A panel study on the relationship between biofuels production and sustainable development

Biomass is one of the renewable energy sources on which policy makers are greatly dependent on since it is a flexible feedstock capable of conversion into electricity, transport liquid fuels and heat by chemical and biological processes on demand. Though numerous publications have examined the relationship of economic growth with renewable energy and other parameters, biomass energy has never been included in these studies. Then, this study examines the causal relationship within a multivariate panel cointegration/error correction framework which combines the cross-section and time series data while allowing for heterogeneity across different provinces. After employing panel data regression model ranging from 2003 through 2012 to examine the relationships of biofuels production with sustainable development in China, the paper concludes that the development of biofuel energy production integrated with the consideration of the improvement of income per capita, and the attraction of more capital investment, does make a significant contribution to economic growth. However, some negative side effects including the increase of greenhouse emissions and the decrease of marginal land still coexist with the economic development. Of course, the importance of these findings lies on their implications and their adoption on strategic policies.     

Sustainable global energy supply based on lignocellulosic biomass from afforestation of degraded areas

An important aspect of present global energy scenarios is the assumption that the amount of biomass that can be grown on the available area is so limited that a scenario based on biomass as the major source of energy should be unrealistic. We have been investigating the question whether a Biomass Scenario may be realistic. We found that the global energy demand projected by the International Energy Agency in the Reference Scenario for the year 2030 could be provided sustainably and economically primarily from lignocellulosic biomass grown on areas which have been degraded by human activities in historical times. Moreover, other renewable energies will contribute to the energy mix. There would be no competition with increasing food demand for existing arable land. Afforestation of degraded areas and investment for energy and fuel usage of the biomass are not more expensive than investment in energy infrastructure necessary up to 2030 assumed in the fossil energy based Reference Scenario, probably much cheaper considering the additional advantages such as stopping the increase of and even slowly reducing the CO₂ content of the atmosphere, soil, and water conservation and desertification control. Most importantly, investment for a Biomass Scenario would be actually sustainable, in contrast to investment in energy-supply infrastructure of the Reference Scenario. Methods of afforestation of degraded areas, cultivation, and energetic usage of lignocellulosic biomass are available but have to be further improved. Afforestation can be started immediately, has an impact in some few years, and may be realized in some decades. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.

Carbon abatement in the fuel market with biofuels: Implications for second best policies

A carbon tax on fuel would penalize carbon intensive fuels like gasoline and shift fuel consumption to less carbon intensive alternatives like biofuels. Since biofuel production competes for land with agricultural production, a carbon tax could increase land rents and raise food prices. This paper analyzes the welfare effect of a carbon tax on fuel consisting of gasoline and biofuel in the presence of a labor tax, with and without a biofuel subsidy. The market impacts of a carbon tax are also compared with that of a subsidy. Findings show that if a carbon tax increases biofuel demand, the tax interaction effect due to higher fuel prices is exacerbated by higher land rent and food prices and greater erosion of the carbon tax base. Thus, the second best optimal carbon tax for fuel is lower with biofuel in the fuel mix, especially if biofuel is subsidized.     

Recovery of biomass wastes by hydrolysis in sub-critical water

The recovery of waste substances is important not only for the prevention of environmental issues, but also for the rational utilization of natural resources. Hydrolysis reaction in sub-critical water is a promising method for the treatment of organic wastes and has been attracting worldwide attention. In this paper, sub-critical water hydrolysis was employed as a method for producing amino acids, reducing sugars, bio-oil and gas fuels from biomass wastes. The current statuses of these useful chemicals production from biomass wastes by hydrolysis in sub-critical water were reviewed. The review indicates that sub-critical water hydrolysis can be an efficient process for recovering useful chemicals from biomass wastes. This method is renewable, sustainable, efficient, and safe for the environment.     

Charcoal versus LPG grilling: A carbon-footprint comparison

Undoubtedly, grilling is popular. Britons fire up their barbeques some 60 million times a year, consuming many thousands of tonnes of fuel. In milder climates consumption is even higher, and in the developing world, charcoal continues to be an essential cooking fuel. So it is worth comparing the carbon footprints of the two major grill types, charcoal and LPG, and that was the purpose of the study this paper documents. Charcoal and LPG grill systems were defined, and their carbon footprints were calculated for a base case and for some plausible variations to that base case. In the base case, the charcoal grilling footprint of 998 kg CO₂e is almost three times as large as that for LPG grilling, 349 kg CO₂e. The relationship is robust under all plausible sensitivities. The overwhelming factors are that as a fuel, LPG is dramatically more efficient than charcoal in its production and considerably more efficient in cooking. Secondary factors are: use of firelighters, which LPG does not need; LPG's use of a heavier, more complicated grill; and LPG's use of cylinders that charcoal does not need.     

Renewable biofuel production from hydrocracking of soybean biodiesel with a commercial petroleum Ni-W catalyst

As a potential hydrocarbon production method, the hydrocracking of soybean biodiesel, using a commercial petroleum hydrocracking catalyst, was studied. Experiments were carried out in a 1,000 mL, high-pressure autoclave for 2–4 hr over the temperature range of 200–280°C under an initial hydrogen pressure of 10 MPa. Hydrocracking of soybean biodiesel produced n-paraffins in the C₈–C₁₇ boiling range, which includes both green gasoline and diesel. Both pressure and temperature play important roles in the transformation of soybean biodiesel. Hydrocarbons can be formed above 220°C with a liquid yield of 81.76%. The n-alkanes content of the liquid product reached 32.29% at 280°C, with 88.32% C₁₁–C₁₄ selectivity. In addition, hydrocracking results in many changes of catalyst such as physical properties, morphology, etc. For the used catalyst, the concentrations of Ni and C increased, and the pore channels were significantly reduced.     

Pervaporation of ethanol produced from banana waste

Banana waste has the potential to produce ethanol with a low-cost and sustainable production method. The present work seeks to evaluate the separation of ethanol produced from banana waste (rejected fruit) using pervaporation with different operating conditions. Tests were carried out with model solutions and broth with commercial hollow hydrophobic polydimethylsiloxane membranes. It was observed that pervaporation performance for ethanol/water binary mixtures was strongly dependent on the feed concentration and operating temperature with ethanol concentrations of 1–10%; that an increase of feed flow rate can enhance the permeation rate of ethanol with the water remaining at almost the same value; that water and ethanol fluxes was increased with the temperature increase; and that the higher effect in flux increase was observed when the vapor pressure in the permeate stream was close to the ethanol vapor pressure. Better results were obtained with fermentation broth than with model solutions, indicated by the permeance and membrane selectivity. This could be attributed to by-products present in the multicomponent mixtures, facilitating the ethanol permeability. By-products analyses show that the presence of lactic acid increased the hydrophilicity of the membrane. Based on this, we believe that pervaporation with hollow membrane of ethanol produced from banana waste is indeed a technology with the potential to be applied.     

Alternative transportation fuel standards: Welfare effects and climate benefits

This paper develops an integrated model of the fuel and agricultural sectors to analyze the welfare and greenhouse gas emission (GHG) effects of the existing Renewable Fuel Standard (RFS), a Low Carbon Fuel Standard (LCFS) and a carbon price policy. The conceptual framework shows that these policies differ in the incentives they create for the consumption and mix of different types of biofuels and in their effects on food and fuel prices and GHG emissions. We also simulate the welfare and GHG effects of these three policies which are normalized to achieve the same level of US GHG emissions. By promoting greater production of food-crop based biofuels, the RFS is found to lead to a larger reduction in fossil fuel use but also a larger increase in food prices and a smaller reduction in global GHG emissions compared to the LCFS and carbon tax. All three policies increase US social welfare compared to a no-biofuel baseline scenario due to improved terms-of-trade, even when environmental benefits are excluded; global social welfare increases with a carbon tax but decreases with the RFS and LCFS due to the efficiency costs imposed by these policies, even after including the benefits of mitigating GHG emissions.     

Distribution and leaching characteristics of trace elements in ashes as a function of different waste fuels and incineration technologies

Impact of waste fuels (virgin/waste wood, mixed biofuel (peat, bark, wood chips) industrial, household, mixed waste fuel) and incineration technologies on partitioning and leaching behavior of trace elements has been investigated. Study included 4 grate fired and 9 fluidized boilers. Results showed that mixed waste incineration mostly caused increased transfer of trace elements to fly ash; particularly Pb/Zn. Waste wood incineration showed higher transfer of Cr, As and Zn to fly ash as compared to virgin wood. The possible reasons could be high input of trace element in waste fuel/change in volatilization behavior due to addition of certain waste fractions. The concentration of Cd and Zn increased in fly ash with incineration temperature. Total concentration in ashes decreased in order of Zn > Cu > Pb > Cr > Sb > As > Mo. The concentration levels of trace elements were mostly higher in fluidized boilers fly ashes as compared to grate boilers (especially for biofuel incineration). It might be attributed to high combustion efficiency due to pre-treatment of waste in fluidized boilers. Leaching results indicated that water soluble forms of elements in ashes were low with few exceptions. Concentration levels in ash and ash matrix properties (association of elements on ash particles) are crucial parameters affecting leaching. Leached amounts of Pb, Zn and Cr in > 50% of fly ashes exceeded regulatory limit for disposal. 87% of chlorine in fly ashes washed out with water at the liquid to solid ratio 10 indicating excessive presence of alkali metal chlorides/alkaline earths.     

Evaluation of recycling the effluent of hydrogen fermentation for biobutanol production: Kinetic study with butyrate and sucrose concentrations

Butyrate in the effluent of hydrogen-producing bioreactor is a potential feed for biobutanol production. For recycling butyrate, this study investigated the kinetics of biobutanol production by Clostridium beijerinckii NRRL B592 from different paired concentrations of butyrate and sucrose in a series of batch reactors. Results show that the lag time of butanol production increased with higher concentration of either sucrose or butyrate. In regression analyses, the maximum specific butanol production potential of 6.49 g g⁻¹ of dry cell was projected for 31.9 g L⁻¹ sucrose and 1.3 g L⁻¹ butyrate, and the maximum specific butanol production rate of 0.87 g d⁻¹ g⁻¹ of dry cell was predicted for 25.0 g L⁻¹ sucrose and 2.6 g L⁻¹ butyrate. The specific butanol production potential will decrease if more butyrate is added to the reactor. However, both sucrose and butyrate concentrations are weighted equally on the specific butanol production rate. This observation also is true on butanol yield. The maximum butanol yield of 0.49 mol mol⁻¹ was projected for 25.0 g L⁻¹ sucrose and 2.3 g L⁻¹ butyrate. In addition, a confirmation study found butanol yield increased from 0.2 to 0.3 mol mol⁻¹ when butyrate addition increased from 0 to 1 g L⁻¹ under low sugar concentration (3.8 g L⁻¹ sucrose). The existence of butyrate increases the activity of biobutanol production and reduces the fermentable sugar concentration needed for acetone–butanol–ethanol fermentation.