排序方式: 共有48条查询结果,搜索用时 15 毫秒
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微波消解ICP-AES法测定土壤中的金属元素研究 总被引:1,自引:0,他引:1
采用硝酸-盐酸-氢氟酸-双氧水作溶剂,通过微波消解技术、电感耦合等离子发射光谱法测定土壤中的锑、砷、铍、镉、铬、铜、铅、镍、硒、银、铊、锌,优化了微波消解仪和等离子发射光谱仪的工作参数,研究了共存离子的干扰和消除方法。优化后的微波消解酸体系及用量比例为HNO3∶HCl∶HF∶H2O2=5∶2∶3∶1,方法线性良好,各元素的检出限在0.000 2 mg/L~0.010 1 mg/L之间,土壤样品测定的标准偏差在0.001~0.051之间,加标回收率在85.5%~108.5%之间。该方法检出限低、精密度高、准确度好,测定结果令人满意。 相似文献
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电感耦合等离子体质谱法在环境监测中的应用 总被引:2,自引:0,他引:2
针对ICP-MS技术的使用特点及其近年来在环境监测领域的应用进行综合阐述,并对ICP-MS技术的发展前景作出简单的评述。 相似文献
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ICP/MS法测定酸雨中的Pb 总被引:2,自引:0,他引:2
采用 ICP/MS法分析酸雨中的 Pb元素 ,在优化的工作条件下 ,研究可能的干扰影响及选择合适的内标元素( Y89) ,同时测定 Pb的同位比以确定大气中 Pb的污染。 Pb的检出限 0 .0 0 2~ 0 .0 0 3ppb,相对标准偏差 0 .0 2 %~ 2 .0 1% 相似文献
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ICP-MS法同时测定地表水中18种金属元素 总被引:3,自引:1,他引:3
以115In-103Rh为双内标校正系统,采用电感耦合等离子体质谱法同时测定地表水中铜、锌、硒、砷、汞、镉、铅、铁、锰、钼、钴、铍、锑、镍、钡、钒、钛、铊等18种金属元素,优化了测量同位素、内标元素等试验条件。18种金属元素在0μg/L~100μg/L范围内线性良好,检出限为0.006μg/L~0.123μg/L,标准样品的测定值均在保证值范围内,平行测定的RSD为1.7%~4.2%,实际水样加标回收率为89.0%~100%。 相似文献
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徐州市生活垃圾填埋场地下水典型金属污染物研究 总被引:1,自引:0,他引:1
在对徐州地区生活垃圾填埋场调查分析的基础上,根据填埋特征和地质状况选取4座典型填埋场为调查对象,采用ICP-MS对垃圾渗滤液及地下水中26种重金属进行监测分析。结果表明,在4个垃圾填埋场地下水及渗滤液中ρ(Sr)均相对较高(700μg/L);地下水中金属元素均正在以Ca,Mg为主向Na,Mg为主转化;地下水中Al,B质量浓度大小顺序为Y场(雁群)S场(睢宁)C场(翠屏山)P场(邳州);4个垃圾填埋场共同典型重金属污染物为Mn,Fe,Zn,Ba;除上述污染物外,Y场地下水潜在典型重金属污染物为Pb和Mo;S场为Mo和As;C场为Tl和Co;P场为As。 相似文献
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Water-quality parameters and concentrations of various metals in bed sediments of the River Kali and the River Hindon in India were analysed to understand their behaviour in subtropical fluvial systems. Variations in the physico-chemical parameters of the river water and metal content in the bed sediments were recorded in four seasons of the year (post-monsoon, winter, summer and monsoon). Results show that water and sediments contain high cadmium (Cd) and Zinc (Zn). Total and soluble Cd and Zn profiles show that in summer, metals in the water phase exist predominantly in the bound form. Cd and Zn in bed sediments increase from the post-monsoon to the summer season. During and after the monsoon season, metal concentrations in sediments fall rapidly. Correlation coefficients of metals in sediments represent their common source and identical behaviour during transport. 相似文献
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Mari S. Golub Carl L. Keen Joel F. Commisso Charles B. Salocks T.R. Hathaway 《Environmental geochemistry and health》1999,21(3):199-209
A potentially high bioavailability of arsenic in gold mine tailings from a site in northern California has been suggested by solubility studies. To help address this issue, an in vivo dosing study was conducted using 12dayold Swiss Webster mouse pups (n=8/group). A sample of sizefractionated mine tailings from the site (<20m particle size, 691g g–1 arsenic) was prepared as an aqueous suspension and administered by gavage in a volume that provided 4mg As/kg body weight. The control group received the same volume of a commercial soil (1g g–1 As) of similar particle size (<60m). No mortality or toxic signs were noted in either group. Tissue samples were collected 1h after gavage, freezedried, microwavedigested and analysed for arsenic by ICP/MS (detection limit 2ng As g–1 dry weight). Arsenic concentrations (ng As g–1 dry weight) in tissues from the pups who received mine tailings were significantly higher than in control tissues. The mean elevation in arsenic concentration was highest in the liver (3364% of control, p<0.0001), followed by blood (818 of control, p<0.0001), skin (207% of control, p=0.07), and brain (143% of control, p<0.0001). The carcass arsenic concentration (excluding the GI tract, liver, brain and skin) was 138 of control (p=0.02). The data indicate uptake of arsenic from weathered mine tailings by the immature mouse pups after oral exposure. 相似文献
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采用微波消解-ICP-AES法测定底泥中的铜、镍等金属元素。通过实验和加标回收率的测定,回收率在88~102%之间。 相似文献
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