用BaCl2滴定法快速测定硫酸盐的研究

用铬酸钡光度法、EDTA滴定法、间接原子吸收法、离子色谱法等方法测定SO42-检测上限都很低(12-200mg/L),且只适用于清洁水,若水样混浊则全引起较大的误差.有的地下水,SO42-浓度高达44000mg/L,用BaCl2滴定法测定SO42-:测试水样,以溴酚蓝做酸碱指示剂,加1∶50盐酸,调为pH=3.5,加入30ml异丙醇,以钍试剂做终点指示剂,滴加0.01mol/L BaCl2,砖红色为终点,根据BaCl2用量计算SO42-浓度.本方法快捷、准确、测定范围大,上限可达2000mg/L,克服了光度法测定浑浊水样引起误差大的缺点.     

应用添加剂烟气碳化处理回收碱渣

介绍应用ＹＪ添加剂碳化法处理炼油过程中的汽油、柴油、液化气碱渣，回收酚及环烷酸，并再生制取ＮａＯＨ稀碱液的工业实验，结果表明，此法在生产上可行，回收酚再生碱均达到产品质量标准     

Production of hydrogen by steam gasification of dehydrochlorinated poly(vinyl chloride) or activated carbon in the presence of various alkali compounds

Steam gasification of dehydrochlorinated poly(vinyl chloride) (PVC) or activated carbon was carried out in the presence of various alkali compounds at 3.0 MPa and 560°C–660°C in a batch reactor or in a semi-batch reactor with a flow of nitrogen and steam. Hydrogen and sodium carbonate were the main products, and methane and carbon dioxide were the minor products. Yields of hydrogen were high in the presence of sodium hydroxide and potassium hydroxide. The acceleration effect of the alkali compounds on the gasification reaction was as follows: KOH > NaOH > Ca(OH)₂ > Na₂CO₃. The rate of gasification increased with increasing partial steam pressure and NaOH/C molar ratio. However, the rate became saturated at a molar ratio of NaOH/C greater than 2.0.     

浅析电子废弃物回收利用及危害解决办法

随着高科技的发展和人们需求的增长,电子产品不断推陈出新,电子废弃物成为世界上数量增长最快的垃圾."电子垃圾",主要包括各种使用后废弃的电脑、通信设备、电视机、电冰箱、洗衣机等电子电器产品.电子废弃物不规范回收处理易造成污染.电子废弃物中含有很多可回收再利用的有色金属、黑色金属、玻璃等物质.严格意义上讲,这些电子废弃物,不应称其为电子垃圾,而应称作电子旧货.伴随着电子工业的高速发展,电子废弃物污染不可避免地摆在了我们面前.电子废弃物具有危害性和可利用性.     

Extraction of raw sewage sludge containing iron phosphate for phosphorus recovery

The objective of the present study was to establish an alkali extraction technology for FePO₄-containing sewage sludge obtained from a wastewater treatment system that includes phosphorous removal by iron electrolysis. By clarifying the extraction properties of phosphorous, organic matter, and inorganic matter, conditions for alkali extraction were optimized. As a result, it was suggested that unheated phosphorous extraction would be superior for FePO₄-containing sewage sludge. And, extraction methods and sewage sludge properties were also compared, and the noteworthy result that extraction of metals can be suppressed to extremely low amounts with alkali extraction as compared with acid extraction was obtained. A new insight was also gained that, as compared with the use of incinerated ash reported in previous studies, alkali extraction was more efficient when raw sewage sludge was used.     

Management plan for an alkali sink and its endangered plantCordylanthus palmatus

Cordylanthus palmatus is a hemiparasitic annual of the family Scrophulareacae. It is on both the federal and state lists of endangered species. Only four widely separated populations remain, all of them in alkali sinks, where the plant thrives in saline-sodic soils. The largest population is at Springtown, Alameda County, California. This article reports on efforts to develop a management plan for both the plant and the alkali sink ecosystem. The plan is based on: (1) characterization of hydrology, soils and geomorphology of the site; (2) characterization of the land use impacts to the site; (3) analysis of plant distribution in relation to gradients of elevation and soil chemistry; (4) studies on water potential and water stress inCordylanthus palmatus and associated species. On the basis of this plan, both the State of California and private groups are cooperating to create, restore, and manage a preserve in the Springtown Alkali Sink.     

Design training and aesthetic evaluation: An intergroup comparison

A number of studies have observed differences in the evaluation of visual, aesthetic stimuli between those with and without professional training in art and design. If exposure to design training underlies such differences it follows that evidence of training effects should be observable when comparing subjects at different stages of design training, and not observable when comparing subjects at different stages of non-design training. In addition, this evidence should be consistent with directional predictions. The study reported in this paper investigated this question using a sample of 192 trained and untrained subjects in an evaluative task. Subjects were from two departments (Design and Computer Studies) of the same educational establishment and comprised balanced groups of lecturers, 1st, 2nd and 3rd year undergraduate students. The results obtained demonstrated evaluative differences and patterns of association both within and between the subject groups consistent with a training hypothesis.     

公众环境意识与可持续发展关系初探

目前,国内存在的各种环境问题,归根到底是由于发展战略的不同所致,人们开始重新去认识和评价传统发展战略的局限性,标志着人类文明即将步入一个被称之"环境文明"新的历史时代.历史文化传统和经济发展水平决定公众环境意识,公众的环境意识直接影响可持续发展战略的实施,如何增强,提出决策和建议,通过大力开展环境宣传教育,提高公众环境意识,可持续发展,实现可持续发展的战略.     

Alkali resistance promotion of Ce-doped vanadium-titanic-based NH3-SCR catalysts

The effect of K deactivation on V_2O_5/WO_3-TiO_2 and Ce-doped V_2O_5/WO_3-TiO_2 catalysts in the selective catalytic reduction(SCR) of NOxby NH_3 was studied.Ce-doped V_2O_5/WO_3-TiO_2 showed significantly higher resistance to K deactivation than V_2O_5/WO_3-TiO_2.Ce-doped V_2O_5/WO_3-TiO_2 with K/V = 4(molar ratio) showed 90% NOxconversion at 350°C,whereas in this case V_2O_5/WO_3-TiO_2 showed no activity.The fresh and K-poisoned V_2O_5/WO_3-TiO_2 and Ce-doped V_2O_5/WO_3-TiO_2 catalysts were investigated by means of in situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS),NH_3-temperature progress decomposition(NH_3-TPD),X-ray photoelectron spectroscopy(XPS) and H2-temperature program reduction(H_2-TPR).The effect of Ce doping on the improving resistance to K of V_2O_5/WO_3-TiO_2 were discussed.     

聚四氟乙烯高压密封罐消解样品测定五氧化二钒

利用聚四氟乙烯高压密封罐消解矿石样品测定五氧化二钒,具有操作手续相对简便、轻松、快捷等优点,与传统的硫酸－磷酸混合酸消解或采用碱熔融前处理法比较,相对误差小于１．６％,样品的添加标准回收率为９２．９％～１０３．５％。