全文获取类型
收费全文 | 186篇 |
免费 | 21篇 |
国内免费 | 43篇 |
专业分类
安全科学 | 25篇 |
废物处理 | 6篇 |
环保管理 | 16篇 |
综合类 | 163篇 |
基础理论 | 15篇 |
环境理论 | 1篇 |
污染及防治 | 16篇 |
评价与监测 | 2篇 |
社会与环境 | 1篇 |
灾害及防治 | 5篇 |
出版年
2023年 | 3篇 |
2022年 | 4篇 |
2021年 | 14篇 |
2020年 | 11篇 |
2019年 | 13篇 |
2018年 | 8篇 |
2017年 | 7篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 5篇 |
2013年 | 7篇 |
2012年 | 20篇 |
2011年 | 27篇 |
2010年 | 19篇 |
2009年 | 20篇 |
2008年 | 8篇 |
2007年 | 14篇 |
2006年 | 7篇 |
2005年 | 6篇 |
2004年 | 9篇 |
2003年 | 4篇 |
2002年 | 5篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1981年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有250条查询结果,搜索用时 140 毫秒
1.
Dong Cao Ziyu Rao Fanglan Geng Hongyun Niu Yali Shi Yaqi Cai Yuehui Kang 《环境科学学报(英文版)》2020,32(11):67-74
Molecular level characterization of dissolved organic sulfur (DOS) by electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR MS) is necessary for further understanding of the role of DOS in the environment. Here, ESI spray solvent, a key parameter for ion production during ESI process, was investigated for its effect on the molecular characterization of DOS by ESI-FTICR MS. 100% MeOH as spray solvent was found for the first time to remarkably enhance the ionization efficiency of the majority of CHOS-molecules in NOM, which facilitated a total of 1473 CHOS-molecular formulas with one sulfur atom to be detected. The number of CHOS-molecular formulas obtained using 100%MeOH as spray solvent increased notably over 740 in comparison with those using 50% MeOH aqueous solution (731) or 50% ACN aqueous solution (653). Moreover, due to the enhancement of ionization efficiency of DOS during ESI processes, the tandem mass spectra of the NOM CHOS-molecules could be easily obtained using 100% MeOH as spray solvent, which were hardly obtained using 50% MeOH aqueous solution as spray solvent. The results of the tandem mass spectra suggested the first discovery of organosulfates or sulfonic acids in Suwannee River NOM sample. A simple method based on 100% MeOH as ESI spray solvent for advanced molecular characterization of DOS by ESI-FTICR MS was proposed and applied, and the results revealed more molecular information of DOS in sea DOM samples. 相似文献
2.
Cynthia J. Sims MD Don T. Fujito Dennis R. Burholt Josef Dadok Harlan R. Giles D. Allan Wilkinson 《黑龙江环境通报》1993,13(6):473-480
We have investigated the ability of high-resolution proton NMR spectroscopy to provide a biochemical constituent screening of human amniotic fluid (AF). Proton NMR spectra were obtained at 300 MHz on AF from patients undergoing amniocentesis in the mid-trimester. Only AF from normal pregnancies (normal fetal karyotype, normal a-fetoprotein levels, normal birth outcome) was used in this study. The AF supernatant was lyophilized and resuspended in deuterated water containing 0.1 mm phosphate buffer and 6.02 mm disodium maleate. Identification of low molecular weight compounds was confirmed by two-dimensional NMR spectra (primarily correlated spectroscopy, or COSY) and standard addition techniques. A broad profile of compounds were ‘NMR visible’ in a single proton spectrum, including creatinine, glucose, organic acids (acetate, citrate, and lactate) and several amino acids (alanine, histidine, leucine, phenylalanine, tyrosine and valine). The proton spectrum was unaffected by prior freezing/thawing of AF samples. We were able to quantify compounds by comparison with an added concentration standard (maleate) at concentrations as low as 30 μm. Good agreement with literature values based on other analytical techniques was obtained. 相似文献
3.
不同声学元件在公路声屏障中的应用 总被引:1,自引:0,他引:1
通过对公路声屏障不同声学元件声学性能的比较研究,阐明了两种声学元件在治理交通噪声中的差别,指出吸声共振型声学元件将是未来公路声屏障的发展方向,该研究结论对于开展公路声障声学设计有较为重要的参考价值 相似文献
4.
目的 解决某单缸摩托车发动机台架测试时中低速扭矩线性度差的问题.方法 基于CFD数值分析方法,运用热力学仿真分析软件GT-Power对发动机进行建模和标定,然后对原方案发动机进行摸底分析,最后通过优化配气机构和进排气系统来实现改善中低速性能的目标.结果 优化后的发动机台架测试结果中,发动机中低速扭矩线性度改善,动力性和经济性及排放都达到项目预期目标,峰值功率达到16 kW(9500 r/min),峰值扭矩达到18.6 N·m(7000 r/min),最低比油耗为183 g/(kW·h),CO、THC、NOx排放量分别为840、83、54 mg/km.配气机构运动学动力学性能与可靠性提升,进排气凸轮丰满系数分别达到5.14、5.15.结论 原方案中低速扭矩线性度差的原因为此转速段充气效率较低.优化凸轮型线、空滤器、消声器、排气管道参数能更好地利用进排气管道谐振效应来提升发动机中低速动力性能. 相似文献
5.
通过红外光谱和核磁共振方法分析生产水杨酸甲酯时所产生的废渣的主要在分,得出主要成分是4-羟基-1,3-苯二甲酸二甲酯的讨论。该化合物在药物合成上一定的用途。 相似文献
6.
7.
Roberta Palmieri Giuseppe Bonifazi Silvia Serranti 《Waste management (New York, N.Y.)》2014,34(11):2120-2130
This study characterizes the composition of plastic frames and printed circuit boards from end-of-life mobile phones. This knowledge may help define an optimal processing strategy for using these items as potential raw materials. Correct handling of such a waste is essential for its further “sustainable” recovery, especially to maximize the extraction of base, rare and precious metals, minimizing the environmental impact of the entire process chain. A combination of electronic and chemical imaging techniques was thus examined, applied and critically evaluated in order to optimize the processing, through the identification and the topological assessment of the materials of interest and their quantitative distribution. To reach this goal, end-of-life mobile phone derived wastes have been systematically characterized adopting both “traditional” (e.g. scanning electronic microscopy combined with microanalysis and Raman spectroscopy) and innovative (e.g. hyperspectral imaging in short wave infrared field) techniques, with reference to frames and printed circuit boards. Results showed as the combination of both the approaches (i.e. traditional and classical) could dramatically improve recycling strategies set up, as well as final products recovery. 相似文献
8.
Xiangyun Zhong Shiyong Wu Yang Liu Zhenning Zhao Yaru Zhang Jinfeng Bai Jun Xu Bai Xi 《环境科学学报(英文版)》2013
The evolvement of morphology and structure of the coal with different metamorphic degrees during coking process in the vertical furnace was investigated by infrared Image detector. Moreover, the temperature distribution in the radial direction and the crack formation were also studied in heating process. The results show that the amount of crack and the shrinkage level of char decrease with the coal rank rising. In addition, the initial temperature of crack formation for char increases with the coal rank rising. 相似文献
9.
10.
A new resonance scattering method was proposed for the determination of chlorite, basing on the resonance scattering effect of rhodamine dye. In HCl-sodium acetate buffer solution, chlorite oxidizes 1- into 12 and the reaction of 12 and excess 1- results in If. It is respectively combined with rhodaminc dyes, including rhodamine B (RhB), butyl rhodamine B (b-RhB), rhodamine G (RhG) and rhodamine S (RhS), to form association complex particles, which exhibit stronger resonance scattering (RS) effect at 400 nm. The chlorite concentration of ClO2 in the range of 0.00726-0.218 μg/ml, 0.0102-0.292 μg/ml, 0.00726-0.145 μg/ml and 0.0290- 0.174 μg/ml is respectively linear to the RS intensity of association complex particle systems at 400 nm for the RhB, b-RhB, RhG and RhS. The detection limits of the four systems were respectively 0.00436, 0.00652, 0.00580 and 0.01450μg/ml ClO2^-. In the four systems, the RhB system possesses good stability and high sensitivity. It has been applied to the analysis of chlorite in wastewater with satisfactory results. 相似文献