CO2捕集与封存研究进展及其在我国的发展前景

碳捕集与封存(CCS)技术已被广泛地认为是一种潜力巨大、可供选择的CO2减排手段。据预测,其减排贡献将从2020年占总减排量的3%上升至2030年的10%,并在2050年将达到20%左右,成为CO2减排份额最大的单项技术。本文介绍了CCS的主要技术环节(捕集、运输、封存)、封存地类型和目前国际上开展的主要CCS示范项目及发展趋势。同时特别探讨了海底封存CO2的可行性、封存潜力以及我国在海底封存CO2方面的研究进展和发展前景。     

Contaminants in the coastal karst aquifer system along the Caribbean coast of the Yucatan Peninsula, Mexico

Intensive land development as a result of the rapidly growing tourism industry in the “Riviera Maya” region of the Yucatan Peninsula, Mexico may result in contamination of groundwater resources that eventually discharge into Caribbean coastal ecosystems. We deployed two types of passive sampling devices into groundwater flowing through cave systems below two communities to evaluate concentrations of contaminants and to indicate the possible sources. Pharmaceuticals and personal care products accumulated in the samplers could only have originated from domestic sewage. PAHs indicated contamination by runoff from highways and other impermeable surfaces and chlorophenoxy herbicides accumulated in samplers deployed near a golf course indicated that pesticide applications to turf are a source of contamination. Prevention and mitigation measures are needed to ensure that expanding development does not impact the marine environment and human health, thus damaging the tourism-based economy of the region.     

Impact of Sea Level Rise on Groundwater Salinity in a Coastal Community of South Florida1

Guha, Hillol and Sorab Panday, 2012. Impact of Sea Level Rise on Groundwater Salinity in a Coastal Community of South Florida. Journal of the American Water Resources Association (JAWRA) 48(3): 510-529. DOI: 10.1111/j.1752-1688.2011.00630.x Abstract: Freshwater resources of coastal communities in the United States and world over are threatened by the rate of sea level rise. According to recent estimates by various governmental agencies and climate researchers, the global sea level rise is likely to be between 0.6 and 2.1 m by the year 2100. South Florida is a coastal community and much of its coastline is subject to sea level rise and potential impacts to wetlands and the water resources of the area. To understand what the impact of sea level rise would cause to the groundwater level and salinity intrusion, an integrated groundwater and surface water model was developed for North Miami-Dade and Broward Counties of South Florida. The model was calibrated against daily groundwater heads, base flows in canals, and chloride concentrations for a period of one year and six months. Three separate sensitivity analyses were conducted by increasing the sea level by 0.6, 0.9, and 1.22 m. Results of the simulations shows increase of groundwater heads in some areas from 4 to 15%; whereas the average relative chloride concentrations increased significantly by 100-600% in some wells. The increase in groundwater elevations and chloride concentrations varies from location of the wells and its proximity to the coast. The model results indicate that even a 0.6 m increase in sea level (which is the conservative estimate) is likely to impair the vital freshwater resources in many parts of South Florida.     

CENTRAL NEBRASKA RIVER BASINS,NEBRASKA1

ABSTRACT: The Central Nebraska Basins (NAWQA) study unit includes the Platte River and two major tributaries, the Loup and Elkhorn Rivers. Platte River flows are variable in the western part of the study unit because of diversions, but the Loup and Elkhorn Rivers originate in an area of dune sand covered by grassland that generates consistent base flows. More frequent runoff in the eastern part of the study unit also sustains stream flow. Ground water in the study unit has no regional confining units and the system is a water table aquifer throughout. Macroinvertebrate and fish taxa at biological sampling sites in the state were related to stream flow. One of the four wetland complexes identified in the study unit includes habitat for threatened and endangered bird species. The study unit is an agricultural area that includes row crops, both irrigated and nonirrigated in the eastern and southern parts, and rangeland in the Sand Hills of the western part. A water quality assessment will be based on the differences in environmental setting in each of four subunits within the study unit.]     

CO2 storage capacity estimation: Methodology and gaps

Implementation of CO₂ capture and geological storage (CCGS) technology at the scale needed to achieve a significant and meaningful reduction in CO₂ emissions requires knowledge of the available CO₂ storage capacity. CO₂ storage capacity assessments may be conducted at various scales—in decreasing order of size and increasing order of resolution: country, basin, regional, local and site-specific. Estimation of the CO₂ storage capacity in depleted oil and gas reservoirs is straightforward and is based on recoverable reserves, reservoir properties and in situ CO₂ characteristics. In the case of CO₂-EOR, the CO₂ storage capacity can be roughly evaluated on the basis of worldwide field experience or more accurately through numerical simulations. Determination of the theoretical CO₂ storage capacity in coal beds is based on coal thickness and CO₂ adsorption isotherms, and recovery and completion factors. Evaluation of the CO₂ storage capacity in deep saline aquifers is very complex because four trapping mechanisms that act at different rates are involved and, at times, all mechanisms may be operating simultaneously. The level of detail and resolution required in the data make reliable and accurate estimation of CO₂ storage capacity in deep saline aquifers practical only at the local and site-specific scales. This paper follows a previous one on issues and development of standards for CO₂ storage capacity estimation, and provides a clear set of definitions and methodologies for the assessment of CO₂ storage capacity in geological media. Notwithstanding the defined methodologies suggested for estimating CO₂ storage capacity, major challenges lie ahead because of lack of data, particularly for coal beds and deep saline aquifers, lack of knowledge about the coefficients that reduce storage capacity from theoretical to effective and to practical, and lack of knowledge about the interplay between various trapping mechanisms at work in deep saline aquifers.     

Groundwater resources in India: an arena for diverse competition

There is evidence of a looming groundwater crisis in India. Unlike in the case of surface water, competition around groundwater generally does not result in open conflicts. Measurability and visibility of surface water accord a clearer public perception of water quantities, which leads to conflicts. Groundwater in an aquifer is sourced in a dispersed manner, and boundaries, quantities and interdependencies are less visible or measurable. Hence, groundwater resources go through intense and intricate competition between users and uses before open conflicts begin. Competition occurs with reference to sources rather than around the resource. The interdependency of sources is a function of changing patterns of usage as intricacies of aquifer characteristics come into play. Governance institutions and regulatory frameworks of groundwater need to be sensitive to the various forms in which groundwater competition manifests in different hydrogeological settings, and the consequences of this in terms of access and rights, in relation to issues of equity and justice.     

EVALUATION OF AN INDUCED INFILTRATION MODEL AS APPLIED TO GLACIAL AQUIFER SYSTEMS1

ABSTRACT: Numerical models were used to examine the limitations of the assumptions used in an analytical induced infiltration model. The assumptions tested included negligible streambed effects, negligible areal recharge, two-dimensional ground water flow, fully penetrating rivers and wells, and constant surface water stage. For situations that deviate from the underlying assumptions, the analytical model becomes a less reliable predictor of induced infiltration. The numerical experiments show that streambed effects cannot be neglected if the streambed conductivity is more than one order of magnitude lower than the aquifer hydraulic conductivity. Areal recharge cannot be neglected if the ground water basin receives more than 5 in/yr of areal recharge. Three-dimensional flow effects due to well partial penetration cannot be neglected if the ratio of horizontal hydraulic conductivity to vertical hydraulic conductivity (K_h/K_u) is greater than 10. Surface water elevation fluctuations can significantly influence the induced infiltration rate, depending on the degree of fluctuations and the ground water hydraulic gradient.     

Does salt water intrusion constitute a mercury contamination risk for coastal fresh water aquifers?

Four different sampling surveys were carried out in 1998 to evaluate the possible causes of severe mercury contamination involving many wells spread over a vast territory along the coast of southern Tuscany (Italy). Several samples of groundwater and coastal sea water were collected to determine the Hg, Cl, Ar, He and N contents. Anthropogenic or deep-seated sources of the Hg involved in the contamination event can be excluded. The observed coupling of Hg pollution with progressive salt water intrusion along the coastal aquifer indicates a close causal relation between these two phenomena.     

Changes in quality of groundwater with seasonal fluctuations: an example from Ghor Safi area, southern Dead Sea coastal aquifers, Jordan

Introduction The alluvial fan along the eastern and southern m argins of the D ead Sea (hereafter denoted D S) consists of fine to coarse-grained siliclastic sand and pebble-size gravel w ith thin intercalations of lam inated m arl of H olocene age (Pow e…     

DRAWDOWN DUE TO PUMPING IN AN ANISOTROPIC AQUIFER1

ABSTRACT: A variable change is used to convert drawdown formulas for isotropic aquifers for use where the aquifer is anisotropic. Contours of the cone of depression assume an oval configuration with the major and minor axes oriented in the directions for which the permeability is greated and least. The case of a well pumped at a constant rate, the case of a well drawing water at a constant rate from an aquifer with a leaky roof and the flowing artesian well case are treated. In all cases the well is considered to completely penetrate the aquifer.