无机高分子铁钙铝混凝剂PFCA的研制及性能研究

复合型无机高分子混凝剂（ＩＰＣ）能进一步提高煤泥水的处理效果，降低有机高分子助凝剂的用量。本研究在合成得到β－ＰＦＳ溶液的基础上，引入钙铝离子共聚得到ＰＦＣＡ液体产品。含Ｆｅ＾３＋８％的ＰＦＣＡ液样通过添加晶种和活化剂的方式，极易制成偻剂产品。本文还运用透射电镜分析了ＰＦＣＡ与水中煤粒相互作用的机理。     

重金属螯合捕集剂NBMIPA的合成及其捕集Cu2+、Zn2+性能

以间苯二甲酰氯(IPC)和巯基乙胺盐酸盐(CHC)为原料,采用一步法合成重金属螯合捕集剂N,N’-双(2-巯基乙基)—1,3-苯二甲酰胺(NBMIPA),重点研究了物质的量比(n(CHC):n(IPC))和反应温度对NBMlPA产率的影响,并研究了NBMIPA投加量和pH对Cu2+、Zn2+捕集性能的影响.结果表明:重金属螯合捕集剂NBMIPA的最佳合成工艺为n(CHC):n(IPC) =2.8、反应温度-5℃,此时NBMIPA的最高产率为78.64％;NBMIPA对Cu2+和Zn2+的捕集性能优良,NBMIPA投加量越大,捕集性能越高;NBMIPA对pH具有较宽的适应性.当NBMIPA投加量分别为45 mL和30 mL时,NBMIPA对Cu2+和Zn2+的捕集效果最佳,Cu2+的去除率达到99.33％,残余Cu2+浓度为0.46 mg·L-1,Zn2+的去除率达到97.49％,残余Zn2+浓度为1.84 mg·L-1.     

制革污水处理控制系统设计

阐述了一种制革污水处理控制系统的设计方案。该方案中,工控机作为集中管理层,PLC作为现场控制层,电气设备作为远程设备层。详细阐述了该控制系统的上位机监控系统和下位机控制程序的开发过程。目前该系统已经成功投运,从经济成本、控制系统功能和现场的实际运行情况看,该控制系统具有经济性、先进性、可靠性等优点,对工业污水处理控制系统的设计具有一定的示范意义。     

The meaning of BATNEEC: interpreting excessive costs in UK industrial pollution regulation

The paper examines how the concept of ‘excessive costs’ has been interpreted in the implementation of industrial pollution control in the UK. Since 1984, industrial air pollution regulation in the EU has been guided by the framework concept of Best Available Technology Not Entailing Excessive Costs (BATNEEC). With the introduction of the Integrated Pollution Prevention and Control (IPPC) Directive in 1996, this has been replaced by the concept of Best Available Techniques (BAT). Despite the absence of the NEEC qualification, IPPC BAT includes excessive costs in its definition of ‘available’. Both concepts require interpretation and both devolve potentially controversial decisions to the level of the individual site regulator. A central issue in interpreting ‘excessive costs’ is the relative importance of environmental cost–benefit analysis versus the ability of a sector to ‘afford’ environmental improvements. Also important is how such concepts can be operationalized by regulators who lack resources and depend upon industry for information. The paper provides a historical account of how these issues have been dealt with in the UK and argues that the key difficulties are far from being resolved. The paper concludes by assessing the implications for the future implementation of IPPC. Copyright © 2002 John Wiley & Sons, Ltd.