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1.
In this work,we fabricated three kinds of Ag/Fe_2O_3 model catalysts with different morphologies to study the interfacial interactions between Ag and Fe_2O_3,and how they affected the catalytic activity in hydrogenation of p-nitrophenol was explored.The hydrothermal method was used to synthesize the metal oxide supported silver catalyst,with various morphologies including nanoplates(NPs),nanospheres(NSs),and nanocubes(NCs).The crystal structure,morphology and surface elements of the composite were investigated by various measurements,such as X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM) and X-ray photoelectron spectroscopy(XPS).The catalytic activity was also evaluated by the reduction of p-nitrophenol to p-aminophenol.It was found that the activities of the above catalysts varied with the morphology of the support.Among them,Ag/Fe_2O_3 NPs promoted the highest performance,Ag/Fe_2O_3 NSs were slightly inferior,and Ag/Fe_2O_3 NCs were the worst.At last,we ascribed the remarkable activity of Ag/Fe_2O_3 NPs to the strong metal-support interactions between Ag and Fe_2O_3. 相似文献
2.
司志远 《环境监测管理与技术》1995,7(4):13-17
综述了预富集技术在无机痕量分析中的应用,概述了国内外最新进展,介绍了主要技术及方法的特点,大量文献表明预富集技术用于痕量分析取得满意的效果,降低了检测限,提高了灵敏度。 相似文献
3.
环境样品中痕量锰的催化动力学测定法 总被引:2,自引:0,他引:2
对环境样品中痕量锰的催化动力学测定方法进行简要评述,引述文献16篇。 相似文献
4.
此文介绍了一个用于数值模拟过程的二维图形界面,它由两大部分组成:“MANU”实现计算结果的手工操作显示及编辑,“AUTO”用于数值计算过程的自动跟踪.文中详细介绍了系统的设计方法、结构、工作原理和主要功能. 相似文献
5.
6.
催化燃烧法处理炼油污水处理场臭气 总被引:1,自引:0,他引:1
申屠灵女 《石油化工环境保护》2003,26(4):36-39
介绍了污水处理场臭气来源、危害和影响,从技术、经济和环境效益等方面对几种处理方法进行了比较,提出了采用催化燃烧法的技术实施方案。 相似文献
7.
《环境科学学报(英文版)》2023,35(3):319-331
Oxidation-absorption technology is a key step for NOx removal from low-temperature gas. Under the condition of low O3 concentration (O3/NO molar ratio = 0.6), F-TiO2 (F-TiO2), which is cheap and environmentally friendly, has been prepared as ozonation catalysts for NO oxidation. Catalytic activity tests performed at 120°C showed that the NO oxidation efficiency of F-TiO2 samples was higher than that of TiO2 (about 43.7%), and the NO oxidation efficiency of F-TiO2-0.15 was the highest, which was 65.3%. Combined with physicochemical characteristics of catalysts and the analysis of active species, it was found that there was a synergistic effect between F sites and oxygen vacancies on F-TiO2, which could accelerate the transformation of monomolecular O3 into multi-molecule singlet oxygen (1O2), thus promoting the selective oxidation of NO to NO2. The oxidation reaction of NO on F-TiO2-0.15 follows the Eley-Rideal mechanism, that is, gaseous NO reacts with adsorbed O3 and finally form NO2. 相似文献
8.
9.
The release process and influencing factors of bioactive iodine of kelp are systemically studied by leaching experiment. The results showed that the bioactive iodine of kelp can be released rapidly and the principal form of iodine in lixivium is I^- . There is a dynamic process between the release and absorption of iodine. With the increase of leaching water, the gross amounts of released iodine rise.There also exists a transforming process among I^- , IO3^- and organic iodine in lixivium. 相似文献
10.
《环境科学学报(英文版)》2023,35(4):517-530
Graphite carbon nitride has many excellent properties as a two-dimensional semiconductor material so that it has a wide application prospect in the field of photocatalysis. However, the traditional problems such as high recombination rate of photogenerated carriers limit its application. In this work, we introduce nitrogen deficiency into g-C3N4 to solve this problem a simple and safe in-situ reduction method. g-C3N4/CaCO3 was obtained by a simple and safe one-step calcination method with industrial-grade micron particles CaCO3. Cyano group modification was in-situ reduced during the thermal polymerization process, which would change the internal electronic structure of g-C3N4. The successful combination of g-C3N4 and CaCO3 and the introduction of cyanide have been proved by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer. The formation of the cyano group, an electron-absorbing group, promotes the effective separation of photogenic electron hole pairs and inhibits the recombination of photogenic carriers. These advantages result in the generation of more •O2− and 1O2 in the catalytic system, which increases the photocatalytic efficiency of nicotine degradation by ten times. Furthermore, the degradation process of nicotine has been studied in this work to provide a basis for the degradation of nicotine organic pollutants in the air. 相似文献