基于决策树的辽宁省北部沙漠化信息提取研究

以沙漠化问题较突出的辽宁省北部地区为例,选取2007年Landsat 5 TM遥感影像作为基本数据源,通过对影像中耕地、林地、草地、水域等常见地物及典型沙漠化土地进行光谱特征分析和波段间的相互运算,将修改型土壤调整植被指数（MSAVI）、归一化差异水体指数（NDWI）和遥感图像缨帽变换后的土壤亮度指数（SBI）、绿度植被指数（GVI）及湿度指数（WVI）等特征变量融入决策树分类模型后进行分层分离,从而实现对沙漠化信息的高精度提取。结果显示,决策树分类法可排除提取地物时的干扰信息,是保证沙漠化土地信息快速自动提取的方法之一。     

超越主奴模式,建构平等的人与自然关系

无论人类中心论还是自然中心论,所建构的人与自然关系图景都属于等级尊卑的主奴关系,一方为主,另一方为辅,这都不是人与自然的本真关系。马克思自然观的核心思想是人与自然是一个本质统一的整体,不可分割,这内在地蕴涵着人与自然拥有平等的价值地位。同时,人与自然也拥有平等的权利义务并公平交换其权利义务;人必然要消费自然资源.也必须供养环境;自然承担着养育人类的义务,也享有被人类保护的权利。     

Removal of polycyclic aromatic hydrocarbons from aqueous solution by raw and modified plant residue materials as biosorbents

Removal of polycyclic aromatic hydrocarbons （PAHs）, e.g., naphthalene, acenaphthene, phenanthrene and pyrene, from aqueous solution by raw and modified plant residues was investigated to develop low cost biosorbents for organic pollutant abatement. Bamboo wood, pine wood, pine needles and pine bark were selected as plant residues, and acid hydrolysis was used as an easily modification method. The raw and modified biosorbents were characterized by elemental analysis, Fourier transform infrared spectroscopy and scanning electron microscopy. The sorption isotherms of PAHs to raw biosorbents were apparently linear, and were dominated by a partitioning process. In comparison, the isotherms of the hydrolyzed biosorbents displayed nonlinearity, which was controlled by partitioning and the specific interaction mechanism. The sorpfion kinetic curves of PAHs to the raw and modified plant residues fit well with the pseudo second-order kinetics model. The sorption rates were faster for the raw biosorbents than the corresponding hydrolyzed biosorbents, which was attributed to the latter having more condensed domains （i.e., exposed aromatic core）. By the consumption of the amorphous cellulose component under acid hydrolysis, the sorption capability of the hydrolyzed biosorbents was notably enhanced, i.e., 6-18 fold for phenanthrene, 6-8 fold for naphthalene and pyrene and 5-8 fold for acenaphthene. The sorpfion coefficients （Kd） were negatively correlated with the polarity index [（O＋N）/C], and positively correlated with the aromaticity of the biosorbents. For a given biosorbent, a positive linear correlation between logKoc and logKow for different PAHs was observed. Interestingly, the linear plots of logKoc-logKow were parallel for different biosorbents. These observations suggest that the raw and modified plant residues have great potential as biosorbents to remove PAHs from wastewater.     

Photocatalytic activity of Fe-doped CaTiO3 under UV-visible light

The photocatalytic degradation of methylene blue（MB） over Fe-doped CaTiO3 under UV-visible light was investigated. The as-prepared samples were characterized using X-ray diffraction（XRD）, scanning electron microscope（SEM） equipped with an energy dispersive spectrometer（EDS） system, Fourier transform infrared spectra（FT-IR）, and UV-visible diffuse reflectance spectroscopy（DRS）. The results show that the doping with Fe significantly promoted the light absorption ability of CaTiO3 in the visible light region. The Fe-doped CaTiO3 exhibited higher photocatalytic activity than CaTiO3 for the degradation of MB.However, the photocatalytic activity of the Fe-doped CaTiO3 was greatly influenced by the calcination temperature during the preparation process. The Fe-doped CaTiO3 prepared at500°C exhibited the best photocatalytic activity, with degradation of almost 100% MB（10 ppm）under UV-visible light for 180 min.     

三峡蓄水前后宜昌–城陵矶水情多尺度变化特征分析

采用Morlet小波分解重构和频谱分析等方法,对宜昌、枝城、沙市、监利和城陵矶1997~2014年水位和流量及三峡水库2003~2014年入库、出库流量和库水位数据进行了统计分析,探究了各水文站在三峡建坝前后水情的变化特征及原因。结果表明:各观测站的水位和流量沿程递减,水位的年内波动处同一水平,研究河段内上游河段流量年内和年际变化比下游河段剧烈;各水文站水位和流量变化的显著周期为6.05、11.78、21.2、30.29和53个月,各水文站水位1 a周期变化幅度均在2 m以上,其他周期上的变化幅度为0.08~0.82 m;三峡水库蓄水活动对下游水文站水位和流量等水情的影响有限,主要反映在对水情趋势项的影响上,三峡大坝蓄水后,各水文站水位和流量受到一定程度影响,呈波动性递减变化。     

湖南省四水流域水沙周期特征及其影响因素分析

采用复小波变换和M K非参数检验的方法分析了湖南省四水流域主要控制站1951~2011年径流量与输沙量周期规律和突变特征。结果表明：(1)湖南四水径流量存在多个波动增加和波动减少的波动变化现象,但无显著变化趋势;而输沙量虽然有一定的波动,但总体上呈波动减少变化态势,而且下降趋势较显著;(2)湘潭站、桃江站和桃源站径流量和输沙量存在20~25 a的第一主周期,而石门站径流量和输沙量的第一主周期不具有一致性,径流量主周期为2 a,输沙量主周期为13 a,但其径流量和输沙量第二、三主周期变化规律相吻合,均为3~5 a的周期;(3)大量的水利工程建设是导致输沙量减少的主要原因,径流量的变化与降水的变化规律较为一致     

数据安全新思路

利用小波的时频局部化的特征,将信息的加密过程由传统的时域中进行改为在时域和频域中进行,达到信息加密和增强信息安全性的目的。采用两种方法实现信息的加密与解密的过程,一种是将明文保存为图像文件格式,对图像文件进行小波的分解与重构,实现信息的加密与解密;另一种是将明文数值化为一个系数矩阵,对数值矩阵进行小波的分解与重构,实现信息的加密与解密。通过小波分解过程进行加密,小波的重构过程进行解密,改变了传统的在空域中通过一系列的移位、迭代和置换的方式进行的加密过程,因此也不能通过传统的解密方式进行解密,增强了信息的安全性。由于小波的多样性,不同的小波变换得到的结果也会不同,增加了解密的难度,保证了数据的安全。     

职业安全卫生检测的新工具——傅里叶变换红外光谱技术

傅里叶变换光谱（ＦｏｕｒｉｅｒＴｒａｎｓｆｏｒｍＩｎｆｒａｒｅｄＳｐｅｃｔｒｏｐｈｏｔｏｍｅｔｒｙ—ＦＴＩＲ）技术是近２０年发展起来的一种全新、全能的技术,它是建立在计算机和激光技术的基础上,具有灵敏度高、信噪比高、测量速度快、分辨率高、应用范围广等优点。能够对多组分的复杂现场环境进行实时和连续定性、定量监测,又能够对气体、液体、固体、微区微量、表层表面进行分析,也能够进行远距离遥感检测。它将会在职业安全卫生检测领域发挥巨大作用,有着广阔的应用前景。     

Potential particulate pollution derived from UV-induced degradation of odorous dimethyl sulfide

UV-induced degradation of odorous dimethyl sulfide (DMS) was carried out in a static White cell chamber with UV irradiation. The combination of in situ Fourier transform infrared (FT-IR) spectrometer, gas chromatograph-mass spectrometer (GC-MS), wide-range particle spectrometer (WPS) technique, filter sampling and ion chromatographic (IC) analysis was used to monitor the gaseous and potential particulate products. During 240 min of UV irradiation, the degradation e ciency of DMS attained 20.9%, and partially oxidized sulfur-containing gaseous products, such as sulfur dioxide (SO2), carbonyl sulfide (OCS), dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO2) and dimethyl disulfide (DMDS) were identified by in situ FT-IR and GC-MS analysis, respectively. Accompanying with the oxidation of DMS, suspended particles were directly detected to be formed by WPS techniques. These particles were measured mainly in the size range of accumulation mode, and increased their count median diameter throughout the whole removal process. IC analysis of the filter samples revealed that methanesulfonic acid (MSA), sulfuric acid (H2SO4) and other unidentified chemicals accounted for the major non-refractory compositions of these particles. Based on products analysis and possible intermediates formed, the degradation pathways of DMS were proposed as the combination of the O(1D)- and the OH- initiated oxidation mechanisms. A plausible formation mechanism of the suspended particles was also analyzed. It is concluded that UV-induced degradation of odorous DMS is potentially a source of particulate pollutants in the atmosphere.