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1.
Based on density functional theory (DFT) and basic structure models, the chemical reactions on the surface of vanadium-titanium based selective catalytic reduction (SCR) denitrification catalysts were summarized. Reasonable structural models (non-periodic and periodic structural models) are the basis of density functional calculations. A periodic structure model was more appropriate to represent the catalyst surface, and its theoretical calculation results were more comparable with the experimental results than a non-periodic model. It is generally believed that the SCR mechanism where NH3 and NO react to produce N2 and H2O follows an Eley-Rideal type mechanism. NH2NO was found to be an important intermediate in the SCR reaction, with multiple production routes. Simultaneously, the effects of H2O, SO2 and metal on SCR catalysts were also summarized. 相似文献
2.
流行病学调查结果表明,环境的极低频电磁场暴露与人群某些肿瘤,如白血病、乳腺癌、脑肿瘤等,以及生殖、神经、心血管和内分泌等系统疾患的发病相关,这些结果在一定程度上得到实验室人体测试的支持。然而,极低频电磁场对健康影响的确切效应,迄今尚未能作出结论,亟等进一步开展多层次、多水平的研究。 相似文献
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4.
环境监测实验室的检测结果直接为环境管理、污染治理等环保部门提供服务,因此检测数据的准确性十分重要。本文通过对影响环境监测实验室检测结果的因素人、机、料、法、环五个方面入手,详尽地研究这五个方面对检测结果的影响。 相似文献
5.
采用冷原子吸收法,使用便携式测汞仪对实验室空气中汞的浓度进行测定,监测结果表明,环境监测实验室空气中汞的污染较为严重,主要来源于COD、氨氮、大气中氨及汞样品测定时含汞试剂及汞标液的使用和含汞废液的排放。根据对监测结果的评价和分析提出了相应的防治措施,提醒实验室的管理及分析人员,要增强环境保护意识,加强实验室的管理,减少含汞及其它有毒废液的排放,改善实验室的环境空气质量,保护分析人员的身体健康。 相似文献
6.
环境监测实验室质量监督之管见 总被引:3,自引:0,他引:3
郭晓茆 《环境监测管理与技术》2007,19(6):1-3
阐述了环境监测实验室质量监督的重要性及加强质量监督的组织保证、制度建设、工作程序和如何发挥监督作用的思考,以期改善忽视质量监督的局面,进一步提高监测工作质量. 相似文献
7.
环境监测实验室废液的管理与处理方法 总被引:2,自引:0,他引:2
徐根红 《环境监测管理与技术》2007,19(6):50-51
环境监测实验室的废液处理常常被忽视,提出建立有效的废液管理制度的必要性.有针对性地介绍了环境监测实验室中常见废液的处理方法. 相似文献
8.
This study focuses on the verification of test interpretations for different state analyses of diffusion experiments. Part 1 of this study identified that steady, quasi-steady and equilibrium state analyses for the through- and in-diffusion tests with solution reservoirs are generally feasible where the tracer is not highly sorptive. In Part 2 we investigate parameter identifiability in transient-state analysis of reservoir concentration variation using a numerical approach. For increased generality, the analytical models, objective functions and Jacobian matrix necessary for inverse analysis of transient-state data are reformulated using unified dimensionless parameters. In these dimensionless forms, the number of unknown parameters is reduced and a single dimensionless parameter represents the sorption property. The dimensionless objective functions are evaluated for individual test methods and parameter identifiability is discussed in relation to the sorption property. The effects of multiple minima and measurement error on parameter identifiability are also investigated. The main findings are that inverse problems for inlet and outlet reservoir concentration analyses are generally unstable and well-posed, respectively. Where the tracer is sorptive, the inverse problem for the inlet reservoir concentration analysis may have multiple minima. When insufficient measurement data is collected, multiple solutions may result and this should be taken into consideration when inversely analyzing data including that of inlet reservoir concentration. Verification of test interpretation by cross-checking different state analyses is feasible where the tracer is not highly sorptive. In an actual experiment, test interpretation validity is demonstrated through consistency between theory and practice for different state analyses. 相似文献
9.
根据实验室资质认定对于方法确认的要求,结合环境监测实验室的特点,提出了新项目方法确认的具体步骤,并分析了其中存在的常见问题。指出在方法确认过程中,应严格按照标准方法和监测技术规范进行全过程试验,尤其不能忽视采样现场实验、空白实验和检出限的测定。建议在精密度与准确度检验过程中,使用高、中、低不同浓度的有证标准样品,实际样品加标回收,比对试验(方法比对、人员比对、实验室间比对),增加分析次数等多种手段,确保新项目开展的可靠性。 相似文献
10.
Travis C Obenshain KR Gunter JT Regens JL Whipple C 《Environmental science and pollution research international》2004,11(5):302-306
GOAL, SCOPE AND BACKGROUND: This paper uses two case studies of U.S. Department of Energy nuclear weapons complex installations to illustrate the integration of expedited site characterization (ESC) and multimedia modeling in the remedial action decision making process. CONCEPTUAL SITE MODELS, MULTIMEDIA MODELS, AND EXPEDITED SITE CHARACTERIZATION: Conceptual site models outline assumptions about contaminates and the spatial/temporal distribution of potential receptors. Multimedia models simulate contaminant transport and fate through multiple environmental media, estimate potential human exposure via specific exposure pathways, and estimate the risk of cancer and non-cancer health outcomes. ESC relies on using monitoring data to quantify the key components of an initial conceptual site model that is modified iteratively using the multimedia model. CASE STUDIES: Two case studies are presented that used the ESC approach: Los Alamos National Laboratory (LANL) and Pantex. LANL released radionuclides, metals, and organic compounds, into canyons surrounding the facility. The Pantex Plant has past waste management operations which included burning chemical wastes in unlined pits, burying wastes in unlined landfills, and discharging plant wastewaters into on-site surface waters. CONCLUSIONS: The case studies indicate that using multimedia models with the ESC approach can inform assessors about what, where, and how much site characterization data needs to be collected to reduce the uncertainty associated with risk assessment. Lowering the degree of uncertainty reduces the time and cost associated with assessing potential risk and increases the confidence that decision makers have in the assessments performed. 相似文献