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1.
Zihao Li Yang Geng Lei Ma Xiaoyin Chen Junhua Li Huazhen Chang Johannes W. Schwank 《Frontiers of Environmental Science & Engineering》2020,14(4):65
2.
Laboratory batch and column experiments were conducted to investigate the immobilization of phosphorus (P) in soils using synthetic magnetite nanoparticles stabilized with sodium carboxymethyl cellulose (CMC-NP). Although CMC-stabilized magnetite particles were at the nanoscale, phosphorus removal by the nanoparticles was less than that of microparticles (MP) without the stabilizer due to the reduced P reactivity caused by the coating. The P reactivity of CMC-NP was effectively recovered when cellulase was added to degrade the coating. For subsurface non-point P pollution control for a water pond, it is possible to inject CMC-NP to form an enclosed protection wall in the surrounding soils. Non-stabilized “nanomagnetite” could not pass through the soil column under gravity because it quickly agglomerated into microparticles. The immobilized P was 30% in the control soil column, 33% when treated by non-stabilized MP, 45% when treated by CMC-NP, and 73% when treated by both CMC-NP and cellulase. 相似文献
3.
It has been shown that starch can effectively stabilize nanoscale magnetite particles, and starch-stabilized magnetite nanoparticles (SMNP) are promising for in situ remediation of arsenic-contaminated soils. However, a molecular level understanding has been lacking. Here, we carried out XAFS studies to bridge this knowledge gap. Fe K-edge XAFS spectra indicated that the Fe-O and Fe-Fe coordination numbers of SMNP were lower than those for bare magnetite particles, and these coordination numbers decreased with increasing starch concentration. The decrease in the average coordination number at elevated stabilizer concentration was attributed to the increase in the surface-to-volume ratio. Arsenic K-edge XAFS spectra indicated that adsorbed arsenate on SMNP consisted primarily of binuclear bidentate (BB) complexes and monodentate mononuclear (MM) complexes. More BB complexes (energetically more favorable) were observed at higher starch concentrations, indicating that SMNP not only offered greater adsorption surface area, but also stronger adsorption affinity toward arsenate. 相似文献
4.
研究硬脂酸改性磁铁矿对石油污水中油类物质的吸附,通过改变温度、超声振荡时间和磁铁矿与硬脂酸的质量比等因素,在最佳的改性条件下制得改性磁铁矿。将改性后的磁铁矿应用于石油污水处理,改变震荡时间,用红外分光测油仪得出吸附结果。结果表明:当改性温度为35℃、改性时间为35min、硬脂酸与磁铁矿质量比为3.5%时磁铁矿改性效果最佳,当吸附时间为8min时,对石油炼化污水中油类物质的吸附效果最好,吸附量为216.65mg/g。 相似文献
5.
Animals make use of the Earth’s magnetic field for navigation and regulation of vegetative functions; however, the anatomical
and physiological basis for the magnetic sense has not been elucidated yet. Our recent results from histology and X-ray analyses
support the hypothesis that delicate iron-containing structures in the skin of the upper beak of homing pigeons might serve
as a biological magnetometer. Histology has revealed various iron sites within dendrites of the trigeminal nerve, their arrangement
along strands of axons, the existence of three dendritic fields in each side of the beak with specific 3D-orientations, and
the bilateral symmetry of the whole system. Element mapping by micro-synchrotron X-ray fluorescence analysis has shown the
distribution of iron and its quantities. Micro-synchrotron X-ray absorption near-edge-structure spectroscopy has allowed us
to unambiguously identify maghemite as the predominating iron mineral (90 vs 10% magnetite). In this paper, we show that iron-based
magnetoreception needs the presence of both of these iron minerals, their specific dimensions, shapes, and arrangements in
three different subcellular compartments. We suggest that an inherent magnetic enhancement process via an iron-crusted vesicle
and the attached chains of iron platelets might be sufficient to account for the sensitivity and specificity required by such
a magnetoreceptor. The appropriate alignment between the Earth’s magnetic field and the maghemite bands would induce a multiple
attraction of the magnetite bullets perpendicular to the membrane, thus, triggering strain-sensitive membrane channels and
a primary receptor potential. Due to its 3D architecture and physicochemical nature, the dendritic system should be able to
separately sense the three vector components of the Earth’s local field, simultaneously—allowing birds to detect their geographic
position by the magnetic vector, i.e., amplitude and direction of the local magnetic field, irrespective of the animal’s posture
or movement and photoreception. 相似文献
6.
Muhammad Kashif Shahid Yunjung Kim Young-Gyun Choi 《Frontiers of Environmental Science & Engineering》2019,13(5):71
7.
B.K. Singh Aishwarya Jain Sumit Kumar B.S. Tomar Radha Tomar V.K. Manchanda S. Ramanathan 《Journal of contaminant hydrology》2009,106(3-4):144-149
Sorption of 137Cs, 90Sr, 154Eu and 141Ce by magnetite has been studied at varying pH (4 to 11) in the presence and absence of humic acid. The sorption studies have also been carried out at varying ionic strength (0.01 to 0.2 M NaClO4) and humic acid concentration (2 to 20 mg/L). Percentage sorption of 137Cs and 90Sr was found to be pH dependent, with the sorption increasing with increasing pH of the suspension. At any pH, the percentage sorption of 90Sr was higher than that of 137Cs. The results have been explained in terms of the electrostatic interaction between the positively charged metal ions and the surface charge of the magnetite which becomes increasingly negative with increasing pH. On the other hand, 154Eu and 141Ce were found to be strongly sorbed by the magnetite at all pH values, with the sorption being independent of pH. The strong sorption of trivalent and tetravalent metal ions suggests the role of complexation reactions during sorption, apart from the electrostatic interactions. However, in the case of 141Ce surface precipitation of Ce(III) formed by reduction of Ce(IV) in the presence of magnetite cannot be ruled out. Presence of humic acid (2 mg/L) was found to have negligible effect on sorption of all metal ions. 相似文献
8.
Heike Hildebrand Dana Kühnel Katrin Mackenzie Kristin Schirmer 《Environmental pollution (Barking, Essex : 1987)》2010,158(1):65-73
Palladium/magnetite nanoparticulate catalysts were developed for efficient elimination of halogenated organic pollutants from contaminated wastewater. Particle recovery from treated water can be ensured via magnetic separation. However, in worst-case scenarios, this catalyst removal step might fail, leading to particle release into the environment. Therefore, a toxicological study was conducted to investigate the impact of both pure magnetite and palladium/magnetite nanoparticle exposure upon human skin (HaCaT) and human colon (CaCo-2) cell lines and a cell line from rainbow trout gills (RTgill-W1). To quantify cell viability after particle exposure, three endpoints were examined for all tested cell lines. Additionally, the formation of reactive oxygen species was studied for the human cells. The results showed only minor effects of the particles on the tested cell systems and support the assumption that palladium/magnetite nano-catalysts can be implemented for a new wastewater treatment technology in which advantageous catalyst properties outweigh the risks. 相似文献
9.
Meng Zhu Yuhuan He Xiaobao Wei Haoran Qi Yunpeng Zhang Yijun Zhang Ruyi Yang Yongming Luo 《Frontiers of Environmental Science & Engineering》2022,16(9):115
10.
磁铁矿区河流沉积剖面中磁化率与重金属含量相关性分析 总被引:1,自引:0,他引:1
选择广东省铁帽顶铁矿区下游一河流沉积剖面为研究对象,测定沉积物的磁化率与元素含量并作相关性分析,以考察磁铁矿床周边沉积物磁化率指标对重金属富集程度的指示作用。结果显示,该剖面中低频质量磁化率χlf为0. 87×10-6m~3/kg~184. 93×10-6m~3/kg,频率磁化率χfd为0. 5%~7%。χlf仅与Fe2O3呈现极显著的正相关关系,与其他重金属元素相关性差;χfd与Mn、Pb、Cd及REE均呈正相关;元素Cu、Zn、As等与χlf、χfd的相关性都很差。表明在该种磁化率和重金属元素含量背景值均高的特殊地区,简单地利用磁化率指标指示重金属污染水平需谨慎。 相似文献