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1.
Reversible double water in oil in water (W/O/W) emulsions were developed to contain subsurface hydrocarbon spills during their remediation using surfactant flushing. Double emulsions were prepared by emulsifying CaCl2 solutions in canola oil, and subsequently by emulsifying the W/O emulsions in aqueous sodium alginate solutions. The formation of double emulsions was confirmed with confocal and optical microscopy. The double emulsions reversed and gelled when mixed with the surfactants sodium dodecyl sulfate (SDS) and cocamidopropyl betaine (CPB). Gels can act as ‘emulsion locks’ to prevent spreading of the hydrocarbon plume from the areas treated with surfactant flushing, as shown in sand column tests. Shear rheology was used to quantify the viscoelastic moduli increase (gelation) upon mixing the double emulsion with SDS and CPB. SDS was more effective than CPB in gelling the double emulsions. CPB and SDS could adsorb at the interface between water and model hydrocarbons (toluene and motor oil), lowering the interfacial tension and rigidifying the interface (as shown with a Langmuir trough). Bottle tests and optical microscopy showed that SDS and CPB produced W/O and O/W emulsions, with either toluene or motor oil and water. The emulsification of motor oil and toluene in water with SDS and CPB facilitated their flow through sand columns and their recovery. Toluene recovery from sand columns was quantitated using Gas-Chromatography Mass-Spectroscopy (GC-MS). The data show that SDS and CPB can be used both for surfactant flushing and to trigger the gelation of ‘emulsion locks’. Ethanol also gelled the emulsions at 100 mL/L. 相似文献
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此文采用三次多项式表示的流线速度场和基元圆环技术相结合的混合流动模型对国杯—多边形截面杆型复合挤压进行了上限分析,得到挤压力的上限解,分析了杆部截面形状对复合挤压分流点位置及变形力的影响规律并对理论计算进行了实验验证. 相似文献
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Much investigation supports a high incidence of disease and death rates when people live in ambient polluted air for a long time. Thus, the location of residential sites is important from a public health viewpoint. The method outlined in this paper is useful for determining the location of residential sites based on pollution sources assessment. 相似文献
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城市生活垃圾焚烧灰渣及其性质分析 总被引:25,自引:0,他引:25
2002年,上海有2座生活垃圾焚烧厂将点火运动。每年将产生约18万t左右的焚烧灰渣。在决定灰渣的最终处理处置方案前,应对焚烧灰渣的性质有全面的了解。详细介绍了国外城市生活垃圾焚烧灰渣甚至生位置的不同分类,并介绍了各类灰渣的物理化学性质和工程性质,以及其重金属的浸出特征。对灰渣处理放置或有效利用时需注意的问题作了分析。 相似文献
6.
Effects of planned expansion of waste incineration in the Swedish district heating systems 总被引:1,自引:0,他引:1
Recent targets for reduced amounts of waste to landfills in Sweden will result in a large increase in waste incineration with recovery of energy, used primarily for district heating. The aim of this study is to investigate what changes in the usage of other fuels and technologies for district heat production would be caused by this increase. A questionnaire was sent out to the largest district heating companies, and simulations in an energy systems model were carried out. The analysis shows that increased waste incineration reduces the demand for other fuels, especially biomass, for district heat production. The effects include reductions in operating hours as well as the avoidance or postponement of investments in new plants for district heat production. Increased waste incineration will also lead to a greater use of district heating in Sweden. 相似文献
7.
Status and fuzzy comprehensive assessment of combined heavy metal and organo-chlorine pesticide pollution in the Taihu Lake region of China 总被引:13,自引:0,他引:13
The status of combined heavy metal and organo-chlorine pesticide (OCPs; i.e. HCH and DDT) pollution was investigated and the soil environmental quality of the Taihu Lake watershed, one of the most developed regions in China, was evaluated using a fuzzy comprehensive assessment. Statistical analyses showed the presence of combined pollution in the soil. At many sampling sites, heavy metal concentrations were above corresponding background values, indicating the effects of extraneous pollutants. It has been over 20 years since China banned the use of OCPs, but they can still be found in soil samples of this region. HCH levels at all investigated sites were below the Chinese Environmental Quality Standard for Soils. Fuzzy comprehensive assessment showed that the overall soil quality in this region could be categorized as class I. Nevertheless, the high coefficients of variation for levels of DDT, Cd and Hg indicated the existence of some point-source pollution. Continuous monitoring and further studies of the region are recommended to prevent pollution of farmland from these sources. 相似文献
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为实现水资源的循环利用与国民经济的可持续发展,必须对工业废水进行处理。在过去的几十年中,工业废水的任意排放给水资源环境和人民的身体健康带来了巨大的危害,为了杜绝这种现象的再次出现,本文对工业废水的处理方法做了如下的探讨。 相似文献
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