全文获取类型
收费全文 | 1089篇 |
免费 | 105篇 |
国内免费 | 646篇 |
专业分类
安全科学 | 75篇 |
废物处理 | 94篇 |
环保管理 | 94篇 |
综合类 | 1006篇 |
基础理论 | 320篇 |
污染及防治 | 202篇 |
评价与监测 | 27篇 |
社会与环境 | 20篇 |
灾害及防治 | 2篇 |
出版年
2024年 | 9篇 |
2023年 | 32篇 |
2022年 | 54篇 |
2021年 | 53篇 |
2020年 | 49篇 |
2019年 | 58篇 |
2018年 | 47篇 |
2017年 | 49篇 |
2016年 | 49篇 |
2015年 | 76篇 |
2014年 | 88篇 |
2013年 | 127篇 |
2012年 | 115篇 |
2011年 | 114篇 |
2010年 | 86篇 |
2009年 | 86篇 |
2008年 | 81篇 |
2007年 | 95篇 |
2006年 | 94篇 |
2005年 | 62篇 |
2004年 | 73篇 |
2003年 | 51篇 |
2002年 | 35篇 |
2001年 | 47篇 |
2000年 | 32篇 |
1999年 | 41篇 |
1998年 | 24篇 |
1997年 | 21篇 |
1996年 | 12篇 |
1995年 | 23篇 |
1994年 | 16篇 |
1993年 | 12篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 1篇 |
1989年 | 4篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有1840条查询结果,搜索用时 15 毫秒
1.
测试了两种消石灰与垃圾焚烧烟气中HCl的反应率,得出了消石灰的反应率与反应时间的反应曲线,分析了消石灰与HCl的反应机理及影响消石灰最终反应率的因素。试验结果表明,消石灰与HCl反应初期按灰层扩散控制进行,两种消石灰的最终反应率分别为16%和36%。 相似文献
2.
Caroline C. MBA 《Environmental management》1994,18(2):257-261
Four microbial isolates, OP2, OP3, OP6, and OP7, of earthworm casts ofPontoscolex corethrurus were found to be acid tolerant actinomycetes and efficient rock phosphate (RP) solubilizers that could grow fast on NH4Cl-enriched or N-free carboxymethyl cellulose or glucose as sole carbon source.
CMC (carboxymethyl cellulose) induced production of extracellular cellulase enzyme and the production of reducing sugar in
all the isolates. RP solubilizing power was observed to be inversely related to glucose consumption. The most efficient RP
solubilizer was found to consume the least glucose.
Growth was faster on cellulose than on glucose media. N-free CMC induced greater glucose production than NH4Cl-enriched CMC medium. Both CMC and glucose media were acidified by all the isolates, however, RP solubilizing power decreased
with acidification. Solubilization power was greatest with isolate OP7, which also produced the greatest amount of reducing
sugar per gram CMC. Both RP solubilizing power and the cellulolytic efficiency varied among isolates. A minimum of 631 μg
P/0.1 g RP and a maximum of 951.4 μg P/0.1 g RP was recorded. 相似文献
3.
Qiuyi Ji Huan He Zhanqi Gao Xiaohan Wang Shaogui Yang Cheng Sun Shiyin Li Yong Wang Limin Zhang 《环境科学学报(英文版)》2020,32(12):55-61
Tri(2-chloroethyl) phosphate (TCEP) with the initial concentration of 5 mg/L was degraded by UV/H2O2 oxidation process. The removal rate of TCEP in the UV/H2O2 system was 89.1% with the production of Cl? and PO43? of 0.23 and 0.64 mg/L. The removal rate of total organic carbon of the reaction was 48.8% and the pH reached 3.3 after the reaction. The oxidative degradation process of TCEP in the UV/H2O2 system obeyed the first order kinetic reaction with the apparent rate constant of 0.0025 min?1 (R2=0.9788). The intermediate products were isolated and identified by gas chromatography-mass spectrometer. The addition reaction of HO? and H2O and the oxidation reaction with H2O2 were found during the degradation pathway of 5 mg/L TCEP in the UV/H2O2 system. For the first time, environment risk was estimated via the “ecological structure activity relationships” program and acute and chronic toxicity changes of intermediate products were pointed out. The luminescence inhibition rate of photobacterium was used to evaluate the acute toxicity of intermediate products. The results showed that the toxicity of the intermediate products increased with the increase of reaction time, which may be due to the production of chlorine compounds. Some measures should be introduced to the UV/H2O2 system to remove the highly toxic Cl-containing compounds, such as a nanofiltration or reverse osmosis unit. 相似文献
4.
选取湖南省浏阳市某Cd污染稻田进行田间试验,研究组配改良剂石灰石+海泡石(LS)、基施硅肥及叶面喷施硅肥对Cd污染稻田修复效果,结果表明:(1)基施硅肥90kg/hm2和叶面喷施硅肥(0.2,0.4g/L)对土壤pH值无明显影响,添加LS(2250,4500kg/hm2)的各处理均显著提高土壤pH值(P < 0.05).(2)基施硅肥90kg/hm2分别降低土壤交换态、毒性特征浸出(TCLP)提取态Cd含量20.0%和18.5%,叶面喷施硅肥对土壤Cd两种提取态含量无明显影响,添加LS的各处理(2250,4500kg/hm2)分别使土壤交换态、TCLP提取态Cd含量降低25.8%~49.9%、26.4%~44.5%.(3)3种单一技术措施均能明显降低水稻各部位Cd含量,但降低糙米中Cd含量的效果低于3种技术措施的组合处理;“组配改良剂LS+基施硅肥+叶面喷施硅肥”各处理(JL1F1、JL1F2、JL2F1、JL2F2)使水稻糙米中Cd含量降低25.6%~70.5%.(4)“组配改良剂LS+基施硅肥+叶面喷施硅肥”的组合技术处理能显著降低土壤中Cd的有效性,显著降低水稻各部位中Cd含量,其中JL2F2处理效果最佳,能使对照糙米Cd含量从0.66mg/kg降低到0.19mg/kg,实现中重度Cd污染稻田的水稻安全生产. 相似文献
5.
目的研究AZ61镁合金中合金元素成分分析过程中的不确定度因素,以提高分析结果的准确性。方法采用微波消解仪消解样品,以电感耦合等离子体发射光谱仪(ICP-OES)测定AZ61镁合金中锌、锰、铝元素的含量。分析测试过程中产生不确定度的因素,并且进行评定和计算。结果采用微波消解-ICP-OES法测定镁合金中锌、锰、铝元素的含量时,测量不确定度主要由样品溶液稀释、移液枪、标准曲线以及测试的重复性引起,AZ61镁合金主要的合金成分为锌(1.1270%±0.0433%)、锰(0.1797%±0.0064%);铝(6.4468%±0.2029%)。结论对分析过程中产生的不确定度因素进行分析及评定,可以确保分析结果的可靠性以及准确性,从而更好地控制镁合金的性能,提高镁合金的装备环境适应性。 相似文献
6.
D. M. Whelpdale P. W. Summers E. Sanhueza 《Environmental monitoring and assessment》1997,48(3):217-247
This paper presents a summary of globalacid deposition flux data taken from a globalassessment report on acid deposition prepared forUNEP/WMO (Whelpdale and Kaiser, 1996). There is a largevariation in the spacial coverage and reliability ofmonitoring around the world. Many more stationsmeasure wet deposition than collect appropriate datafor estimating dry deposition. The widespread regionswith highest precipitation concentrations anddeposition fluxes of sulphate and nitrate coincideclosely with the regions of highest density ofSO2 and NOx precursor emissions occurringprimarily in the mid-latitude, northern hemispherebelt where a large fraction of the worlds fossilfuels is consumed. Organic acids in precipitation makea minor contribution to acidity (<20%) inindustrial regions, but in the rest of the world theyare of same order, or even exceed, inorganic acids.Less is known about dry deposition, but it appears topredominate near strong emission sources with wetdeposition predominating farther downwind. The molarratio of the N/S contribution to acidic deposition isclose to 1.0 over large areas of Europe and NorthAmerica, but is highly variable elsewhere, beinghighest in equatorial regions due to biomass burningand lowest near smelters and other large sources of SO2. 相似文献
7.
氨基酸法现场快速测定废水中的磷酸盐 总被引:3,自引:0,他引:3
通过磷酸盐与钼酸盐、氨基酸反应使样品呈淡蓝色,讨论了在事故现场快速测定水中磷的方法。试验表明方法灵敏,操作简单快速。检测范围0~15mg/L。 相似文献
8.
Controlled-release fertilizer(CRF):A green fertilizer for controlling non-point contamination in agriculture 总被引:9,自引:0,他引:9
Fertilizers contribute greatly to high yields but also result in environmental non-point contamination, including the emission of greenhouse gas(N2O) and eutrophication of water bodies. How to solve this problem has become a serious challenge, especially for China as its high ecological pressure. Controlled-release fertilizer(CRF) has been developed to minimize the contamination while keeping high yield and has become a green fertilizer for agriculture. Several CRFs made with special coating technology were used for testing the fertilizer effects in yield and environment through pot experiment and field trial. The result indicated that the CRFs had higher N use efficiency, thus reducing N loss through leaching and volatilization while keeping higher yields. Comparing with imported standard CRFs,the test on CRFs showed similar fertilizer effect but with much lower cost. CRFs application is becoming a new approach for minimizing non-point contamination in agriculture. 相似文献
9.
10.
烟气脱硫副产物的综合利用 总被引:4,自引:0,他引:4
本文通过分析烟气脱硫石膏的性能,介绍了脱硫石膏的利用情况和研究进展,利用脱硫石膏生产建筑材料,如建筑石膏和高强石膏的工艺越来越成熟,利用脱硫石膏生产水泥辅料已进入工业化,而利用脱硫石膏生产充填尾砂胶结剂已经完成试验阶段,利用脱硫石膏生产路基回填材料,脱硫石膏在农业上也有广泛的用途。 相似文献