Sources, distribution, and risk assessment of organochlorine pesticides in Nairobi City, Kenya

The distribution and sources of organochlorine pesticides (OCPs) in air and surface waters were monitored in Nairobi City using triolein-filled semipermeable membrane devices (SPMDs). The SPMDs were extracted by dialysis using n-hexane, followed by cleanup by adsorption chromatography on silica gel cartridges. Sample analysis was done by GC-ECD and confirmed by GC–MS. Separation of means was achieved by analysis of variance, followed by pair-wise comparison using the t-test (p≤ 0.05). The total OCPs ranged between 0.018 – 1.277 ng/m³ in the air and <LOD – 1391.000 ng/m³ in surface waters. Based on the results, the means of Industrial Area, Dandora and Kibera were not significantly different (p≤ 0.05), but were higher (p≤ 0.05) than those of City square and Ngong’ Forest. The results revealed non-significant (p≤ 0.05) contribution of long-range transport to OCP pollution in Nairobi City. This indicated possible presence of point sources of environmental OCPs in the city. The water-air fugacity ratios indicated that volatilization and deposition played an important role in the spatial distribution of OCPs in Nairobi City. This indicated that contaminated surface waters could be major sources of human exposure to OCPs, through volatilization. The incremental lifetime cancer risks (ILCR) determined from inhalation of atmospheric OCPs were 2.3745  ×  10^?13 – 1.6845  ×  10^?11 (adult) and 5.5404  ×  10^?13 – 3.9306  ×  10^?11 (child) in the order: Dandora > Kibera > Industrial Area > City Square > Ngong’ Forest. However, these were lower than the USEPA acceptable risks, 10^?6 – 10^?4. This study concluded that atmospheric OCPs did not pose significant cancer risks to the residents.     

农业非点源污染环境影响及防治

非点源污染也称面源污染,因其污染的时空范围广,不确定性大,污染严重,对其治理及管理的难度也较大.由于化肥和农药的大量使用,农业非点源已成为中国水环境的主要污染源.文章中对农业非点源污染的特点、来源和危害进行了系统论述,并提出防治农业非点源污染的具体措施建议.     

Trace element speciation in selected smelter-contaminated soils in Anaconda and Deer Lodge Valley, Montana, USA

Long-term copper smelting in the Anaconda and Deer Lodge Valley area of Montana has resulted in an extensive area of trace element contamination. Aerial extent of contamination is generally established, but total analysis of soils does not correlate to relative degree of impact on vegetation growth. Three pedons (Beaverell, Cetrack and Judco) were analyzed by routine soil characterization methods, aqua regia microwave digestion, sequential chemical extraction, and X-ray diffraction analysis with the objective of providing a better understanding of chemical forms and potential reactivity of selected trace elements (Cd, Co, Cr, Cu, Hg, Mn, Ni, P, Pb). Surface horizons of soils are more acidic than subsoils, with pH for all horizons ranging from 4.0 to 8.7. Beaverell is the most contaminated in the upper 20 cm with the sum of total extractable (SUM_TE) trace elements by microwave digestion ranging from 1836 to 3605 mg kg⁻¹, largest H₂O-soluble (WS) and exchangeable (EX) fractions (e.g. 1.6 and 9.3%, respectively), and smallest residual (RES) fraction (e.g. 14.3%). Cetrack has greater SUM_TE elements than Judco, though a lower WS+EX fraction due to the effects of alkaline pH, carbonates and high P. Oxide (OX), organic matter/sulfide (OM/S), and RES fractions predominate over WS, EX, and specially-sorbed/carbonate-bound fractions (SS/CAR) for all horizons. Copper, Zn, Pb and Cd are elevated in surface over subsurface horizons in these latter fractions, indicating these elements were anthropogenic additions. X-ray data indicate that Pb, Cu, Cr and Cd partially exists as both OX and sulfide mineral forms.     

A Conceptual Framework for Selecting and Analyzing Stressor Data to Study Species Richness at Large Spatial Scales

/ In this paper we develop a conceptual framework for selectingstressor data and analyzing their relationship to geographic patterns ofspecies richness at large spatial scales. Aspects of climate and topography,which are not stressors per se, have been most strongly linked withgeographic patterns of species richness at large spatial scales (e.g.,continental to global scales). The adverse impact of stressors (e.g., habitatloss, pollution) on species has been demonstrated primarily on much smallerspatial scales. To date, there has been a lack of conceptual developmenton how to use stressor data to study geographic patterns of speciesrichness at large spatial scales.The framework we developed includes four components: (1) clarification of theterms stress and stressor and categorization of factors affecting speciesrichness into three groups-anthropogenic stressors, natural stressors, andnatural covariates; (2) synthesis of the existing hypotheses for explaininggeographic patterns of species richness to identify the scales over whichstressors and natural covariates influence species richness and to providesupporting evidence for these relationships through review of previousstudies; (3) identification of three criteria for selection of stressor andcovariate data sets: (a) inclusion of data sets from each of the threecategories identified in item 1, (b) inclusion of data sets representingdifferent aspects of each category, and (c) to the extent possible, analysisof data quality; and (4) identification of two approaches for examiningscale-dependent relationships among stressors, covariates, and patterns ofspecies richness-scaling-up and regression-tree analyses.Based on this framework, we propose 10 data sets as a minimum data base forexamining the effects of stressors and covariates on species richness atlarge spatial scales. These data sets include land cover, roads, wetlands(numbers and loss), exotic species, livestock grazing, surface water pH,pesticide application, climate (and weather), topography, and streams.KEY WORDS: Anthropogenic impacts; Biodiversity; Environmental gradients;Geographic information systems; Hierarchy     

“十一五”期间通辽市环境质量存在的主要问题及成因

本文通过对＂十一五＂期间通辽市环境质量监测数据的统计分析,从污染源和环境质量的关系得出存在的问题,从自然环境要素与生态环境两个角度总结＂十一五＂期间存在的问题。通过对环境质量的问题分析,寻找产生这些问题的原因,从而为改善环境质量提供解决的途径。     

东北地区臭氧预氧化对常规净水工艺效果分析

为检验臭氧预氧化在北方地区的效果,结合东北地区某微污染水源做出了分析和探索,发现臭氧氧化对净水处理效果良好。并全面阐述了微污染水源采用臭氧预氧化技术后带来的效果,可用于脱色除臭、控制氯化消毒副产物、去除藻类和藻毒素、助凝和助滤、初步去除或转化污染物,为相关的工程设计奠定了基础。     

Community participatory landscape classification and biodiversity assessment and monitoring of grazing lands in northern Kenya

In this study, we asked the Ariaal herders of northern Kenya to answer "why, what and how" they classified landscape, and assessed and monitored the biodiversity of 10 km(2) of grazing land. To answer the "why question" the herders classified grazing resources into 39 landscape patches grouped into six landscape types and classified soil as 'warm', 'intermediate' or 'cold' for the purpose of land use. For the "what question" the herders used soil conditions and vegetation characteristics to assess biodiversity. Plant species were described as 'increasers', 'decreasers' or 'stable'. The decreaser species were mostly grasses and forbs preferred for cattle and sheep grazing and the increasers were mostly woody species preferred by goats. The herders evaluated biodiversity in terms of key forage species and used absence or presence of the preferred species from individual landscapes for monitoring change in biodiversity. For the "how question" the herders used anthropogenic indicators concerned with livestock management for assessing landscape potential and suitability for grazing. The anthropogenic indicators were related to soils and biodiversity. The herders used plant species grazing preferences to determine the links between livestock production and biodiversity. By addressing these three questions, the study shows the value of incorporating the indigenous knowledge of herders into classification of landscape and assessment and monitoring of biodiversity in the grazing lands. We conclude that herder knowledge of biodiversity is related to the use as opposed to exclusive conservation practices. This type of knowledge is extremely valuable to conservation agencies for establishing a baseline for monitoring changes in biodiversity in the future.     

Historical change of mercury pollution in remote Yongle archipelago, South China Sea

We collected three ornithogenic coral sand sedimentary profiles from Jinyin Island, Jinqing Island and Guangjin Island of Yongle archipelago, South China Sea and reconstructed the deposition flux of anthropogenic Hg over the past 700 years in the study area. On the whole, the anthropogenic Hg flux is relatively low; it remained at a low level before the Industrial Revolution with a small peak at about 1450-1550 AD, which may record the enhanced metallurgy activity in Ming Dynasty of China. During the 20th century, the deposition flux of anthropogenic Hg increased rapidly, but two troughs occurred during the periods around 1940s and 1970s, corresponding to the economic depression caused by World War II, Civil War in China (1945-1949), and the Culture Revolution (1966-1976) in China. Since the 1970s the deposition flux of anthropogenic Hg has been persistently increasing, apparently the result of fast economic development in East and Southeast Asia countries around South China Sea.     

Emissions of biogenic VOC from forest ecosystems in central Europe: Estimation and comparison with anthropogenic emission inventory

This paper describes a method of estimating emission fluxes of biogenic volatile organic compounds (BVOCs) based on the approach proposed by Guenther et al. (1995) and the high-resolution Corine land-cover 2000 database (1 × 1 km resolution). The computed emission fluxes for the Czech Republic (selected for analysis as being representative of a heavily cultivated, central European country) are compared with anthropogenic emissions, both for the entire country and for individual administrative regions. In some regions, BVOC emissions are as high as anthropogenic emissions; however, in most regions the BVOC emissions are approximately 50% of the anthropogenic emissions. The yearly course of BVOC emissions (represented by monoterpenes and isoprene) is presented, along with the spatial distribution of annual mean values. Differences in emission distributions during winter (January) and summer (June) are also considered.     

Variation of low molecular weight organic acids in precipitation and cloudwater at high elevation in South China

To investigate the sources and chemical behaviors of carboxylic acids in Southern China, precipitation and corresponding cloudwater samples were collected in an acid rain-prone area of Mount Heng. The carboxylic acid levels in the samples were measured, and the concentration patterns were evaluated with respect to temporal and seasonal variations. Formic and acetic acids were predominant among the carboxylic acids identified for both precipitation and cloudwater. Most of the organic acids in the precipitation had a clear seasonal pattern, reaching higher levels during the warm season; these higher levels were attributed to the stronger source strength of biogenic emissions during this season. The cloud–fog samples did not display a similar trend. A distinctive diurnal pattern in carboxylic acids was only observed in the precipitation samples during the warm season. In cloud–fog, the ratio of formic to acetic acid differed considerably with time, with these values varying little in the precipitation samples. This result indicates that the organic acids in precipitation originate consistently from primary sources throughout the entire period, while those in cloud are mainly associated with direct emissions in the earlier stage and with secondary sources in the later period.