Acid Deposition in the Tuscan Appennines During the Dry Period 1988-89

The typical parameters of acid precipitation are evaluated in the forest of Vallombrosa (Tuscan Appennines) during the dry period 1988-89. Individual rain events (dry and wet deposition) were sampled in a clearing of the forest and below the canopy of an evergreen tree as well as a deciduous broadleaf tree.

In atmospheric precipitation the pH values usually vary around 4.4, with neutralization in the hot season due to calcareous material from distant sources. Relatively large concentrations of Pb and Cd are found in rain, but only in a small amount in canopy leachate. Aluminium, manganese and iron are more significantly washed off than Pb and Cd.     

焚烧飞灰重金属含量及浸出长期变化规律研究

通过对24个飞灰样品的重金属全量消解和高精度X射线荧光光谱法（HDXRF）快速检测结果进行线性回归分析,发现HDXRF法可较准确测定飞灰中Cu、Pb、Zn、Ni和Cd含量（线性回归决定系数R²³0.90）.采用HDXRF法对某焚烧厂飞灰重金属含量6个月快速检测及浸出毒性测定数据统计分析发现：飞灰重金属月均含量较稳定（变异系数CV<0.14）但日均含量波动较大（CV>2.54）;飞灰中Pb、Cu和Zn含量呈正相关（相关系数r>0.78）;金属浸出浓度受浸出液终点pH值影响显著,超标频率依次为Pb（68.9%）、Cd（66.1%）、Ni（24.0%）、Cu（14.2%）和Zn（1.6%）.短期飞灰金属含量和浸出毒性数据受焚烧工况,烟气处理工况和垃圾组分等多种因素共同影响,不具有代表性.为评估垃圾分类源头削减重金属效果,建议采用快速检测方法对焚烧飞灰重金属含量进行长期监测.     

钴（Ⅱ）－过氧化氢－苯基荧光酮体系催化光度法测定痕量钴的研究

本文研究了钴（Ⅱ）催化过氧化氢氧化苯基荧光酮的褪色反应，测定了反应级数和表观活化能，建立了测定痕量地的新方法。２５℃时本法检出限为２９×１０－１３ｇ／ｍｌ，线性范围为０．０４～２ｎｇ／１０ｍｌ，催化反应表观活化能为５６．１５ＫＪ／ｍｏｌ。该方法己用于维生素Ｂ１２、人发和茶叶中痕量钴的测定．结果满意，相对标准偏差为２．４～３．４％。     

空气颗粒物中铅、镉超声浸取-原子吸收测定方法研究

用超声波震荡方法对大气滤膜样品进行前处理,提取待测元素。研究了浸取液种类、酸度、浸取时间和干扰因素等,确定了颗粒物样品溶液制备的最佳条件,与流动注射在线富集——原子吸收技术结合,建立了大气颗粒物样品测定Pb、Cd方法。结果表明,方法快速、准确,标准样品测定回收率在97％以上,6次测定方目对标准偏差小于2.6％。     

Effects of simulated acid rain on cation release in soils of South China

This paper deals with the release of base cations and Al3+ at the treatment with simulated acid rain (SAR) in main soil types collected from South China. Results showed that the amounts of base cations increased obviously when the pH value of simulated acid rain was lower than 3.0 or 3.5. Compared with the leaching of K+ and Na+, the leaching of Ca2+ and Mg2+ was affected by the pH value of SAR. Only when the amounts of base cations leached from soils exceeded the cation exchange capacity, the pH value of leaching solutions decreased sharply and the amounts of released Al3+ increased. The H+ buffering mechanisms, which were affected notonly by the pH values of SAR, but also by the types and solid components of soils, were proposed for the main soils studied.     

SBR工艺处理城市垃圾渗滤液的可行性分析

在参考国内外垃圾渗滤液的处理方案后，选择厌氧预处理 SBR工艺作为处理方案，通过实验对该废水处理的情况来看，该工艺较好地适应了垃圾渗滤液的处理特点，能达到比较良好的效果。     

Cobalt in alluvial Egyptian soils as affected by industrial activities

ＩｎｔｒｏｄｕｃｔｉｏｎＩｎｎａｔｕｒｅＣｏｏｃｃｕｒｓｉｎｔｗｏｏｘｉｄａｔｉｏｎｓｔａｔｅｓ ,Ｃｏ2 + ａｎｄＣｏ3+ ,ａｎｄｆｏｒｍａｔｉｏｎｏｆｔｈｅｃｏｍｐｌｅｘａｎｉｏｎＣｏ(ＯＨ) - 3 ｉｓａｌｓｏｐｏｓｓｉｂｌｅ .ＤｕｒｉｎｇｗｅａｔｈｅｒｉｎｇＣｏｉｓｒｅｌａｔｉｖｅｌｙｍｏｂｉｌｅｉｎｏｘｉｄｉｚｉｎｇａｃｉｄｅｎｖｉｒｏｎｍｅｎｔ,ｂｕｔｄｕｅｔｏａｈｉｇｈｓｏｒｐｔｉｏｎｂｙＦｅａｎｄＭｎｏｘｉｄｅｓ,ａｓｗｅｌｌａｓｂｙｃｌａｙｍｉｎｅｒａｌｓ,ｔｈｉｓｍｅｔａｌｄｏｅｓｎｏｔｍ…     

云南土壤钴元素背景值及其特征研究

对云南省土壤钴元素背景值进行了采样分析,结果显示:云南土壤钴元素含量呈对数正态分布,中位值16.0mg/kg,几何均值14.88mg/kg,95%置信区间0.92~41.17mg/kg,背景值高于全国,接近南方部分地区。并对其特征进行了研究。     

Effects of simulated acid rain on cation release in soils of South China

This paper deals with the release of base cations and Al3+ at the treatment with simulated acid rain (SAR) in main soil types collected from South China. Results showed that the amounts of base cations increased obviously when the pH value of simulated acid rain was lower than 3.0 or 3.5. Compared with the leaching of K+ and Na+, the leaching of Ca2+ and Mg2+ was affected by the pH value of SAR. Only when the amounts of base cations leached from soils exceeded the cation exchange capacity, the pH value of leaching solutions decreased sharply and the amounts of released Al3+ increased. The H+ buffering mechanisms, which were affected notonly by the pH values of SAR, but also by the types and solid components of soils, were proposed for the main soils studied.     

Effect of long-term fertilization on soil nitrate distribution

ＩｎｔｒｏｄｕｃｔｉｏｎＦｅｒｔｉｌｉｚａｔｉｏｎｉｓｅｓｓｅｎｔｉａｌｆｏｒａｇｒｉｃｕｌｔｕｒａｌｐｒｏｄｕｃｔｉｏｎ ,ｂｕｔｕｎｒｅａｓｏｎａｂｌｙａｐｐｌｙｉｎｇｆｅｒｔｉｌｉｚｅｒｓｃｏｕｌｄｒｅｓｕｌｔｉｎｓｅｒｉｅｓｏｆｐｒｏｂｌｅｍｓｓｕｃｈａｓｃｒｏｐｑｕａｌｉｔｙｄｅｃｌｉｎｅ,ｆｅｒｔｉｌｉｚｅｒｕｓｅｅｆｆｉｃｉｅｎｃｙｄｅｃｒｅａｓｅ,ｒｅｓｉｄｕａｌｆｅｒｔｉｌｉｚｅｒｓｐｏｌｌｕｔｉｏｎ ｇｒｏｕｎｄｗａｔｅｒａｎｄｒｉｖｅｒｓａｎｄｎｉｔｒｏｇｅｎｃｏｎｔｅｎｔｅｄ …