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Elisângela Corradini Syed H. Imam José A. M. Agnelli Luiz H. C. Mattoso 《Journal of Polymers and the Environment》2009,17(1):1-9
Coconut, sisal and jute fibers were added as reinforcement materials in a biodegradable polymer matrix comprised of starch/gluten/glycerol.
The content of fibers used in the composites varied from 5% to 30% by weight of the total polymers (starch and gluten). Materials
were processed in a Haake torque rheometer (120 °C, 50 rpm) for 6 min. The mixtures obtained were molded by heat compression
and further characterized. Addition of lignocellulosic fibers in the matrix decreased the water absorption at equilibrium.
The diffusion coefficient decreased sharply around 5% fiber concentration, and further fiber additions caused only small variations.
The thermogravimetric (TG) analysis revealed improved thermal stability of matrix upon addition of fibers. The Young’s modulus
and ultimate tensile strength increased with fiber content in the matrix. The storage modulus increased with increasing fiber
content, whereas tanδ curves decreased, confirming the reinforcing effect of the fibers. Morphology of the composites analyzed
under the scanning electron microscope (SEM) exhibited good interfacial adhesion between the matrix and the added fibers.
Matrix degraded rapidly in compost, and addition of increased amounts of coconut fiber in the matrix caused a slowdown the
biodegradability of the matrix.
Names are necessary to report factually on available data; however, the USDA neither guarantees nor warrants the standard
of the product, and the use of the name by USDA implies no approval of the product to the exclusion of others that may be
suitable. 相似文献
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Maria T. B. Pimenta Antonio J. F. Carvalho Fabiola Vilaseca Jordi Girones Joan P. López Pere Mutjé Antonio A. S. Curvelo 《Journal of Polymers and the Environment》2008,16(1):35-39
Treated sisal fibers were used as reinforcement of polypropylene (PP) composites, with maleic anhydride-grafted PP (MAPP)
as coupling agent. The composites were made by melting processing of PP with the fiber in a heated roller followed by multiple
extrusions in a single-screw extruder. Injection molded specimens were produced for the characterization of the material.
In order to improve the adhesion between fiber and matrix and to eliminate odorous substances, sisal fibers were treated with
boiling water and with NaOH solutions at 3 and 10 wt.%. The mechanical properties of the composites were assessed by tensile,
bend and impact tests. Additionally, the morphology of the composites and the adhesion at he fiber–matrix interface were analyzed
by SEM. The fiber treatment led to very light and odorless materials, with yields of 95, 74 and 62 wt.% for treatments with
hot water, 3 and 10 wt.% soda solution respectively. Fiber treatment caused an appreciable change in fiber characteristics,
yet the mechanical properties under tensile and flexural tests were not influenced by that treatment. Only the impact strength
increased in the composites with alkali-treated sisal fibers. 相似文献
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