分层开采工艺对地表沉降的影响研究

分层开采是厚煤开采的经典工艺,这种工艺对地表沉降的影响比较复杂。通过测试原岩物理力学参数,利用有限元软件flac3D对分层和一次采全高时地表沉降进行了数值模拟。结果表明,如果采高较小,砌体梁距煤层较近,且采完上分层后长时间停采,给顶板再生留足时间,分层开采较一次采全高对地表沉降影响要小。     

滇池鲤鱼的背景元素调查

通过滇池鲤鱼与松花坝水库和国内外同类鲤鱼的元素含量对比,确认滇池鲤鱼受工业污水的危害影响主要是As、Se。鱼体As、Se含量目前已经超过正常值,Ni、Cr、Cu、Fe、Pb比正常值偏低,其它元素属正常值范围。为了避免过多的元素富集,建议滇池鲤鱼以半年到一年为生长捕捞期为宜。     

基于有限元分析的橡胶减振器优化设计

目的加快橡胶减振器的设计过程。方法分析橡胶材料及Mooney-Rivllin橡胶本构模型特点,介绍橡胶减振器应用特点及隔振设计的相关理论,采用Mooney-Rivllin模型模拟橡胶材料的力学特性,通过引进有限元优化技术,在设计初期保证减振器的刚度特性。结果在某设备减振设计中,采用单轴拉压曲线获取了橡胶材料的Mooney-Rivllin模型参数,以减振器的部分结构尺寸为设计参数,减振器的三向刚度为设计目标,获取了三轴向频率近似相等的隔振系统(轴向频率40 Hz、径向频率40.9 Hz)。通过试验测试,减振系统频率与试验值差别较小,其中轴向差别为2%,径向差别为1%。结论通过引进有限元优化技术,采用合理的橡胶本构模型,可以满足工程精度要求,加速了橡胶减振器的设计过程。     

黔西南喀斯特地区红色风化壳的物源及元素迁移特征

南方喀斯特地区广泛分布着大量的红色风化壳,其成因及形成机制目前还存在争议。本文以贵州黔西南布依族苗族自治州泥凼石林的两处红色风化壳剖面(ND和YK)为研究对象,来探讨风化剖面上覆红土的物源问题,并计算其主、微量元素及稀土元素的迁移规律,认为本研究两处风化壳上覆红土为下伏基岩原位风化形成的,而且两剖面土壤均继承各自基岩的地球化学特征,并由于pH、风化强度等因素的影响表现出了元素迁移特征上的差异性。     

螯合树脂在线富集——火焰原子吸收光度法测定水中微量Cu,Pb,Zn,Cd

对螯合树脂在线富集，火焰原子吸收光度法进行了条件试验。试验证实方法对Ｃｕ、Ｐｂ、Ｚｎ、Ｃｄ４个元素检出浓度可达μｇ／Ｌ级，校准曲线性、样品重现性及准确度可满足测定要求。     

The Chemistry of Soils, Rocks and Plant Bioindicators in Three Ecosystems of the Holy Cross Mountains, Poland

In June of 2000, biogeochemical study was carried out in three ecosystems of the Holy Cross Mountains (south-central Poland). This paper presents element concentrations and stable sulfur (and in one site lead) isotope ratios in rocks, detailed soil profiles, and plant bioindicators including epiphytic lichen Hypogymnia physodes (L.) Nyl., mosses (Pleurozium schreberi (Brid.) Mitt., Hypnum cupressiforme Hedw. S. Str., Hylocomium splendens (Hedw.) B.S.G.), Scots pine (Pinus sylvestris L.), common birch (Betula pendula Roth.), aspen (Populus tremula L.) and English oak (Quercus robur L.). Chemical analyses were performed with ICP-AES and AAS methods in the accredited laboratory (Central Chemical Laboratory of the Polish Geological Institute in Warsaw). The principal objective of this study was to compare the chemical composition of rocks, soils and selected plant bioindicators between investigation sites using the same methods of sample collection, preparation and analyses. The results of this study have shown that there is a high variability in concentrations of elements in plant bioindicators from the same sites that can not be explained only by soil properties or anthropogenic influence. This conclusion indicates that for biomonitoring purposes (especially with vascular plants) we cannot neglect individual features of the species examined.     

Large-scale mercury variations in Lake Vänern (Sweden) 1974-98

Lake V?nern, the largest lake in Sweden, has been seriously contaminated with mercury during the 20th century. In the 1970's and 80's the direct load, mainly from a chlor-alkali industry in the area, of mercury was drastically reduced as a response to new legislation, from three to five tons down to between five and ten kg yr(-1). Large amounts of the disposed pollutant have accumulated in the sediments. The question posed in this work is now, is the effect of the drastic load reduction after more than two decades visible in the sediments? The question is relevant as large areas still are blacklisted for fishing, but also as a follow-up of a major remedy action. The lake also serves as a freshwater reservoir for even Sweden's second largest city. This work synthesises and compares data of mercury in the sediments from three major field programs, in 1974, 1984 and 1998. The interest is focused on both spatial heterogeneity and temporal trends. In 1974, the surface concentrations are significantly higher than in subsequent surveys. Significant differences are also found between 1984 and 1998. Significant spatial differences within the lake are found for respective year. The most contaminated area is located in the north, close to the major point source (a former chlor-alkali industry). This is also the area with the largest improvement, as a direct response to the reduction in load. Further from the outlet, the recovery is more affected by burial and transport processes out into the deeper basins.     

Exposure Assessment to Mercury Vapor in Chloralkali Industry

The aim of the study was to develop a sampling method aimed at individual sampling of mercury vapor and subsequent individualexposure assessment of the worker. Hopcalite available fromInowrocawskie Zakady Chemiczne (in Poland) was founduseful for mercury vapor sampling in active and passive individual samplers. However the sampling rate determined forpassive sampler in steady-state laboratory chamber cannot be usedunder fluctuating conditions of mercury vapor concentration andair movement typical for field measurement. In order to check comparativeness of passive and active sampling methods, sampleswere taken in the same time and individual samplers fixed toworker's clothes were used. Mercury vapor concentration wasmeasured at two chloralkali industries in Poland and the resultswere presented. Excessive exposure in both industries wasconfirmed by finding elevated mercury concentration in urinesamples from the workers.     

MERCURY EMISSION INVENTORY IN ONTARIO

Mercury is released to the environment from various anthropogenic and natural sources. This work is a compilation of mercury emissions from anthropogenic sources in Ontario, Canada. The goal of our study was to identify all sources of mercury, and develop an emission inventory of anthropogenic mercury in Ontario. The result of our investigation revealed that combustion of fossil fuels and emissions from landfill sites are two primary sources of mercury to the atmosphere. Other sources of significance are emissions from waste incinerators, various industrial activities, and cement production. Total mercury emission in Ontario is estimated as 4100 kg per year.     

金属体积成形过程有限元模拟中六面体网格重划技术的研究

针对金属体积成形过程有限元模拟中的网格重划问题 ,提出了基于边界构形的有限元网格重划技术 ,并对其中的一系列技术处理进行了详尽的讨论。将该技术应用于矩形块体镦粗过程的有限元模拟中 ,较好地解决了六面体网格重划问题。