生态文明视角下的国土空间底线管控：“双评价”与国土空间规划监测评估预警

生态文明新时代下的空间规划体系对国土空间底线管控提出了明确要求,“双评价”与国土空间规划监测评估预警是底线思维的体现。研究“双评价”与国土空间规划监测评估预警在国土空间底线管控中的作用和地位,通过国土空间规划“一张图”实施监督信息系统的建设,对二者的联系及其相互作用进行体现,构建二者的联动方式,服务于国土空间底线管控及治理的全过程。“双评价”与国土空间规划监测评估预警共同组成底线管控的两个阶段,前者是开展底线管控的基础,后者是底线管控的路径和手段,两者皆是生态文明新时代下国土空间规划底线管控的重要工具,需以国土空间规划“一张图”实施监督信息系统为基础加强两者的有机结合。     

Density functional theory (DFT) studies of vanadium-titanium based selective catalytic reduction (SCR) catalysts

Based on density functional theory (DFT) and basic structure models, the chemical reactions on the surface of vanadium-titanium based selective catalytic reduction (SCR) denitrification catalysts were summarized. Reasonable structural models (non-periodic and periodic structural models) are the basis of density functional calculations. A periodic structure model was more appropriate to represent the catalyst surface, and its theoretical calculation results were more comparable with the experimental results than a non-periodic model. It is generally believed that the SCR mechanism where NH₃ and NO react to produce N₂ and H₂O follows an Eley-Rideal type mechanism. NH₂NO was found to be an important intermediate in the SCR reaction, with multiple production routes. Simultaneously, the effects of H₂O, SO₂ and metal on SCR catalysts were also summarized.     

Effect of substituents in hydroxyl radical-mediated degradation of azo pyridone dyes: Theoretical approaches on the reaction mechanism

Understanding the degradation behavior of azo dyes in photocatalytic wastewater treatment is of fundamental and practical importance for their application in textile-processing and other coloration industries. In this study, quantum chemistry, as density functional theory, was used to elucidate different degradation pathways of azo pyridone dyes in a hydroxyl radical (HO^?)-initiated photocatalytic system. A series of substituted azo pyridone dyes were synthesized by changing the substituent group in the para position of the benzene moiety, ranging from strong electron-donating to strong electron-withdrawing groups. The effect of dye molecular structure on the photocatalytic degradation reaction mechanism was analyzed and quantification of substituent effects on the thermodynamic and kinetics parameters was performed. Potential energy surface analysis revealed the most susceptible reaction site for the HO^? attack. The calculated reaction barriers are found to be strongly affected by the nature of substituent group with a good correlation using Hammett σ_p constants and experimentally determined reaction rates. The stability of pre-reaction complexes and transition state complexes were analyzed applying the distortion-interaction model. The increased stability of the transition state complexes with the distancing from the substituent group has been established.     

车载巡测在区域射频电磁环境质量监测与表征中的应用分析

对北京中央电视塔周围25 km²区域电磁环境质量分别进行了射频的网格法手工监测和车载巡测自动监测，通过SPSS软件等对两种监测方法获取的数据进行了统计对比分析，发现两组数据在总体水平及数值分布特征上较为接近，因此车载巡测监测可以替代网格法监测。以车载巡测数据为基础，绘制了实测数据的道路电磁地图，利用插值法绘制了区域电磁地图，对区域电磁环境质量进行了直观表征。从回应公众关注和城市电磁规划出发，建议今后可利用车载巡测监测加强时域和频域的监测。     

平流式二次沉淀池中异重流现象研究

通过对影响异重流形成因素的研究,发现在异重流的形成过程中进水污泥浓度对密度的影响远大于温度对密度的影响,二沉池的进水通常形成下层异重流.利用水力模型进行示踪试验,结果表明在平流式二沉池中存在明显的回流区.异重流对二沉池处理效果的影响有利有弊.     

基于GIS的海洋环境质量评价图编制

本文介绍了采用地理信息系统技术制作海洋环境质量评价图的基本内容，重点阐述了图件的表现形式、编制过程和具体的操作方法，为海洋环境质量评价图的制作提供了一种新的方法。     

试论国家自然保护地图集的编制——以中国自然保护地图集为例

本文从自然保护角度论述了编制自然保护地图集的意义和用途,指出了自然保护地图集是专门表示保护可更新自然资源的综合性地图集,并以中国自然保护地图集为例,探讨了用地图这一研究手段和工具来推动国家自然保护事业的发展。     

吉林省1:50万土地资源图的编制研究

本文研究了吉林省1:50万土地资源图的分类系统原则、依据、标准或指标体系,以及制图方法、颜色设计等制图理论和技术问题,对编制各类土地资源图提供了有力的借鉴。     

Experimental and theoretical studies on NO selective catalytic oxidation over α-MnO2

Based on the experimental and theoretical methods, the NO selective catalytic oxidation process was proposed. The experimental results indicated that lattice oxygen was the active site for NO oxide over the $\mathrm{\alpha }$-MnO₂(110) surface. In the theoretical study, DFT (density functional theory) and periodic slab modeling were performed on an $\mathrm{\alpha }$-MnO₂(110) surface, and two possible NO oxidation mechanisms over the surface were proposed. The non-defect $\mathrm{\alpha }$-MnO₂(110) surface showed the highest stability, and the surface O_s (the second layer oxygen atoms) position was the most active and stable site. O₂ molecule enhanced the joint adsorption process of two NO molecules. The reaction process, including O₂ dissociation and O=N-O-O-N=O formation, was calculated to carry out the NO catalytic oxidation mechanism over $\mathrm{\alpha }$-MnO₂(110). The results showed that NO oxidation over the $\mathrm{\alpha }$-MnO₂(110) surface exhibited the greatest possibility following the route of O=N-O-O-N=O formation. Meanwhile, the formation of O=N-O-O-N=O was the rate-determining step.     

试论陆相火山岩区火山地层单位与划分──关于火山岩区填图单元划分的讨论

火山活动具多旋回性，一个火山活动旋回的岩浆作用产物及其形成的火山构造形迹具时空分布协调性，同一旋回的火山构造在空间上呈串珠状或并列式展布，不同旋回的火山构造在空间上呈叠置式展布；火山喷发类型与火山岩相具一致性，岩相及相序是推演古火山演化历史、恢复古火山机构的主要依据，亦是组成火山地层并且成因意义的单元；不同旋回火山机构内的火山地层层序的综合、叠置是建立区域火山地层层序的基础；火山构造是火山岩区地质构造的主要内容，以区域构造、火山构造、火山岩浆作用产物的岩相为内容的火山岩相构造图是揭示火山岩区地质构造特征的综合性图件；环形火山构造叠置与区域线形构造交织分布组成线─环形境构造格局．是火山岩区所特有的构造面貌，在火山地质图上应得到充分的体现；。根据上述认识，对陆相火山岩区作为火山地层填图单元的岩石地层单位群─组─段─层划分提出了方案，建议用旋回─组─岩相─层（即火山构造─组─岩相─层）四级作为火山地层划分单位和填图单元，其中旋回火山构造一致，组与火山机构演化阶段一致，岩相与火山喷发类型一致，层为岩相内容的补充。据此填制的火山地质图才能真正成为反映火山岩浆作用及其产物的特色和具普遍意义的图件。