全文获取类型
收费全文 | 261篇 |
免费 | 5篇 |
国内免费 | 48篇 |
专业分类
安全科学 | 4篇 |
废物处理 | 23篇 |
环保管理 | 12篇 |
综合类 | 145篇 |
基础理论 | 22篇 |
污染及防治 | 97篇 |
评价与监测 | 10篇 |
社会与环境 | 1篇 |
出版年
2023年 | 8篇 |
2022年 | 4篇 |
2021年 | 15篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 10篇 |
2017年 | 4篇 |
2016年 | 4篇 |
2015年 | 9篇 |
2014年 | 8篇 |
2013年 | 23篇 |
2012年 | 11篇 |
2011年 | 21篇 |
2010年 | 7篇 |
2009年 | 16篇 |
2008年 | 18篇 |
2007年 | 21篇 |
2006年 | 14篇 |
2005年 | 14篇 |
2004年 | 9篇 |
2003年 | 26篇 |
2002年 | 9篇 |
2001年 | 14篇 |
2000年 | 5篇 |
1999年 | 6篇 |
1998年 | 7篇 |
1997年 | 4篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1990年 | 1篇 |
排序方式: 共有314条查询结果,搜索用时 125 毫秒
1.
Gabriela P. Mendes Vivian M.A. Magalhães Lélia C.R. Soares Rayanne M. Aranh Claudio A.O. Nascimento Marilda M.G.R. Viann Osvaldo Chiavone-Filho 《环境科学学报(英文版)》2020,32(4):67-77
Chemical oxidation was applied to an artificially contaminated soil with naphthalene (NAP). Evaluation of NAP distribution and mass reduction in soil, water and air phases was carried out through mass balance. Evaluation of NAP distribution and mass reduction in soil, water and air phases was carried out through mass balance. The importance of the air phase analysis was emphasized by demonstrating how NAP behaves in a sealed system over a 4 hr reaction period. Design of Experiments method was applied to the following variables: sodium persulfate concentration [SP], ferrous sulfate concentration [FeSO4], and pH. The system operated with a prefixed solid to liquid ratio of 1:2. The following conditions resulted in optimum NAP removal [SP] = 18.37 g/L, [FeSO4] = 4.25 g/L and pH = 3.00. At the end of the 4 hr reaction, 62% of NAP was degraded. In the soil phase, the chemical oxidation reduced the NAP concentration thus achieving levels which comply with Brazilian and USA environmental legislations. Besides the NAP partitioning view, the monitoring of each phase allowed the variabilities assessment over the process, refining the knowledge of mass reduction. Based on NAP distribution in the system, this study demonstrates the importance of evaluating the presence of semi-volatile and volatile organic compounds in the air phase during remediation, so that there is greater control of the system as to the distribution and presence of the contaminant in the environment. The results highlight the importance of treating the contaminant in all its phases at the contaminated site. 相似文献
2.
As a novel alternative to traditional perfluoroalkyl substances (PFASs), including perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS), hexafluoroproplyene oxide trimer acid (HFPO-TA) has been detected worldwide in surface water. Moreover, recent researches have demonstrated that HFPO-TA has stronger bioaccumulation potential and higher hepatotoxicity than PFOA. To treat these contaminants e.g. PFOA and PFOS, some photochemical techniques by adding exogenous substances had been reported. However, there is still no report for the behavior of HFPO-TA itself under direct UV irradiation. The current study investigated the photo-transformation of HFPO-TA under UV irradiation in aqueous solution. After 72 hr photoreaction, 75% degradation ratio and 25% defluorination ratio were achieved under ambient condition. Reducing active species, i.e., hydrated electrons and active hydrogen atoms, generated from water splitting played dominant roles in degradation of HFPO-TA, which was confirmed by different effects of reaction atmospheres and quenching experiments. A possible degradation pathway was proposed based on the products identification and theoretical calculations. In general, HFPO-TA would be transformed into shorter-chain PFASs, including hexafluoropropylene oxide dimer acid (HFPO-DA), perfluoropropionic acid (PFA) and trifluoroacetate (TFA). This research provides basic information for HFPO-TA photodegradation process and is essential to develop novel remediation techniques for HFPO-TA and other alternatives with similar structures. 相似文献
3.
生活垃圾生物处理的研究与展望 总被引:2,自引:0,他引:2
综述了国内外生活垃圾生物处理的研究进展和目前生活垃圾微生物研究水平,以及生活垃圾处理发展趋势与新动向,在此基础上提出了生活垃圾处理的建议和展望。 相似文献
4.
5.
6.
7.
污染物的微生物毒性检验 总被引:2,自引:0,他引:2
从文献报导的10几种污染物毒性试验方法中,选择了脱氢酶活性、Microtox毒性、微生物呼吸率、以及降解动力学等4种方法,系统地比较,研究了其表示污染物对微生物的毒性效应的灵敏性,准确性,可靠性和实用性,研究结果应用于焦化废水、染化废水与黄浦江水样的检验表明,MTX方法能最好地反映污染物的微生物毒性,且操作简便,费时少,数据的解释也最为方便。 相似文献
8.
9.
4—氯苯甲酸钠的光催化氧化降解及其影响因素 总被引:8,自引:0,他引:8
本试验采用P-25TiO2,光催化剂,对4-氯苯甲酸钠的光催化氧化降解及污染物初始浓度,催化剂投加量和入射光强等因素的影响进行了研究,研究发现污染物初始降解速率与其初始浓度的关系遵循Langmuir-Hinshelwood模式,其中半饱和浓度常数Ks不仅是催化剂和污染物种类的函数,而且也是入射光强的函数,催化剂投加量存在一限值,当低于此限值时,污染物降解速率由于催化剂浓度的不足受到影响而下降,当高于此限值时,污染物降解速率受催化剂投加量的影响变小,在本试验4-CBA-Na浓度为0.15-0.6mmol/L时该催化剂限值浓度大约为0.4g/L,在入射光强为1-7mW/cm^2和催化剂浓度为0.4g/L下,污染物降解速率与光强成0.67次幂关系,经估算其量子效率为6.3%。 相似文献
10.
农药杀虫单的稻田流失规律研究 总被引:2,自引:0,他引:2
通过测坑、人工降雨等手段,对水溶性农药杀虫单的稻田消解动态、渗漏流失和径流流失等进行了研究。结果表明,(1)无水稻时,杀虫单在稻田水中消解的半衰期为0.76d;分蘖初期,杀虫单在稻田水中降解的半衰期为1.02d;平均为0.89d。(2)杀虫单的渗漏流失量在用药后8d内可达总用药量的7%—10%,平均为8.48%。(3)极端情况下,用药当天如果遇暴雨(50mm雨量),杀虫单的径流流失量将达到用药量的30%左右。杀虫单的渗漏损失不可避免,故其流失控制应从径流损失着手,尽量避免在可能有暴雨的当天或雨前1—2d用药。 相似文献