低温等离子体协同催化降解废气污染物的研究进展

阐述了低温等离子体协同催化工艺流程与反应机理,探讨了反应温度、废气进口组分、废气中水蒸气含量、气体流速、气溶胶等因素对降解效果的影响。分析认为:一段式低温等离子体协同催化可改变低温等离子体特征及催化剂催化特性,但尚未解决尾气臭氧逃逸、副产物产生及放电稳定性等问题;两段式低温等离子体协同催化可提高污染物分子降解效率并减少尾气臭氧逃逸,但未能有效利用等离子体的能量,气体中的水蒸气、粉尘及反应过程中产生的气溶胶均能影响后置催化剂的催化性能;两段式低温等离子体协同催化已具备工程应用条件,还需配套高效预处理单元以降低废气中水蒸气、粉尘等对催化剂的影响。     

上海地区二氧化硫浓度和风速的统计关系

应用上海市1986年6月至1987年5月间5个自动监测站的全年每日逐时SO_2浓度平均值和同步的风速平均值资料,按季进行比较、归纳,得到风速—SO_2浓度的诊断判据,并利用1984年全年的相应资料进行验证,准确率达85％;得到了各季浓度—风速的回归方程,和浓度—风速、温差的二元回归方程、复相关系数。     

赣南数字地震台网近震分析与震情速报

震相识别与分析是地震预报与速报的基础.为识别赣南地区的震相,用震例统计和实例说明了不同距离,不同方位,不同类型的地震震相特征、地震震相与爆破波形的区别,并阐述了如何快速、准确地对有感地震进行速报.     

Synergistic effect of F and triggered oxygen vacancies over F-TiO2 on enhancing NO ozonation

Oxidation-absorption technology is a key step for NO_x removal from low-temperature gas. Under the condition of low O₃ concentration (O₃/NO molar ratio = 0.6), F-TiO₂ (F-TiO₂), which is cheap and environmentally friendly, has been prepared as ozonation catalysts for NO oxidation. Catalytic activity tests performed at 120°C showed that the NO oxidation efficiency of F-TiO₂ samples was higher than that of TiO₂ (about 43.7%), and the NO oxidation efficiency of F-TiO₂-0.15 was the highest, which was 65.3%. Combined with physicochemical characteristics of catalysts and the analysis of active species, it was found that there was a synergistic effect between F sites and oxygen vacancies on F-TiO₂, which could accelerate the transformation of monomolecular O₃ into multi-molecule singlet oxygen (¹O₂), thus promoting the selective oxidation of NO to NO₂. The oxidation reaction of NO on F-TiO₂-0.15 follows the Eley-Rideal mechanism, that is, gaseous NO reacts with adsorbed O₃ and finally form NO₂.     

有机物分子结构与光催化氧化反应活性的关系

从正辛醇－水分配系数与Ｈａｍｍｅｔｔ常数，光催化氧化过程中的光解作用，表面活性剂的微环境效应及取代基的诱导效应等方面，探讨了有机物分子结构与其光催化氧化反应性之间的关系。     

粉煤灰综合利用—制无烟型煤

粉煤灰,又称“烟道灰”,是从燃烧装置的烟道气中收集而得到的细灰.目前,国内外对粉煤灰的综合利用极为重视,但大部分都着眼于建材、建筑和农业等方面,而本发明是将粉煤灰作为型煤的掺合料配制型煤,即将粉煤灰与烟煤、褐煤和泥炭混配,再加入适量的添加剂,混匀后经压力成型制成各种形状的无烟燃料.实践证明,只要灰质、煤质和掺比相匹配,可压制成合格的掺灰型煤,达到“煤掺灰,灰代煤、效益高”的效果.该掺灰型煤,具有反应活性高,燃烧效果好,基本无烟等特点,投资少,见效快,效益高,节约能源等.经试烧证明,燃烧排烟中的各种污染物可消减50%以上,节约煤炭约30%以上,并且,每吨掺灰型煤(按售价每吨100元计算)可增收15—20元.     

Decomplexation of Cu-1-hydroxyethylidene-1,1-diphosphonic acid by a three-dimensional electrolysis system with activated biochar as particle electrodes

The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10⁻³ and 1.94 × 10⁻⁵ min⁻¹respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H₂O₂ and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed.     

填埋场垃圾堆体平面压实工程试验研究

原生垃圾密度很小，为提高填埋垃圾堆体密实度、延长填埋场使用寿命，对填埋垃圾进行压实处理很重要。本文通过现场工程试验对影咱填埋垃圾堆体平面压实效果的主要因素进行了系统研究。实验结果表明：为取得最佳的垃圾堆体平面压实效果，最佳垃圾摊铺厚度在0.5m—0.7m之间，最佳机械行程次数为3次，增加碾压次数有利于提高垃圾堆体密实度，垃圾最佳含水率在30％——50％之间。     

吉林省的风能潜力(英文)

近两年我国电力突然短缺,已经引起政府的高度重视。由于我国风电发展的紧迫性和风电发展的潜力,特别是国际上正在如火如荼地开发风电的情景,中国- 奥地利政府间双边合作计划将风电评估列入2001～2003 年度合作计划,论文是该计划的成果之一。以我国吉林省为研究对象,采用广泛使用的风机选址算法和空间分布诊断程序( WAsP和ZAWIMOD2),运用数字地形图和遥感资料获得的土地利用图,进而得到数字化的表面粗糙度,再对吉林省的风能潜力进行估算。完成了近1km² 分辨率的距地面60m高度的风速和风能密度计算,并制作了它们的分布图。这是我国第一次在较大区域上估算距地面60m 高度的风速和风能密度,其方法对我国风电资源的评估有重要的借鉴作用。结果显示最有效的风能资源在吉林省的中西部地区,而南部和东部的高风资源区位于山脊和山顶,对风能的开发有一定的限制。     

南昌地震台地下水位变化异常的分析判别

本篇文章主要通过对南昌台地下水位资料变化的处理分析，利用求地下水水位变化的加速度来判别和分析地震异常，并初步进行试验预报和探索研究。