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高效液相色谱法分析水中痕量多环芳烃 总被引:14,自引:3,他引:14
本文利用高效液相色谱法测定水中痕量多环芳烃(PAHs)。以二氯甲烷作溶剂,超声提取水中痕量PAHs;甲醇、水作流动相,梯度淋洗,用程序可变波长荧光检测器测定。PHAs浓度为0.007=0.6μg·ml^-1范围时,线性相关系数均在0.9999以上;峰高、峰面积的相对标准偏差(n=10)分别为1.01-1.85%,2.00-3.94%;检测限(S/N=2)为3.1-23.0pg;实际水样的加标回收率 相似文献
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以不同煤种的煤样为研究对象,对其进行程序升温氧化实验,采集不同温度时煤样所产生的气体,进行气相色谱分析,研究不同煤样升温氧化过程中产生的气体种类以及气体浓度的变化特征。实验结果表明:不同煤样升温氧化过程中产生的气体种类不同,气体产生先后顺序依次是CO、C2H6、C2H4、C3H8,气体产生量与温度都近似呈指数变化关系;随煤变质程度的增高,煤样气体产生率急剧上升的拐点温度也变高,煤样氧化能力降低,相同时间段内煤样产生气体量却减少。 相似文献
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A gas chromatographic method without derivatization was developed for the residue analysis of 10 organonitrogen and 9 organophosphorus pesticides in soil and water. The samples were blended or shaken with acetone for extraction. The extracts were cleaned up by coagulation, then, re-extracted with three 50 ml portions of dichloromethane. The final residue was detected by gas chromatography equipped with NPD. All of the 19 pesticides were completely separated at a constant temperature. The method described above was applicable to the simultaneous determination of 10 organonitrogen and 9 organophosphorus pesticides .in soil and water with the satisfactory recovery (from 82.42% to 103.57%), coefficient of variance (from 0.17% to 12.57%) and limit of detection (from 0.0006 ppm to 0.058 ppm). 相似文献
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