and related environmental factors on the mobility of Li, Ni, Zn, As, Se, Mo, and U from FGD-gypsums for a comprehensive assessment of element leaching behaviour were also carried out. Results show that the extraction rate of the studied elements generally increases with decreasing the pH value of the FGD-gypsum leachates. The increase of the mobility of elements such as U, Se, and As in the FGD-gypsum entails the modification of their aqueous speciation in the leachates; UO₂SO₄, H₂Se, and HAsO₂ are the aqueous complexes with the highest activities under acidic conditions. The speciation of Zn, Li, and Ni is not affected in spite of pH changes; these elements occur as free cations and associated to SO₄² in the FGD-gypsum leachates. The mobility of Cu and Mo decreases by decreasing the pH of the FGD-gypsum leachates, which might be associated to the precipitation of CuSe₂ and MoSe₂, respectively. Time-of-Flight mass spectrometry of the solid phase combined with geochemical modelling of the aqueous phase has proved useful in understanding the mobility and geochemical behaviour of elements and their partitioning into FGD-gypsum samples.     

The potential leaching and mobilization of trace elements from FGD-gypsum of a coal-fired power plant under water re-circulation conditions

Experimental and geochemical modelling studies were carried out to identify mineral and solid phases containing major, minor, and trace elements and the mechanism of the retention of these elements in Flue Gas Desulphurisation (FGD)-gypsum samples from a coal-fired power plant under filtered water recirculation to the scrubber and forced oxidation conditions. The role of the pH and related environmental factors on the mobility of Li, Ni, Zn, As, Se, Mo, and U from FGD-gypsums for a comprehensive assessment of element leaching behaviour were also carried out. Results show that the extraction rate of the studied elements generally increases with decreasing the pH value of the FGD-gypsum leachates. The increase of the mobility of elements such as U, Se, and As in the FGD-gypsum entails the modification of their aqueous speciation in the leachates; UO₂SO₄, H₂Se, and HAsO₂ are the aqueous complexes with the highest activities under acidic conditions. The speciation of Zn, Li, and Ni is not affected in spite of pH changes; these elements occur as free cations and associated to SO₄ ² in the FGD-gypsum leachates. The mobility of Cu and Mo decreases by decreasing the pH of the FGD-gypsum leachates, which might be associated to the precipitation of CuSe₂ and MoSe₂, respectively. Time-of-Flight mass spectrometry of the solid phase combined with geochemical modelling of the aqueous phase has proved useful in understanding the mobility and geochemical behaviour of elements and their partitioning into FGD-gypsum samples.     

A contaminated site investigation: comparison of information gained from geophysical measurements and hydrogeological modeling

The investigation of contaminated sites is usually a long and expensive process. It is therefore desirable to use a combination of methodologies in an integrative approach that can reduce redundant information gathering. The objective of this study was to examine the usefulness of 2 non-intrusive exploration techniques in a contaminated site investigation. Borehole positioning based on geophysical measurements was compared to positioning based on the Bayesian expert system for flow-field modeling. The goal set at the field site was the assessment of the type and load of contaminants transported from the landfill site to the adjacent aquifer and the extent of leachate plumes within the groundwater. The two methods made different demands on information gathering and were found to be complementary. The geophysical approach focused attention on the waste compartments at the site and on mixing plumes in the adjacent aquifer but could not, without prior information, provided information on the flow field. The Bayesian approach to flow-field modeling determined areas of greatest model uncertainty at the model boundaries. The model highlighted areas of greatest uncertainty that might otherwise have been overlooked and provided information on the most likely mean direction of the leachate plumes. It was concluded that both methods contribute to a site investigation and should be used before additional drilling is carried out.     

Utilization of sepiolite materials as a bottom liner material in solid waste landfills

Landfill bottom liners are generally constructed with natural clay soils due to their high strength and low hydraulic conductivity characteristics. However, in recent years it is increasingly difficult to find locally available clay soils that satisfy the required engineering properties. Fine grained soils such as sepiolite and zeolite may be used as alternative materials in the constructions of landfill bottom liners. A study was conducted to investigate the feasibility of using natural clay rich in kaolinite, sepiolite, zeolite, and their mixtures as a bottom liner material. Unconfined compression tests, swell tests, hydraulic conductivity tests, batch and column adsorption tests were performed on each type of soil and sepiolite–zeolite mixtures. The results of the current study indicate that sepiolite is the dominant material that affects both the geomechanical and geoenvironmental properties of these alternative liners. An increase in sepiolite content in the sepiolite–zeolite mixtures increased the strength, swelling potential and metal adsorption capacities of the soil mixtures. Moreover, hydraulic conductivity of the mixtures decreased significantly with the addition of sepiolite. The utilization of sepiolite–zeolite materials as a bottom liner material allowed for thinner liners with some reduction in construction costs compared to use of a kaolinite-rich clay.     

Photoacoustic infrared spectroscopy for conducting gas tracer tests and measuring water saturations in landfills

Gas tracer tests can be used to determine gas flow patterns within landfills, quantify volatile contaminant residence time, and measure water within refuse. While gas chromatography (GC) has been traditionally used to analyze gas tracers in refuse, photoacoustic spectroscopy (PAS) might allow real-time measurements with reduced personnel costs and greater mobility and ease of use. Laboratory and field experiments were conducted to evaluate the efficacy of PAS for conducting gas tracer tests in landfills. Two tracer gases, difluoromethane (DFM) and sulfur hexafluoride (SF₆), were measured with a commercial PAS instrument. Relative measurement errors were invariant with tracer concentration but influenced by background gas: errors were 1-3% in landfill gas but 4-5% in air. Two partitioning gas tracer tests were conducted in an aerobic landfill, and limits of detection (LODs) were 3-4 times larger for DFM with PAS versus GC due to temporal changes in background signals. While higher LODs can be compensated by injecting larger tracer mass, changes in background signals increased the uncertainty in measured water saturations by up to 25% over comparable GC methods. PAS has distinct advantages over GC with respect to personnel costs and ease of use, although for field applications GC analyses of select samples are recommended to quantify instrument interferences.     

城市生活垃圾的处理和防治污染对策

本文分析了发达国家和我国城市生活垃圾处理的现状，并以广州为例，提出了城市垃圾处置的一些问题，指出卫生填埋城市生活垃圾在我国有广阔的应用前景。     

Integration of multi-channel piezometry and electrical tomography to better define chemical heterogeneity in a landfill leachate plume within a sand aquifer

The Hanai-Bruggeman effective medium theory is used to relate bulk electrical conductivity, measured by surface and cross-borehole images, to fluid electrical conductivity, surface conductance, porosity and the geometry factor, in a medium- to fine-grained sand deposit. The change in bulk EC is caused by the presence of a landfill leachate plume. Repeated electrical images over a period of 16 months indicate that various segments of the plume are moving. The chemical constituents of the leachate plume have been determined by sampling from a bundled piezometer located in the electrical image field. Very close agreement is demonstrated between the fluid EC anomaly and the presence of elevated bulk EC indicating that the electrical images can be used to map the plume geometry and to monitor the movement of the plume segments.     

On the Issue of Functional Form Choice in Hedonic Price Functions: Further Evidence

/ Historically, researchers applying the hedonic technique devoted little effort to testing alternative functional forms. This study used Box-Cox transformations on a hedonic model examining property value effects of a closed landfill to help select among alternative functional forms. Although this particular application found that a log-log functional form was appropriate, it appears that functional form may vary by problem and case study area selected. Benefit estimates generated using the hedonic technique may be substantial over- or underestimates if the incorrect functional form is chosen. Proximity to the landfill had no significant effect on property values.KEY WORDS: Hedonics; Functional form; Box-Cox; Landfills     

Making or breaking waste facility siting successes with a siting framework

Waste facility siting successes depend on many linked factors of facility design and impacts, site characteristics, and community beliefs and values. A facility siting framework is constructed to combine important elements and cause–effect linkages that affect the siting outcome. The framework consists of three main components: (1) core elements of facility design, effects, and community beliefs, attitude and response; (2) contributing factors of site and community characteristics, community beliefs and values that affect the interpretation of the facility and its effects; and (3) siting management interventions to manage the process and facility impacts. The framework is applied in an unsuccessful and a successful siting case to determine the key elements that contribute to siting outcome: (1) thorough need justification for the facility from the proponent's and the community's perspective; (2) careful facility design and prediction of the impacts and to select impact management compensation measures; (3) screening and selection of communities where the beliefs and values are compatible with the type of facility and its effects, (4) cooperatively selected impact reduction (i.e., prevention, control, and mitigation) measures followed by compensation and incentives; and (5) intensive process management to balance the community characteristics and values with the proponent's efforts to plan, design, assess and manage impacts, and ultimately, gain approval of the facility. The siting framework provides a comprehensive and robust structure of key factors that contribute to siting outcome and, therefore, provides the tool to identify, evaluate, and design siting interventions to enhance the chances of successful siting outcome.