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溶胶-凝胶法制备TiO2膜光催化降解偏二甲肼的研究 总被引:5,自引:0,他引:5
以钛酸四丁酯为原料采用溶胶-凝胶法制备了纳米TiO2/玻璃膜光催化剂,用于光催化氧化降解水中偏二甲肼,其降解反应为一级动力学反应。实验结果表明,与悬浮型TiO2相比,TiO2膜具有较高的催化活性,且不易脱落,可重复使用。涂覆6-8次得到的TiO2膜效果较好。 相似文献
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硫化物溶液标准物质的研究 总被引:3,自引:0,他引:3
研究了硫化钠配制标准溶液不稳定的原因,制备出稳定一年的硫化物溶液标准物质.它均匀,定值结果准确,浓度范围50~100μg/ml(S2-计). 相似文献
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综采工作面安全性评价的逼近理想解(TOPSIS)方法 总被引:8,自引:2,他引:6
基于熵权的TOPSIS(逼近理想解的排序方法)方法是一种新的安全性评价方法,该方法以灰熵理论确定评价指标的权重———熵权,从而避免低层次多因素权重确定的主观性。以评价对象与理想解和负理想解的距离确定的相对接近度作为评价准则,避免了评价方法的主观性。通过对平顶山煤业集团有限责任公司六矿综采工作面安全性进行的评价,指出综采工作面安全管理中存在的问题,并提出相应的改进措施。理论与实例表明,该方法较其他方法更加客观,更易于操作,结果也更符合生产实际。 相似文献
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Titania nanomaterial with an anatase structure and 5.6 nm crystallite size and 280.7 m2 g−1 specific surface areas had been successfully prepared by sol–gel/hydrothermal route. The effect of pH as a type of autoclave and calcination was studied. Crystallite size and phase composition of the prepared samples were identified. X-ray diffraction analyses showed the presence of anatase with little or no rutile phases. The crystallite size of the prepared TiO2 with acidic catalyst was both smaller than that prepared with basic catalyst, and was increasing after acidic calcinations by a factor 4–5. Basic calcinations produced a specific increase of 1.5. Rutile ratio and the particle size were increased after calcination at 500 °C. However, TiO2 powder synthesized using a basic catalyst persisted the anatase phase and a loosely aggregation of particles. Anatase TiO2 as prepared with acidic catalyst in Teflon lined stainless steel autoclave demonstrated the highest photocatalytic activity for degradation of 2,6-dichlorophenol-indophenol under ultraviolet irradiation with t½ 0.8 min. 相似文献
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The results of studies carried out using a computer programme simulating the coagulation of suspensions containing spherical sol particles and spherical coagulant particles are reported.The influence of the degree of dispersion of the system on the coagulation reaction kinetics was investigated. The obtained results of kinetic studies were tested in the light of classical Müller–Smoluchowski equations. The influence of the physical properties of the coagulant,such as size, density and mass, on the coagulation rate was tested. It was found that within the range described in this paper, the rate of the simulated coagulation process fulfils both the kinetic equation of a first-order reaction, and the kinetic equation of a second-order reaction.Within the tested range, a significant influence of the mass and size of the coagulant on the coagulation rate was ascertained. The kinetic Müller–Smoluchowski dependence is fulfilled in a broader range of the degree of dispersion, when the coagulant particle mass and the sol particle mass are equal. When the particle mass increases with an increase in the particle radius, the coagulation rate increases faster that it would result from the Müller's dependence. 相似文献
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