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利用嗜酸性硫杆菌的生物产酸作用处理洗毛废水 总被引:2,自引:1,他引:1
利用洗毛废水在低pH条件下,有机物絮凝沉降的特点,通过嗜酸性硫杆菌(Acidophilic thiobacillus)的产酸作用降低体系pH,破坏废水固有的稳定性,改变有机物的亲水性能,实现固液分离,达到去除COD的目的.试验结果表明,生物产酸作用能有效地去除废水COD,改善其脱水性能.当体系pH降至3.00, COD去除率达到最大值91.4%,处理后的废水有很好的机械脱水和沉降性能,比阻从大于9.81×1013 m·kg-1降至5.60×1011 m·kg-1.而对照处理在整个培养期内,未发生明显的改变,仅有20%的COD被去除.本研究为油脂含量高、难被生物利用的有机废水提供了一条新的处理方法. 相似文献
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《Journal of environmental science and health. Part. B》2013,48(5):663-679
In order to remove high concentrations of hydrogen sulfide (H2S) gas from anaerobic wastewater treatments in livestock farming, a novel process was evaluated for H2S gas abatement involving the combination of chemical absorption and biological oxidation processes. In this study, the extensive experiments evaluating the removal efficiency, capacity, and removal characteristics of H2S gas by the chemical absorption reactor were conducted in a continuous operation. In addition, the effects of initial Fe2 + concentrations, pH, and glucose concentrations on Fe2 + oxidation by Thiobacillus ferrooxidans CP9 were also examined. The results showed that the chemical process exhibited high removal efficiencies with H2S concentrations up to 300 ppm, and nearly no acclimation time was required. The limitation of mass‐transfer was verified as the rate‐determining step in the chemical reaction through model validation. The Fe2 + production rate was clearly affected by the inlet gas concentration as well as flow rate and a prediction equation of ferrous production was established. The optimal operating conditions for the biological oxidation process were below pH 2.3 and 35°C in which more than 90% Fe3 + formation ratio was achieved. Interestingly, the optimal glucose concentration in the medium was 0.1%, which favored Fe2 + oxidation and the growth of T. ferrooxidans CP9. 相似文献
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酸性矿山废水(AMD)具有酸度高并含有大量可溶性Fe、硫酸根及重(类)金属的特点,采用生物矿化方法促使AMD中Fe向羟基硫酸铁次生矿物转变,对AMD后期石灰中和减少氢氧化铁和废石膏的产生,提高中和效率具有实际意义.通过模拟酸性矿山废水,考察了Cl-、NO3-、PO43-3种阴离子对嗜酸性氧化亚铁硫杆菌(A.ferrooxidans)体系中pH值、Fe2+氧化率、总Fe沉淀率、次生铁矿物矿相的影响.结果表明,高浓度阴离子对A.ferrooxidans氧化Fe2+能力具有抑制作用.A.ferrooxidans对阴离子的耐受性依次为PO43- > NO3- > Cl-.阴离子浓度在A.ferrooxidans耐受范围内时,其对Fe2+的生物氧化速率基本没有影响.但高浓度阴离子会通过抑制A.ferrooxidans的氧化活性,从而间接影响Fe3+的水解成矿过程,导致培养终点时总Fe沉淀率降低和次生铁矿物产量减少.受Fe3+供应速率降低的影响,次生铁矿物的合成途径易向施氏矿物转变. 相似文献
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氧化亚铁硫杆菌对亚铁离子的氧化及其动力学研究 总被引:6,自引:0,他引:6
采用9K培养基研究了氧化亚铁硫杆菌氧化Fe^2+过程中,pH和氧化还原电位的变化规律,并对Fe^2+的氧化过程进行动力学分析,确定了其反应级数及反应速率常数。结果表明,(1)在温度为30℃,摇床转速为150r/min的条件下,氧化亚铁硫杆菌的最佳接种量为10.0%;(2)Fe^2+初始质量浓度在11.39~21.72g/L时,随着浓度的增大,Fe^2+达到100%转化率需要的时间增加;(3)氧化亚铁硫杆菌对Fe^2+的氧化可近似看作一级反应,反应速率常数为0.0527~0.0788h。 相似文献
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微生物法烟气脱硫技术研究 总被引:34,自引:0,他引:34
采用微生物(氧化亚铁硫杆菌,简称TF菌)法脱除烟气中的二氧化硫。在相同操作条件下,比较了传统的工业化 方法稀硫酸吸收法(千代田法)与本法的优劣,研究了液气化、二氧化硫浓度、三价铁离子浓度等因素对吸收效率的影响;分析了脱硫反应前后吸收率pH值、三价铁离子浓度的变化。研究结果表明:适宜的液气比(12.5L/Nm^3 以上)、二氧化硫浓度(1000-5000ppm)和三价铁离子浓度(0.6g/L以上)能使该法具有较高(>98%)的脱硫率。在常温常压操作条件下,微生物法的脱硫率远优于千代田法,具有一定的工业化价值。 相似文献