Advanced molecular-fingerprinting analysis of dissolved organic sulfur by electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry using optimal spray solvent

Molecular level characterization of dissolved organic sulfur (DOS) by electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR MS) is necessary for further understanding of the role of DOS in the environment. Here, ESI spray solvent, a key parameter for ion production during ESI process, was investigated for its effect on the molecular characterization of DOS by ESI-FTICR MS. 100% MeOH as spray solvent was found for the first time to remarkably enhance the ionization efficiency of the majority of CHOS-molecules in NOM, which facilitated a total of 1473 CHOS-molecular formulas with one sulfur atom to be detected. The number of CHOS-molecular formulas obtained using 100%MeOH as spray solvent increased notably over 740 in comparison with those using 50% MeOH aqueous solution (731) or 50% ACN aqueous solution (653). Moreover, due to the enhancement of ionization efficiency of DOS during ESI processes, the tandem mass spectra of the NOM CHOS-molecules could be easily obtained using 100% MeOH as spray solvent, which were hardly obtained using 50% MeOH aqueous solution as spray solvent. The results of the tandem mass spectra suggested the first discovery of organosulfates or sulfonic acids in Suwannee River NOM sample. A simple method based on 100% MeOH as ESI spray solvent for advanced molecular characterization of DOS by ESI-FTICR MS was proposed and applied, and the results revealed more molecular information of DOS in sea DOM samples.     

地球化学数据去噪方法研究

在简要介绍移动平均、傅立叶交换和小波变换基本原理的基础上，比较了它们在地球化学数据处理过程中去除噪声效果的优劣，并应用于塔北雅克松-轮台地区的地球化学勘探实际。研究结果表明，小波变换是一种理想的数据处理方法。     

福州乌鸦咀泉水电导率幅频谱分析初探

地震观测数据受各种周期性因素影响，其动态曲线表现为周期性变化特征，是大小不同的周期和非周期因素相互作用的结果。利用MATLAB工具包，编程幅频分析和滤波程序，以福州乌鸦咀泉水电导率的模拟观测数据为例，对其幅频谱特征和震例进行初步探讨。     

具有变频器的矿井低压漏电保护研究

为了解决移动变电站低压侧为变频器供电时漏电保护装置误动的问题，提出了基于傅式算法的附加直流原理漏电保护新方法。通过理论分析和MATLAB/Simulink仿真，研究了具有变频器的矿井低压供电系统附加直流原理漏电保护，提出由傅式算法分解出采样电压直流分量以反映电缆绝缘水平的保护方法；同时分析了其他因素对直流分量的影响。研究结果表明:变频器对传统附加直流保护整定值有较大影响，易造成漏电保护装置误动且无法实现电缆的在线绝缘监测；所提出的直流分量法能准确测量电缆对地绝缘电阻，且可消除电缆分布电容、变频器载波频率、变频器输出频率等其他因素的干扰；采用该漏电保护方法，可承受变频器投入时对采样电压造成的较大冲击，不必在启动期间解除漏电保护装置，能够消除在此期间存在的人身触电安全隐患。     

优化的甘蔗皮渣吸附居室甲醛

为了研究优化后的甘蔗皮渣吸附居室中的甲醛,本研究通过3种方法处理材料进行吸附甲醛对比,得出简便高效的碱热烫处理,并针对其热烫时间(X1)、pH值(X2)、水浴锅温度(X3)和水浴时间(X4)设置正交实验,得出热烫时间30 min、pH=11、水浴锅温度80℃、水浴时间2.5 h,甘蔗皮渣对甲醛吸附率可达27.91%。通过与活性炭、硅藻纯吸附效果比较,经F检验得出优化处理甘蔗皮渣与硅藻纯吸附效果相当,均极显著优于活性炭。电镜观测出优化甘蔗皮渣与活性炭、硅藻纯同具粗糙、皱褶、疏松多孔结构;傅里叶红外光谱分析出C≡C等基团在甲醛吸附中起主要作用。     

大气环境数据分析预测方法对比研究

以西安市2006年9月27日至2008年5月3日每日的SO2平均浓度时间序列为例,应用时间序列分析对前555个数据进行拟合,得到合适的时间序列模型ARIMA(1,1,2);利用神经网络中的BP神经网络和RBF神经网络对同样的样本进行训练,用这三种方法对2008年4月4日至2008年5月3日的SO2日均浓度值进行了预测,并用同样的方法分析预测了同期PM10日均浓度值,最后比较了它们的预测效果。结果表明,利用这三种方法进行浓度预测都是可行的,其中RBF神经网络法的预测误差最小,效果最好。     

估计近场地震动的统计—经验格林函数法

本文提出统计-经验格林函数法,用以估计缺乏小震记录场点在大震时的地震动时程。统计-经验格林函数的富里哀幅值谱从其它类似场地获得的小震记录的富里哀谱的衰减关系中得到,其相位谱则直接取自小震记录的相位谱。本文分别用经验格林函数法和统计-经验格林函数法,用迁安台记录到的1976年唐山地震的三次余震(M_L 5.8、M_L 5.7和M_L 5.4)的加速度记录,合成唐山地震的最大余震滦县地震(M_s 7.1)时迁安台的加速度时程曲线,合成结果说明了所提方法的可行性。     

脉动风速功率谱与随机Fourier幅值谱的关系研究

功率谱密度函数是随机过程在频域内的重要特征量,但由于其本质上是平稳过程的频域数值特征,致使其很难全面反映原始随机过程的概率信息,这就需要从更本源的意义上考察随机过程。本文试图从Fourier随机函数的角度反映随机过程,将经典的功率谱密度函数中具有物理意义的可测变量看作随机变量,利用功率谱与Fourier幅值谱的关系,定义了随机Fourier幅值谱;以Davenport谱为例,证实当地面粗糙度服从对数正态分布、10m高度基本风速服从极值Ⅰ型分布时,可通过功率谱构造具有物理意义的随机Fourier幅值谱。通过实测风速Fourier谱与随机Fourier幅值谱的比较,证明随机Fourier幅值谱的概念具有合理性。     

Application and mechanism of polysaccharide extracted from Enteromorpha to remove nano-ZnO and humic acid in coagulation process

Green source Ep was extracted from marine alga waste. The molecule model structure of Ep was studied and constructed. PAC-Ep coagulation system improves the efficiency of removal efficiency. Synergistic effects between NPs and HA make a big difference to enhance efficiency. Mechanism is charge neutralization, hydrogen bonding and adsorbing-complexing Enteromorpha polysaccharide (Ep) extracted from alga a novel green coagulant aid for nanoparticles (NPs) and heavy metal ions removal and the structure of EP was intensively studied in this study. The integration of Ep with polyaluminum chloride (PAC-Ep) coagulants exhibited higher coagulation performance than that of the polyaluminum chloride (PAC) because of the negatively charged NPs suspension and humic aid (HA) solution. Significant high removal efficiencies of dissolved organic matter (94.1%), turbidity (99.3%) and Zn ions (69.3%) were achieved by the PAC-Ep coagulants. The dual-coagulation properties of PAC-Ep for different pollutants was based on multiple mechanisms, including (i) Al³⁺ charge neutralization; (ii) hydroxy aluminum hydroxyl bridging formed polynuclearhydroxy complexes bridge and sweep colloidal particles; (iii) adsorption and bridging of Ep chain for the NPs and heavy metal ions. Results indicated that the destabilization of colloid was induced by the coexisting HA and higher removal was achieved as ions adsorption was enhance in the presence of HA complexation. On the basis of that, the extraction of polysaccharide is a promising candidate for its high coagulation performance in water treatment.