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排序方式: 共有57条查询结果,搜索用时 15 毫秒
1.
Effect of microbial siderophore DFO-B on Cd accumulation by Thlaspi caerulescens hyperaccumulator in the presence of zeolite 总被引:1,自引:0,他引:1
Hyperaccumulators are grown in contaminated soil and water in order that contaminants are taken up and accumulated. Transport of metals from soil to plant is initially dependent on the solubility and mobility of metals in soil solution which is controlled by soil and metal properties and plant physiology. Complexation with organic and inorganic ligands may increase mobility and availability of metals for plants. In this work the influence of desferrioxamine-B (DFO-B), which naturally is produced in the rhizosphere, and zeolite on Cd accumulation in root and shoot of Thlaspi caerulescens (Cd hyperaccumulator) was investigated. Plants were grown in pots with clean quartz sand, amended with 1% zeolite; treatment solutions included 0, 10, and 100 μM Cd and 70 μM DFO-B. Addition of zeolite to the quartz sand significantly reduced Cd concentration in plant tissues and translocation from root to shoot. On contrary, DFO-B considerably enhanced Cd sorption by roots and translocation to aerial part of plants. Treating the plants with zeolite and DFO-B together at 10 μM Cd resulted in reduction of the bioaccumulation factor but enhancement of Cd translocation from root to shoot at the rate of 13%. In contrast, at 100 μM Cd in the solution both bioaccumulation and translocation factors decreased. Total metal accumulation as a key factor for evaluating the efficiency of phytoremediation was highly influenced by treatments. Presence of zeolite in pots significantly decreased total Cd accumulation by plants, whereas, DFO-B clearly enhanced it. 相似文献
2.
The antimicrobial activity of Cu2O, ZnO and NiO nanoparticles supported onto natural clinoptilolite was investigated in the secondary effluent under dark conditions. After 24 h of contact the Cu2O and ZnO nanoparticles reduced the numbers of viable bacterial cells of Escherichia coli and Staphylococcus aureus in pure culture for four to six orders of magnitude and showed consistent 100% of antibacterial activity against native E. coli after 1 h of contact during 48 exposures. The antibacterial activity of NiO nanoparticles was less efficient. The Cu2O and NiO nanoparticles showed 100% of antiprotozoan activity against Paramecium caudatum and Euplotes affinis after 1 h of contact, while ZnO nanoparticles were less efficient. The morphology and crystallinity of the nanoparticles were not affected by microorganisms. The metal oxide nanoparticles could find a novel application in the disinfection of secondary effluent and removal of pathogenic microorganisms in the tertiary stage of wastewater treatment. 相似文献
3.
Panax notoginseng (Burk.) F.H. Chen, a rare traditional Chinese medicinal herb, is a widely used phytomedicine used all over the world. In recent years, the arsenic contamination of the herb and its relative products becomes a serious problem due to elevated soil As concentration. This study aimed to evaluate the effects of different types and dosages of amendments on As stabilization in soil and its uptake by P. notoginseng. Results showed that comparing to control treatment, the As concentrations of P. notoginseng declined by 49–63%, 43–61% and 52–66% in 0.25% zero-valent iron (Fe(0)), 0.5% bauxite residue, and 1% zeolite treatment, respectively; whereas the biomasses were elevated by 62–116%, 45–152% and 114–265%, respectively. The As(III) proportions of P. notoginseng increased by 8%, 9%, and 8%, and the transfer factors of As from root to shoot increased by 37%, 42% and 84% in the optimal treatments of Fe(0), bauxite residue, and zeolite. For soil As, all the three amendments could transform the non-specifically adsorbed As fraction to hydrous oxides Fe/Al fractions (by Fe(0) and red mud) or specifically adsorbed As fraction (by zeolite), therefore reduced the bioavailability of soil As. With a comprehensive consideration of stabilization efficiency, plant growth, environmental influence, and cost, Fe(0) appeared to be the best amendment, and zeolite could also be a good choice. In conclusion, this study was of significance in developing As contamination control in P. notoginseng planting areas, and even other areas for medicinal herb growing. 相似文献
4.
The elemental mercury removal abilities of three different zeolites (NaA, NaX, HZSM-5) impregnated with iron (III) chloride were studied on alab-scale fixed-bed reactor. X-ray diffraction, nitrogen adsorption porosimetry, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and temperature programmed desorption (TPD) analy-ses were used to investigate the physicochemical properties. Results indicated that the pore structure and active chloride species on the surface of the samples are the key factors for physisorption and oxidation of Hg0, respectively. Relatively high surface area and micropore volume are beneficial to efficient mercury adsorption. The active Cl species generated on the surface of the samples were effective oxidants able to convert elemental mercury (Hg0) into oxidized mercury (Hg2+). The crystallization of NaCl due to the ion exchange effect during the impregnation of NaA and NaX reduced the number of active Cl species on the surface, and restricted the physisorption of Hg0. Therefore, the Hg0 removal efficiencies of the samples were inhibited. The TPD analysis revealed that the species of mercury on the surface of FeCl3-HZSM-5 was mainly in the form of mercuric chloride(HgCl2), while on FeCl3-NaX and FeCl3-NaA it was mainly mercuri coxide(HgO). 相似文献
5.
氮、磷是引发水体富营养化的限制性因素,控制水体中的氮、磷总量可以有效抑制水体富营养化的产生。以人造沸石为研究对象,探究不同改性方法对人造沸石同步去除水中氮、磷的影响。主要工艺为高温碱(NaOH)浸改善沸石结构,高温盐浸(MgCl)负载纳米态氧化镁。结果表明改性的最佳条件为:两阶段的烘干温度45℃;NaOH溶2+3-液浓度0.5 mol/L;MgCl溶液的浓度1 mol/L。对NH-N和PO的去除效率分别可达到83.76%和74.24%。对人造沸石2 4 4的热稳定性进行了实验,其烧失量达40.6%。最后,对吸附饱和的人造沸石进行脱附实验,脱附剂的选择为NaCl、KCl以及+3-两者的混合液。NaCl对NH4+-N和PO43-都有较为明显的脱附效果,脱附率分别可达84.54%和59.35%。 相似文献
6.
利用粉煤灰合成Linde type F(K)沸石吸附重金属Zn2+,考察吸附剂量、pH值、反应温度对Zn 2+吸附效果影响,研究沸石吸附Zn2+的等温线与动力学,得到了相应的模型。结果表明:吸附剂量、pH值、反应温度均对Zn2+去除效果影响显著。随着吸附剂量增大,Zn 2+去除效果不断提高,饱和吸附量逐渐减小。初始pH值为3~7时,沸石对Zn2+去除率随pH值升高迅速提高。反应温度越高,沸石吸附Zn2+到达平衡时间越短。沸石对Zn2+吸附过程符合Langmuir吸附等温式,其吸附为单分子层吸附;准二级反应动力学方程能很好描述沸石对Zn2+的吸附行为。 相似文献
7.
不同填料人工湿地处理系统的净化能力研究 总被引:50,自引:0,他引:50
研究了沸石、沸石-石灰石、石灰石3种填料的人工湿导的净化能力。结果表明:(1)沸石和石灰石混合使用,不会降低沸石吸附氨氮的能力;(2)沸石可促使难溶性P的释放,使得石灰石吸附P被植物和微生物吸收利用;(3)沸石和石灰石发生了协同作用,对TN、TP的去除效果均好于其单独使用。 相似文献
8.
This work presents an unconventional procedure for the recovery of spent Al-rich caustic soda solutions from the pickling of dies for the production of aluminium extrusions. Caustic soda was regenerated at roughly 70%, by precipitating aluminate, after addition of a silica source, in the form of zeolite A, a microporous material that is widely used in many technological sectors. It was shown that the process is reliable and can be repeated for several cycles, provided the concentration of the caustic soda solution is suitably restored. The by-product obtained, zeolite A, proved to be a high-grade material with performance as a cation exchanger and physical sorbent that is certainly comparable to that reported in literature (e.g., cation exchange capacity equal to 5.14 meq g(-1) vs. 5.48 meq g(-1) and water vapour adsorption capacity of 26.5% vs. 27.6% at 16 torr and 298 K). The economics of the process, although not examined yet, would appear generally favourable, considering that zeolite A is a valuable by-product which widely covers the costs for the recovery of the spent solutions. There are, therefore, significant prospects for the use of zeolite A, particularly as a builder in detergent formulation. 相似文献
9.
10.
Jing Chen Jia Zeng Yiran He Shiquan Sun Haipeng Wu Yaoyu Zhou Zhenguo Chen Jianhui Wang Hong Chen 《环境科学学报(英文版)》2023,35(3):160-170
Simultaneous anammox and denitrification(SAD) is an efficient approach to treat wastewater having a low C/N ratio; however, few studies have investigated a combination of SAD and partial nitritation(PN). In this study, a lab-scale up-flow blanket filter(UBF) and zeolite sequence batch reactor(ZSBR) were continuously operated to implement SAD and PN advantages, respectively. The UBF achieved a high total nitrogen(TN) removal efficiency of over 70% during the start-up stage(days 1–50), and reached... 相似文献