室内空气和灰尘中全(多)氟烷基化合物的研究进展

全(多)氟烷基化合物(per(poly)fluoroalkyl substances,PFASs)在环境各个介质及人体样品中广泛被检出,近年,在室内空气和灰尘中也普遍发现PFASs.研究表明,室内空气中PFASs的含量普遍高于室外空气,室内空气和灰尘中的PFASs可能是室外空气的污染来源及人体暴露源,因此室内环境中PFASs成为环境领域的又一个研究热点.但目前为止,我国还没有开展室内空气中PFASs的相关研究,室内灰尘中PFASs的研究也相对较少.本文就室内空气和灰尘中PFASs的采样与分析方法、污染现状、来源分析及人体暴露等4个方面进行了综合阐述,以期为我国室内环境中PFASs的研究提供参考.     

Analysis of the Trend and Seasonal Cycle of Carbon Monoxide Concentrations in an Urban Area (4 pp)

Background, Aim and Scope Air quality is an field of major concern in large cities. This problem has led administrations to introduce plans and regulations to reduce pollutant emissions. The analysis of variations in the concentration of pollutants is useful when evaluating the effectiveness of these plans. However, such an analysis cannot be undertaken using standard statistical techniques, due to the fact that concentrations of atmospheric pollutants often exhibit a lack of normality and are autocorrelated. On the other hand, if long-term trends of any pollutant’s emissions are to be detected, meteorological effects must be removed from the time series analysed, due to their strong masking effects. Materials and Methods The application of statistical methods to analyse temporal variations is illustrated using monthly carbon monoxide (CO) concentrations observed at an urban site. The sampling site is located at a street intersection in central Valencia (Spain) with a high traffic density. Valencia is the third largest city in Spain. It is a typical Mediterranean city in terms of its urban structure and climatology. The sampling site started operation in January 1994 and monitored CO ground level concentrations until February 2002. Its geographic coordinates are W0°22′52″ N39°28′05″ and its altitude is 11 m. Two nonparametric trend tests are applied. One of these is robust against serial correlation with regards to the false rejection rate, when observations have a strong persistence or when the sample size per month is small. A nonparametric analysis of the homogeneity of trends between seasons is also discussed. A multiple linear regression model is used with the transformed data, including the effect of meteorological variables. The method of generalized least squares is applied to estimate the model parameters to take into account the serial dependence of the residuals of this model. This study also assesses temporal changes using the Kolmogorov-Zurbenko (KZ) filter. The KZ filter has been shown to be an effective way to remove the influence of meteorological conditions on O₃ and PM to examine underlying trends. Results The nonparametric tests indicate a decreasing, significant trend in the sampled site. The application of the linear model yields a significant decrease every twelve months of 15.8% for the average monthly CO concentration. The 95% confidence interval for the trend ranges from 13.9% to 17.7%. The seasonal cycle also provides significant results. There are no differences in trends throughout the months. The percentage of CO variance explained by the linear model is 90.3%. The KZ filter separates out long, short-term and seasonal variations in the CO series. The estimated, significant, long-term trend every year results in 10.3% with this method. The 95% confidence interval ranges from 8.8% to 11.9%. This approach explains 89.9% of the CO temporal variations. Discussion The differences between the linear model and KZ filter trend estimations are due to the fact that the KZ filter performs the analysis on the smoothed data rather than the original data. In the KZ filter trend estimation, the effect of meteorological conditions has been removed. The CO short-term componentis attributable to weather and short-term fluctuations in emissions. There is a significant seasonal cycle. This component is a result of changes in the traffic, the yearly meteorological cycle and the interactions between these two factors. There are peaks during the autumn and winter months, which have more traffic density in the sampled site. There is a minimum during the month of August, reflecting the very low level of vehicle emissions which is a direct consequence of the holiday period. Conclusions The significant, decreasing trend implies to a certain extent that the urban environment in the area is improving. This trend results from changes in overall emissions, pollutant transport, climate, policy and economics. It is also due to the effect of introducing reformulated gasoline. The additives enable vehicles to burn fuel with a higher air/fuel ratio, thereby lowering the emission of CO. The KZ filter has been the most effective method to separate the CO series components and to obtain an estimate of the long-term trend due to changes in emissions, removing the effect of meteorological conditions. Recommendations and Perspectives Air quality managers and policy-makers must understand the link between climate and pollutants to select optimal pollutant reduction strategies and avoid exceeding emission directives. This paper analyses eight years of ambient CO data at a site with a high traffic density, and provides results that are useful for decision-making. The assessment of long-term changes in air pollutants to evaluate reduction strategies has to be done while taking into account meteorological variability     

The Thermal Discharges From Nuclear Power Plants in Taiwan

The increasing use of sea water for industrial cooling presents a real threat to the ecological environment in the ocean. in Taiwan where many electric power plants along the coast take sea water for cooling, people are concerned seriously about nuclear power plants. There are three nuclear power plants in Taiwan. Each plant has two units for generating power. the first two are located along the northern coast of Taiwan. the third is located in Kenting National Park along the coast of southernmost Taiwan. the plants take sea water for cooling, and discharge their heated effluents to the ocean surface from the coast. the thermal effluents have variable effects on the ecological environment near the plants. Fishermen living near the power plants complain that the heated water affects the inshore fishery catch. in addition, the thermal water from the second plant is easily accumulated near the coastal zone to influence the nearby swimming area in the summer-time. the thermal water from the third plant bleaches or kills some corals in shallow water near the outlet, and this conflicts with the interests of Kenting National Park.     

Effects of landscape homogeneity on starling roost distribution

The possible effects of landscape structure on starling roost distribution were investigated in western France using GIS analysis at different radii (2, 4, 8 and 10 km). Composition (11 land use classes) and configuration (patch size, diversity index) of the landscapes surrounding 97 roost sites used by starlings from 1981 to 2002 and surrounding 50 random points not used as roost sites were compared. Significant results suggested that starling roosts were established preferentially in the centre of an agricultural landscape where large units of pastures and arable land predominated and where natural areas were lacking both in large patches (forests or wetland classes) and in small patches such as woods in the mixed land class. A varied farmland landscape with natural areas and small patches should be promoted to limit the starling damage in wintering regions and also to favour their reproduction in regions where it has declined.     

共振腔消声器在煤矿风井噪声治理中的应用

对煤矿风井噪声产生的机理与特性进行了分析，提出了用共振腔消声器治理风井噪声的新方法，详细阐述了该方法所依据的理论基础，并以应用实例加以说明。     

Influence of new town development on the urban heat island - The case of the Bundang area

Five new towns have been developed around the Seoul metropolitan area since 1996. However, these new towns generate lots of traffic and related problems in the areas including those new towns and Seoul as a result of increases in population and a lack of ecological-self-sufficiency. Currently, construction of another new town is under deliberation, and what should be a major consider is the notion that the new town be located within a wide, green zone. Many studies have revealed that green space can play an important role in improving urban eco-meteorological capability and air quality. In order to analyze the urban heat island which will be created by the new urban development, and to investigate the local thermal environment and its negative effects caused by a change of land use type and urbanization, Landsat TM images were used for extraction of urban surface temperature according to changes of land use over the last 15 years. These data are analyzed together with digital land use and topographic information. As a study result, it was found the urban heat island of the study area from 198.5 to 1999 rapidly developed which showed a difference of mean temperature above 2.0. Before the Bundang new town construction the temperature of the residential area was the same as a forest, but during the new town construction in 1991 analysis revealed the creation of an urban heat island. The temperature of a forest whose size is over 50% of the investigation area was lowest, and thus the presence of a forest is believed to have a direct cooling effect on the urban environment and its surroundings. The mean temperature of the residential and commercial areas in the study was found to be 4.5 higher than the forest, and therefore this part of land use is believed to be the main factor causing the temperature increase of the urban heat island.     

嘉定城区河流水质现状评价及污染防治对策

通过对嘉定中心城区河流的水质现状调查和评价，提出了引清排污、加强市政措施等污染防治对策。     

风向变化对城市大气污染的影响及试验分析

针对城市大气污染的复杂多变状况，在理论分析的基础上，通过风洞实验对城市大气污染扩散模型进行了模拟试验研究，建立了适合一定条件下城市大气污染物扩散的数学和物理模型，并对城市大气污染状况的影响因素进行了分析，在得到特定条件下城市大气污染扩散普遍规律的同时，重点讨论了风向变化对城市大气污染的影响，该方法同时还可以应用于城市大气污染物扩散浓度的估算。     

滤膜法测定空气中氟化物的改进

测定环境空气中微量氟的方法一般采用滤膜法，但此法工作量大，针对这种情况，本文作两点改进：一是将采集的两张滤膜同时测定；二是将测定过程中的搅拌时间缩短，这样不影响测定结果的准确性，而且降低了工作量。     

乌鲁木齐空气微生物含量的测定

用自然平皿沉降法对乌鲁木齐市13个室内外空气测点作了微生物含量的测定,结果表明平均室外空气的细菌、真菌、总菌含量及F/T%分别为28583 8、780 5、29364 3CFU·m-3及2 7,证实了该市空气处于中度微生物污染状态。少量测点显示其空气已受到严重污染,空气质量不佳。室内空气微生物污染也重。空气微生物污染以细菌为主。分析了室外空气微生物含量的时空分布特点差异,探讨了其成因,并与其他城市作了比较。文章指出增强环境忧患意识,采用切实而有效措施,减少环境污染的必要性。