OCCURRENCE OF PESTICIDES IN GROUND WATER OF THE OZARK PLATEAUS PROVINCE1

ABSTRACT: Pesticides were detected in ground-water samples collected from 20 springs and nine wells in the Ozark Plateaus Province of Arkansas, Kansas, Missouri, and Oklahoma. From April through September 1993, water samples were collected from 50 shallow domestic wells and 50 springs in the Springfield Plateau and Ozark aquifers and analyzed for 47 pesticides and metabolites. Pesticides were detected in 17 water samples from the Springfield Plateau aquifer and 12 water samples from the Ozark aquifer. Fourteen pesticides were detected, with a maximum of four pesticides detected in any one sample. The most commonly detected pesticides were atrazine (14 detections), prometon (11 detections), and tebuthiuron (seven detections). P, P' DDE, a metabolite of DDT, was detected in water samples from three wells and one spring. The remaining pesticides were detected in three or less samples. The occurrence and distribution of pesticides probably are related to the local land use near a sampling site. Pesticide detections were significantly related to aquifer, site type, and discharge of springs.     

Quantifying Legacy Phosphorus Using a Mass Balance Approach and Uncertainty Analysis

Classic agricultural‐conservation practices may not address decades of phosphorus (P) accumulation, known as legacy P. Identifying and quantifying legacy P sources are necessary to identify the most cost‐efficient conservation practices. A method was developed to identify and quantify legacy P at the watershed scale using a mass‐balance approach and uncertainty analysis. The method was applied to two nutrient‐rich watersheds in northeast Oklahoma and northwest Arkansas. Each P import and export to and from the two watersheds was identified and quantified using a probability distribution and uncertainty analysis. The P retained in the soils, reservoirs, and stream systems were estimated from 1925 to 2015. Over 8.5 and 6.1 kg/ha/year of P were added to the Illinois River and Eucha‐Spavinaw watersheds with 53 and 55% from poultry production, respectively. Other major historical sources were attributed to human population and commercial fertilizer. Though currently the net addition of P in the watersheds is small due to the export of approximately 90% of the poultry litter, historically only 14‐19% of all P imported to the Illinois River and Eucha‐Spavinaw watersheds was removed via the reservoir spillways, poultry litter, and food exports. The majority of the retained P is located in the soil, 3.6‐5.8 kg/ha/year, and stream systems, 0.01‐3.0 per ha/year.