A nonstationary time-series model is used to examine the changes occurring at sampling stations on the Chicago Sanitary and Ship Canal. Using data from upstream sampling sites, downstream levels of dissolved oxygen, total dissolved solids, nitrates and nitrites, and ammonia are accurately predicted. The method is simple, insensitive to extreme values, and responsive to changes in the system. 相似文献
Chiral pesticides comprise a new and important class of environmental pollutants nowadays. With the development of industry, more and more chiral pesticides will be introduced into the market. But their enantioselective ecotoxicology is not clear. Currently used synthetic pyrethroids, organophosphates, acylanilides, phenoxypropanoic acids and imidazolinones often behave enantioselectively in agriculture use and they always pose unpredictable enantioselective ecological risks on non-target organisms or human. It is necessary to explore the enantioselective toxicology and ecological fate of these chiral pesticides in environmental risk assessment. The enantioselective toxicology and the fate of these currently widely used pesticides have been discussed in this review article. 相似文献
The oxygenated species, massively produced in the energy production plants based on combustion processes, constitute one of the most numerous categories of hazardous air pollutants. Therefore, development of real time diagnostic tools are needed in order to study their formation during combustion processes and to reveal their presence both in the exhaust and in the atmosphere. In this work, oxygenated compounds were identified inside fuel-rich premixed ethylene/air flames by means of ultraviolet fluorescence spectroscopy with the support of qualitative chemical analysis of the sampled combustion gases.
Strong band progression, typical of aldehydic functionality, were recognized in fluorescence spectra (λexc=355 nm) measured in the early oxidation region of premixed flames varying the equivalence ratio from 3.0 up 21.6. Downstream of the oxidation region, spectroscopic signatures of pyrolytic species were found to prevail on those peculiar of oxygenated compound. The position and the extension of the two main flame zones were found to depend on the flame conditions (C/O ratio) due to the effect of the C/O ratio on the temperature history along the flame axis. This correlation was interpreted on the basis of the measured axial temperature profiles. 相似文献
Mixtures can be divided into simple (chemicals with comparable properties—health risk assessments on the chemicals) and complex,
which can be further subdivided into defined (a reasonably distinct composition, created at a specific time and place despite
dissimilar components—risk assessments on the common source) and coincidental (chemicals without similar properties or constant
composition in time or space—risk assessments on the receptor). Interactions recognized are: independent action, dose addition
(additivity), and potentiation (synergy and antagonism). Unpredicted outcomes need recognition. New approaches in higher education
and multidisciplinary investigations are essential. The community of the Society for Environmental Geochemistry and Health
should help clarify points such as when transformations in mixtures may become important enough to alter the classification
and the risk assessment. The multidisciplinary community is also well placed to support the integration of nonchemical influences
into mixture analysis and to contribute to the investigation of cumulative and multiple exposures. 相似文献